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2010 Fiscal Year Final Research Report

Detections and dynamics of internal motions of radicals and radical complexes with very weak bondings

Research Project

  • PDF
Project/Area Number 19205002
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

ENDO Yasuki  The University of Tokyo, 大学院・総合文化研究科, 教授 (40106159)

Co-Investigator(Kenkyū-buntansha) SUMIYOSHI Yoshihiro  東京大学, 大学院・総合文化研究科, 助教 (50291331)
Project Period (FY) 2007 – 2010
Keywords分子分光学 / フリーラジカル / 分子錯体
Research Abstract

We have prepared mm- and submm-wave sources to extend the applicability of the double resonance spectroscopy, and applied the method for the studies of molecular complexes and short lived species. We have also developed a computer system for the predictions of molecular spectra and analyses of the observed spectra. So far, we have reported results of Ar, Ne-NO and Ne, Kr-OH as interesting and fundamental atom-diatom systems. Observations of H_2CO_3 and HOCO have also been reported, both of which have interesting internal motions.

  • Research Products

    (11 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Spectroscopic detection of the most stable carbonic acid, cis-cis H_2CO_32011

    • Author(s)
      T.Mori, K.Suma, Y.Sumiyoshi, Y.Endo
    • Journal Title

      J. Chem. Phys. 134

      Pages: 044319

    • Peer Reviewed
  • [Journal Article] Microwave spectroscopy of the Ne-OH(^2Π_i) complex and three-dimensional intermolecular potential energy surface2010

    • Author(s)
      Y.Sumiyoshi, I.Funahara, K.Sato, Y.Ohshima, Y.Endo
    • Journal Title

      Phys. Chem. Chem. Phys. 12

      Pages: 8340-8349

    • Peer Reviewed
  • [Journal Article] Intermolecular Potential Energy Surface between Ne and NO (^2Π_r)2010

    • Author(s)
      Y.Sumiyoshi, Y.Endo
    • Journal Title

      J. Phys. Chem. A114

      Pages: 4798-4804

    • Peer Reviewed
  • [Journal Article] Three-dimensional intermolecular potential energy surfaces of the Kr-OH complex2010

    • Author(s)
      Y.Sumiyoshi, I.Funahara K.Sato, Y.Ohshima, Y.Endo
    • Journal Title

      Mol. Phys. 108

      Pages: 2207-2218

    • Peer Reviewed
  • [Journal Article] Spectroscopic detection of isolated carbonic acid2009

    • Author(s)
      T.Mori, K.Suma, Y.Sumiyoshi, Y.Endo
    • Journal Title

      J. Chem. Phys. 130

      Pages: 2040308

    • Peer Reviewed
  • [Presentation] Experimental determination of the intermolecular potentials for open-shell atom-diatom systems2010

    • Author(s)
      Y.Endo
    • Organizer
      米国化学会年会(招待講演)
    • Place of Presentation
      San Fransisco, USA
    • Year and Date
      2010-03-24
  • [Presentation] High-resolution spectroscopy of atom-diatom radical complexes2009

    • Author(s)
      Y.Sumiyoshi, Y.Endo
    • Organizer
      第30回フリーラジカルシンポジウム(招待講演)
    • Place of Presentation
      Finland
    • Year and Date
      2009-07-30
  • [Presentation] Microwave spectroscopy of carbonic acid (cis-trans H_2CO_32009

    • Author(s)
      T.Mori, Y.Sumiyoshi, Y.Endo
    • Organizer
      第30回フリーラジカルシンポジウム
    • Place of Presentation
      Finland
    • Year and Date
      2009-07-26
  • [Presentation] Experimental and analyses on thelarge amplitude motions of rare gas van der Waals complexes2008

    • Author(s)
      Y.Endo
    • Organizer
      Gordon Research Conferences(招待講演)
    • Place of Presentation
      France
    • Year and Date
      2008-09-09
  • [Presentation] Determination of the intermolecular potential energy surface of Ar-NO2007

    • Author(s)
      Y.Sumiyoshi, Y.Endo
    • Organizer
      第29回フリーラジカルシンポジウム
    • Place of Presentation
      Montana USA
    • Year and Date
      2007-08-12
  • [Remarks] ホームページ等

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Published: 2012-01-26   Modified: 2016-04-21  

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