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2009 Fiscal Year Final Research Report

Study on large-scaled hydrogen bond network structures of water by infrared spectroscopy of large-sized clusters

Research Project

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Project/Area Number 19205001
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

FUJII Asuka  Tohoku University, 大学院・理学研究科, 准教授 (50218963)

Co-Investigator(Renkei-kenkyūsha) MAEYAMA Toshihiko  東北大学, 大学院・理学研究科, 助教 (20250673)
MATSUDA Yoshiyuki  東北大学, 大学院・理学研究科, 助教 (70400223)
Project Period (FY) 2007 – 2009
Keywords水素結合 / クラスター / 水 / 赤外分光
Research Abstract

Infrared spectra of size-selected neutral and protonated water clusters have been observed in the size range of n=10-200. The spectra show structural development of the water hydrogen bond network of which size region has not been experimentally explored.

  • Research Products

    (44 results)

All 2010 2009 2008 2007 Other

All Journal Article (22 results) (of which Peer Reviewed: 21 results) Presentation (21 results) Remarks (1 results)

  • [Journal Article] Infrared spectroscopy for acetone and its dimer based on photoionization detection with tunable coherent vacuum-ultraviolet light2009

    • Author(s)
      Yoshiyuki Matsuda, Keisuke Ohta, Naohiko Mikami, Asuka Fujii
    • Journal Title

      Chem.Phys.Lett. 471

      Pages: 50-52

    • Peer Reviewed
  • [Journal Article] Vibrational spectroscopy of size-selected neutral and cationic clusters combined with vacuum-ultraviolet one-photon ionization detection2009

    • Author(s)
      Yoshiyuki Matsuda, Naohiko Mikami, Asuka Fujii
    • Journal Title

      Phys.Chem.Chem.Phys. 11

      Pages: 1279-1290

    • Peer Reviewed
  • [Journal Article] Proton switch correlated with the morphological development of the hydrogen-bond network in H+(MeOH)m(H2O)1 (m=1-9) : A theoretical and infrared spectroscopic study2009

    • Author(s)
      Dan Ding, Jer-Lai Kuo, Ken-ichiro Suhara, Asuka Fujii, Naohiko Mikami
    • Journal Title

      J.Phys.Chem.A 113

      Pages: 2323-2332

    • Peer Reviewed
  • [Journal Article] Interpreting the physical background of empirical solvent polarity via photodetachment spectroscopy of microsolvated aromatic ketyl anions2009

    • Author(s)
      Toshihiko Maeyama, Keiji Yoshida, Izumi Yagi, Asuka Fujii, Naohiko Mikami
    • Journal Title

      J.Phys.Chem.A 113

      Pages: 10593-10602

    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy of phenol-(H2O)n>10 : Structural strains in hydrogen bond networks if neutral water clusters2009

    • Author(s)
      Kenta Mizuse, Toru Hamashima, Asuka Fujii
    • Journal Title

      J.Phys.Chem.A 113

      Pages: 12134-12141

    • Peer Reviewed
  • [Journal Article] Intermolecular proton-transfer in acetic acid clusters induced by vacuum-ultraviolet photoionization2009

    • Author(s)
      Keisuke Ohta, Yoshiyuki Matsuda, Naohiko Mikami, Asuka Fujii
    • Journal Title

      J.Chem.Phys. 131

      Pages: 18304

    • Peer Reviewed
  • [Journal Article] Experimental and theoretical determination of the accurate interaction energies in benzene-hahomethane ; the unique nature of the activated CH/π interaction of haloalkanes2008

    • Author(s)
      Asuka Fujii, Kenta Shibasaki, Takaki Kazama, Ryousuke Itaya, Naohiko Mikami, Seiji Tsuzuki
    • Journal Title

      Phys.Chem.Chem.Phys. 10

      Pages: 2836-2843

    • Peer Reviewed
  • [Journal Article] CH/π interactions in methane clusters with polycyclic aromatic hydrocarbons2008

    • Author(s)
      Seiji Tsuzuki, Kazumasa Honda, Asuka Fujii, Tadafumi Uchimaru, Masuhiro Mikami
    • Journal Title

