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2010 Fiscal Year Final Research Report

Study on Optical Properties of Organometallic Nano-clusters on a Substrate Using Optical Wave Guide Spectroscopy

Research Project

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Project/Area Number 19205004
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionKeio University

Principal Investigator

NAKAJIMA Atsushi  Keio University, 理工学部, 教授 (30217715)

Co-Investigator(Kenkyū-buntansha) MITSUI Masaaki  静岡大学, 理学部, 准教授 (90333038)
Co-Investigator(Renkei-kenkyūsha) NAGAOKA Shuhei  慶應義塾大学, 理工学部, 助教 (60509933)
Project Period (FY) 2007 – 2010
Keywords分子分光 / ナノクラスター / ソフトランディング / 光導波路 / 有機金属
Research Abstract

Organometallic clusters having low dimensional network structures were size-selectively deposited with soft-landing technique, and the optical properties of isolated clusters were revealed. In this study, some experimental techniques, such as an optical wave-guide method, were newly developed, and the structures of deposited clusters were observed spectroscopically. Large-scale synthesis of lanthanide organometallic clusters was developed to measure optical properties with fluorescence spectroscopy, and optical response for europium organometallic clusters in the visible light region

  • Research Products

    (36 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (23 results) Remarks (1 results)

  • [Journal Article] Photoemission enhancement induced by near-fields via local surface plasmon resonance of silver nanoparticles on a hydrogen-terminated Si(111) surface2010

    • Author(s)
      T.Nakamura, N.Hirata, Y.Sekino, S.Nagaoka, A.Nakajima
    • Journal Title

      J.Phys.Chem.C Vol.114

      Pages: 16270-16277

    • Peer Reviewed
  • [Journal Article] Electronic structure of hydrogen-terminated silicon surfaces [H-Si(111)] studied by two-photonphotoemission2010

    • Author(s)
      T.Nakamura, K.Miyajima, N.Hirata, T.Matsumoto, H.Tada, Y.Morikawa, A.Nakajima
    • Journal Title

      Applied Physics A Vol.98

      Pages: 735-743

    • Peer Reviewed
  • [Journal Article] Size-dependent magnetic properties of naked and ligand-capped nickel nanoparticles2010

    • Author(s)
      A.Sugiyama, Y.Taguchi, S.Nagaoka, A.Nakajima
    • Journal Title

      Chemical Physics Letters Vol.485

      Pages: 129-132

    • Peer Reviewed
  • [Journal Article] Two-photon photoemission spectroscopy for silver nanoparticles on a hydrogen-terminated Si(111) surface: Metal nanoparticle-enhanced photoemission2010

    • Author(s)
      T.Nakamura, N.Hirata, S.Nagaoka, A.Nakajima
    • Journal Title

      Chemical Physics Letters Vol.489

      Pages: 69-74

    • Peer Reviewed
  • [Journal Article] Soft-landing experiments of Cr(benzene)2 sandwich complexes onto a carboxyl-terminated self-assembled monolayer matrix2009

    • Author(s)
      K.Ikemoto, S.Nagaoka, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem. C Vol.113

      Pages: 4476-4482

    • Peer Reviewed
  • [Journal Article] Characterization of alkyl monolayer covalently bonded to Si(111) and soft-landing of vanadium-benzene sandwich clusters onto the alkyl monolayer substrate2009

    • Author(s)
      T.Matsumoto, S.Nagaoka, K.Ikemoto, M.Mitsui, M.Ara, H.Tada, A.Nakajima
    • Journal Title

      The European Physical Journal D (EPJ D) Vol.52

      Pages: 99-102

    • Peer Reviewed
  • [Journal Article] An atomic force microscope study of vanadium-benzene sandwich clusters soft-landed on self-assembled monolayers2009

    • Author(s)
      S.Nagaoka, K.Ikemoto, K.Fujio, K.Hiehata, A.Sasahara, M.Mitsui, H.Onishi, A.Nakajima
    • Journal Title

      The European Physical Journal D (EPJ D) Vol.52

      Pages: 103-106

    • Peer Reviewed
  • [Journal Article] Thermal and hyperthermal collision-energy depositions of transition metal?benzene sandwich complexes onto a self-assembled n-octadecanethiol monolayer2008