      Phys.Chem.Chem.Phys 10

      Pages: 2860-2865

    • Peer Reviewed
  • [Journal Article] Nature and physical origin of CH/π interaction : significant difference from conventional hydrogen bonds2008

    • Author(s)
      Seiji Tsuzuki, Asuka Fujii
    • Journal Title

      Phys.Chem.Chem.Phys. 10

      Pages: 2584-2594

  • [Journal Article] Photoelectron spectroscopy of microsolvated benzophenone radical anions to reveal the origin of solvatochromic shifts in alcoholic media2008

    • Author(s)
      Toshihiko Maeyama, Izumi Yagi, Asuka Fujii, Naohiko Mikami
    • Journal Title

      Chem.Phys.Lett. 457

      Pages: 18-22

    • Peer Reviewed
  • [Journal Article] Naohiko Mikami, Size-selected infrared predissociation spectroscopy of neutral and cationic formamide-water clusters : Stepwise growth of hydrated structures and intracluster hydrogen transfer induced by vacuum ultraviolet photoionization2008

    • Author(s)
      Daichi Sakai, Yoshiyuki Matsuda, Masaki Hachiya, Mayumi Mori, Asuka Fujii
    • Journal Title

      J.Phys.Chem.A 112

      Pages: 6840-6849

    • Peer Reviewed
  • [Journal Article] Observation of an isolated intermediate of the nucleophilic aromatic substitution reaction by infrared spectroscopy2008

    • Author(s)
      Hayato Hasegawa, Kenta Mizuse, Masaki Hachiya, Yoshiyuki Matsuda, Naohiko Mikami, Asuka Fujii
    • Journal Title

      Angew.Chem.Int.Ed. 47

      Pages: 6008-6010

    • Peer Reviewed
  • [Journal Article] Infrared predissociation spectroscopy of cluster cations of protic molecules, (NH3)n+, n=2-4 and (CH3OH)n+, n=2,32008

    • Author(s)
      Masaki Hachiya, Yoshiyuki Matsuda, Ken-ichiro Suhara, Naohiko Mikami, Asuka. Fujii
    • Journal Title

      J.Chem.Phys. 129

      Pages: 094306

    • Peer Reviewed
  • [Journal Article] Comprehensive analysis of the hydrogen bond network morphology and OH stretching vibrations in protonated methanol-water mixed clusters, H+(MeOH)1(H2O)n (n=1-8)2008

    • Author(s)
      Jer-Lai Kuo, Zhi-zhong Xie, Dan Bing, Asuka Fujii, Toru Hamashima, Ken-ichiro Suhara, Naohiko Mikami
    • Journal Title

      J.Phys.Chem.A 112

      Pages: 10125-10133

    • Peer Reviewed
  • [Journal Article] Magnitude and nature of interactions in benzene-X (X=ethylene, acetylene) in the gas phase : Significantly different CH/π interaction of acetylene as compared with those of ethylene and methane2007

    • Author(s)
      Kenta Shibasaki, Asuka Fujii, Naohiko Mikami, Seiji Tsuzuki
    • Journal Title

      J.Phys.Chem.A 111

      Pages: 753-758

    • Peer Reviewed
  • [Journal Article] Compatibility between methanol and water in the three-dimensional cage formation of large-sized protonated methanol-water mixed clusters2007

    • Author(s)
      Ken-ichiro Suhara, Asuka Fujii, Kenta Mizuse, Naohiko Mikami, Jer-Lai Kuo
    • Journal Title

      J.Chem.Phys. 126

      Pages: 194306-1-8

    • Peer Reviewed
  • [Journal Article] Naohiko Mikami, Stimulated Raman spectroscopy combined with vacuum ultraviolet photoionization : Application to jet-cooled methanol clusters as a new vibrational spectroscopic method for size-selected species in the gas phase2007

    • Author(s)
      Yoshiyuki Matsuda, Masaki Hachiyta, Asuka Fujii
    • Journal Title

      Chem.Phys.Lett. 442

      Pages: 217-219

    • Peer Reviewed
  • [Journal Article] Long range influence of an excess proton on the architechture of the hydrogen bond network in large-sized water clusters2007