    • Author(s)
      S.Nagaoka, K.Ikemoto, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.C. Vol.112

      Pages: 6891-6899

    • Peer Reviewed
  • [Journal Article] Nanogranular structures formed by combinatorial controlling processes of size-selected metal nanoparticles2008

    • Author(s)
      S.H.Huh, D.H.Riu, C.Y.Kim, Y.Naono, T.Nakamura, A.Sugiyama, A.Nakajima
    • Journal Title

      J.Appl.Phys. Vol.103

      Pages: 094317

    • Peer Reviewed
  • [Journal Article] Soft-landing isolation of gas-phase synthesized transition metal-benzene complexes into a fluorinated self-assembled monolayer matrix2008

    • Author(s)
      S.Nagaoka, K.Ikemoto, T.Matsumoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.C Vol.112

      Pages: 15824-15831

    • Peer Reviewed
  • [Journal Article] Electronic and geometric stabilities of clusters with transition metal encapsulated by silicon2007

    • Author(s)
      K.Koyasu, J.Atobe, M.Akutsu, M.Mitsui, A.Nakajima
    • Journal Title

      J.Phys.Chem.A Vol.111

      Pages: 42-49

    • Peer Reviewed
  • [Journal Article] Soft-Landing Isolation of Multidecker V2(benzene)3 Complexes in an Organic Monolayer Matrix: an Infrared Spectroscopy and Thermal Desorption Study2007

    • Author(s)
      S.Nagaoka, T.Matsumoto, K.Ikemoto, M.Mitsui, A.Nakajima
    • Journal Title

      J.Am.Chem.Soc. Vol.129

      Pages: 1528-1529

    • Peer Reviewed
  • [Presentation] Soft- and Reactive-landing Experiments of Organometallic Sandwich Complexes onto a Self-assembled Monolayer2011

    • Author(s)
      中嶋敦
    • Organizer
      Symposium on Size Selected Clusters 2011
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      2011-03-23
  • [Presentation] 機能複合クラスターの電子物2011

    • Author(s)
      中嶋敦
    • Organizer
      性とそのソフトランディング分子研研究会「分光学が係わるクラスター科学および機能性ナノ構造体科学の将来展望」
    • Place of Presentation
      岡崎コンファレンスセンター
    • Year and Date
      2011-01-07
  • [Presentation] Two-photon Photoemission Study for Alkanethiol Self Assembled Monolayer on Au(111) surface2010

    • Author(s)
      平田直之、渋田昌弘、長岡修平、中嶋敦
    • Organizer
      6th International Workshop on Nano-Scale Spectroscopy & Nanotechnology
    • Place of Presentation
      神戸大学
    • Year and Date
      2010-10-28
  • [Presentation] Soft- and Reactive-landing of Organometallic Clusters onto a Self-assembled Monolayer2010

    • Author(s)
      中嶋敦
    • Organizer
      Molecular Photoscience Research Center International Symposium "New Horizons of Cluster Chemistry"
    • Place of Presentation
      神戸大学
    • Year and Date
      2010-10-09
  • [Presentation] 有機単分子膜表面への遷移金属-アニリンクラスターの固定化と水素吸着反応性2010

    • Author(s)
      堀内一樹、敷島真也、野口裕司、長岡修平、中嶋敦
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2010-09-14
  • [Presentation] Electronic properties of binary superatoms2010

    • Author(s)
      中嶋敦
    • Organizer
      Molecular & Ionic Cluster Conference 2010
    • Place of Presentation
      十日町、新潟
    • Year and Date
      2010-09-06
  • [Presentation] Electronic Structure of H-Terminated Silicon Surfaces [H-Si(111)] Studied by Two-Photon Photoemission2010

    • Author(s)
      中村恒幸、平田直之、中嶋敦
    • Organizer
      7th International Symposium on Ultrafast Surface Dynamics
    • Place of Presentation
      Brijuni Islands, Croatia
    • Year and Date
      2010-08-24
  • [Presentation] Soft-landing experiments of organometallic sandwich complexes onto a self-assembled monolayer2010