    • Author(s)
      Kenta Misuse, Asuka Fujii, Naohiko Mikami
    • Journal Title

      J.Chem.Phys. 126

      Pages: 231101-1-4

    • Peer Reviewed
  • [Journal Article] Stepwise solvatochromism of ketyl anions in the gas phase : Photodetachment excitation spectroscopy of benzophenone and acetophenone radical anions microsolvated with methanol2007

    • Author(s)
      Izumi Yagi, Toshihiko Maeyama, Asuka Fujii, Naohiko Mikami
    • Journal Title

      J.Phys.Chem.A 111

      Pages: 7646-7652

    • Peer Reviewed
  • [Journal Article] Characterization of neutral fragments issued from the photodissociation of protonated tryptophan2007

    • Author(s)
      V. Lapere, B. Lucas, M. Barat. J. A. Fayeton, Y. J. Picard, C. Jouvet, P. Carcabal, I. Nielsen, C. Dedonder-Lardeux, G. Gregoire, A. Fujii
    • Journal Title

      Phys.Chem.Chem.Phys. 9

      Pages: 5330-5334

    • Peer Reviewed
  • [Journal Article] Comprehensive characterization of the photodissociation pathways of protonated tryptophan2007

    • Author(s)
      V. Lapere, B. Lucas, M. Barat. J. A. Fayeton, Y. J. Picard, C. Jouvet, P. Carcabal, I. Nielsen, C. Dedonder-Lardeux, G. Gregoire, A. Fujii
    • Journal Title

      J.Chem.Phys. 127

      Pages: 13413-1-11

    • Peer Reviewed
  • [Journal Article] Theoretical analyses of the morphological development of the hydrogen bond network in protonated methanol clusters2007

    • Author(s)
      Jer-Lai Kuo, Asuka Fujii, Naohiko Mikami
    • Journal Title

      J.Phys.Chem.A 111

      Pages: 9438-9445

    • Peer Reviewed
  • [Presentation] Infrared spectroscopy of size-selected large water clusters2010

    • Author(s)
      Asuka Fujii
    • Organizer
      Discussion meeting on spectroscopy and dynamics of molecules and clusters
    • Place of Presentation
      Goa, India
    • Year and Date
      20100218-20100221
  • [Presentation] 大サイズ Phenol-(H2O)n(n<~50) の赤外分光~大サイズ水クラスターの水素結合ネットワーク構造~2009

    • Author(s)
      濱島徹, 水瀬賢太, 藤井朱鳥
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20090921-20090924
  • [Presentation] アセトン-水クラスターの真空紫外光イオン化誘起プロトンマイグレーション2009

    • Author(s)
      松田欣之, 山田綾子, 三上直彦, 藤井朱鳥
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20090921-20090924
  • [Presentation] Infrared spectroscopy of large-sized water networks in gas phase clusters2009

    • Author(s)
      Asuka Fujii
    • Organizer
      Symposium on Dynamics of Molecules and Clusters, Department of Chemistry, Graduate School of Science
    • Place of Presentation
      Tohoku University
    • Year and Date
      2009-07-03
  • [Presentation] 気相孤立系における芳香族求核置換反応中間体の赤外分光2008

    • Author(s)
      水瀬賢太, 長谷川勇人, 蜂谷正樹, 松田欣之, 三上直彦, 藤井朱鳥
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      20080924-20080927
  • [Presentation] ミクロ溶媒和負イオンの光電子脱離分光から見た "溶媒極性" の物理的背景 その12008

    • Author(s)
      前山俊彦, 吉田啓二, 藤井朱鳥, 三上直彦
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      20080924-20080927
  • [Presentation] プロトン付加水クラスターH+(H2O)nにおける大規模水素結合ネットワーク構造2008

    • Author(s)
      水瀬賢太, 三上直彦, 藤井朱鳥
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      20080924-20080927
  • [Presentation] 酢酸の水素結合クラスター真空紫外光イオン化検出赤外解離分光2008

    • Author(s)
      太田圭亮, 松田欣之, 藤井朱鳥, 三上直彦
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場
    • Year and Date
      20080924-20080927
  • [Presentation] Hydrogen bond structure of large-sized protonated water clusters2008

    • Author(s)
      Asuka Fujii
    • Organizer
      Gordon Research Conference "Molecular and Ionic Clusters, Centre Paul Langevin
    • Place of Presentation
      Aussois, France
    • Year and Date
      20080907-20080912
  • [Presentation] Infrared spectroscopic investigation of nanoscaled hydrogen bond networks in protonated water clusters2008

    • Author(s)
      Asuka Fujii
    • Organizer
      物理化学コロキウム "Laser Chemistry & Nano Materials"
    • Place of Presentation
      東北大学
    • Year and Date
      20080905-20080906
  • [Presentation] 巨大サイズプロトン付加水クラスターの赤外分光~水素結合ネットワーク構造の段階的発展~2008

    • Author(s)
      藤井朱鳥
    • Organizer
      原子衝突研究協会第33回研究会
    • Place of Presentation
      北海道大学
    • Year and Date
      20080806-20080808
  • [Presentation] プロトン性分子クラスターにおける真空紫外光イオン化誘起クラスター内プロトン移動2008

    • Author(s)
      松田欣之, 蜂谷正樹, 太田圭亮, 酒井大地, 三上直彦, 藤井朱鳥
    • Organizer
      第24回化学反応討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      20080602-20080604
  • [Presentation] Infrared and electronic spectroscopy of nucleophilic substitution reaction intermediate cluster cations2008

    • Author(s)
      Kenta Mizuse, Hayato Hasegawa, Asuka Fujii, Naohiko Mikami
    • Organizer
      Gordon Research Conference "Photoions, Photoionization, and Photodetachment"
    • Place of Presentation
      Barga, Italy
    • Year and Date
      20080127-20080201
  • [Presentation] Infrared spectroscopic investigation of nanoscaled hydrogen bond networks in protonated water clusters2008

    • Author(s)
      Asuka Fujii
    • Organizer
      G-COE/IREMC International Meeting "Molecular Science for Future Materials and Complex Phenomena"
    • Place of Presentation
      Tohoku University
    • Year and Date
      2008-08-22
  • [Presentation] Infrared Spectroscopy of Large-Sized Protonated Clusters : Morphological Development of Hydrogen Bond Network2007

    • Author(s)
      Asuka Fujii
    • Organizer
      Okazaki Conference "Molecular Science and Chemical Biology of Biomolecular Function"
    • Place of Presentation
      Okazaki, Institute for Molecular Sciences
    • Year and Date
      20071109-20071111
  • [Presentation] 基本的な溶媒分子のクラスター正イオンの赤外解離分光2007

    • Author(s)
      蜂谷正樹, 松田欣之, 藤井朱鳥, 三上直彦
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台、東北大学
    • Year and Date
      20070917-20070920
  • [Presentation] ホルムアミド-水クラスターの真空紫外光イオン化検出赤外解離分光2007

    • Author(s)
      酒井大地, 松田欣之, 蜂谷正樹, 森麻由美, 藤井朱鳥, 三上直彦
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台、東北大学
    • Year and Date
      20070917-20070920
  • [Presentation] 巨大サイズプロトン付加水クラスター、H+(H20)15-100、の赤外分光~水の大規模水素結合ネットワークに対する余剰プロトンの影響~2007

    • Author(s)
      水瀬賢太, 藤井朱鳥, 三上直彦
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台、東北大学
    • Year and Date
      20070917-20070920
  • [Presentation] 芳香族ケチルアニオンの溶媒和発色機構に対する気相光電子脱離分光による検証2007

    • Author(s)
      八木泉, 前山俊彦, 藤井朱鳥, 三上直彦
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台、東北大学
    • Year and Date
      20070917-20070920
  • [Presentation] 気相クラスターの真空紫外光イオン化検出による質量選別振動分光2007

    • Author(s)
      松田欣之
    • Organizer
      平成19年度化学系学協会東北大会 物理化学コロキウム
    • Place of Presentation
      山形、山形大学
    • Year and Date
      2007-09-21
  • [Presentation] Infrared spectroscopy of large-sized protonated water clusters2007

    • Author(s)
      Asuka Fujii
    • Organizer
      Asia Science Forum
    • Place of Presentation
      Sendai International Center
    • Year and Date
      2007-09-11
  • [Remarks] ホームページ等

    • URL

      http://www.mikamilab.chem.tohoku.ac.jp/

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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