    • Author(s)
      中嶋敦
    • Organizer
      The Cluster-Surface Interactions (CSI) Workshop
    • Place of Presentation
      Stratford-on-Avon, United Kingdom
    • Year and Date
      2010-07-07
  • [Presentation] Adsorption Properties of Organometallic Clusters Soft-Landed on Aliphatic Monolayers2010

    • Author(s)
      長岡修平、敷島真也、堀内一樹、中嶋敦
    • Organizer
      Metal-Oxide Surfaces The Cluster-Surface Interactions (CSI) Workshop
    • Place of Presentation
      Stratford-on-Avon, United Kingdom
    • Year and Date
      2010-07-07
  • [Presentation] Chemical Reactivity of Hydrogen Molecules on Titanium-Aniline Half-Sandwich Clusters Grafted on an Organic2010

    • Author(s)
      敷島真也、堀内一樹、長岡修平、中嶋敦
    • Organizer
      Monolayer Surface第26回化学反応討論会
    • Place of Presentation
      広島大学東広島キャンパス
    • Year and Date
      2010-06-02
  • [Presentation] 機能ナノクラスターの創成とナノ材料化2010

    • Author(s)
      中嶋敦
    • Organizer
      ナノ学会第8回大会
    • Place of Presentation
      岡崎コンファレンスセンター
    • Year and Date
      2010-05-14
  • [Presentation] 2D Phase Transition of Self Assembled Monolayer Studied by the Softlanding Experiments2010

    • Author(s)
      中嶋敦
    • Organizer
      4th Jekyll Island Conference on Clusters and Nanostructures
    • Place of Presentation
      Jekyll Island, Georgia, U.S.A.
    • Year and Date
      2010-02-17
  • [Presentation] 液相反応による有機‐ランタノイドサンドイッチクラスターの大量合成2009

    • Author(s)
      辻享志,細谷夏樹,深澤 駿,長岡修平,中嶋敦
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2009-09-21
  • [Presentation] 2光子光電子分光法による水素終端シリコン基板の電子状態の解明2009

    • Author(s)
      中村恒幸,宮島謙,平田直之,松本剛士,森川良忠,夛田博一,中嶋敦
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2009-09-21
  • [Presentation] Electronic properties of size-selected Ag nanoparticles studied by two-photon photoelectron spectroscopy2009

    • Author(s)
      平田直之、中村恒幸、長岡修平、中嶋敦
    • Organizer
      第25回化学反応討論会
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2009-06-01
  • [Presentation] 液相反応による有機-ランタノイドサンドイッチクラスターの大量合成2009

    • Author(s)
      辻享志、細谷夏樹、長岡修平、中嶋敦
    • Organizer
      ナノ学会第7回大会
    • Place of Presentation
      東京大学 本郷キャンパス
    • Year and Date
      2009-05-09
  • [Presentation] カルボキシル末端有機単分子膜へのアニリン-遷移金属サンドイッチクラスターのソフトランディング2008

    • Author(s)
      長岡修平,池本佳織,三井 正明,中嶋 敦
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場、福岡
    • Year and Date
      2008-09-26
  • [Presentation] Soft-Landing Isolation of Transition Metal-Benzene Clusters in Organic Monolayer Matrices2008

    • Author(s)
      S.Nagaoka, K.Ikemoto, K.Fujio, K.Hiehata, A.Sasahara, M.Mitsui, H.Onishi, A.Nakajima
    • Organizer
      14th International Symposium on Small Particles and Inorganic Clusters
    • Place of Presentation
      バリャドリッド,スペイン
    • Year and Date
      2008-09-16
  • [Presentation] 化学修飾したアルカンチオール自己組織化単分子膜上における有機金属クラスターの吸着状態2008

    • Author(s)
      池本佳織,長岡修平,三井正明,中嶋敦
    • Organizer
      第24回化学反応討論会
    • Place of Presentation
      北海道大学学術交流会館
    • Year and Date
      2008-06-02
  • [Presentation] 気相中で作製した表面非修飾ニッケルナノ粒子の磁気特性の評価2008

    • Author(s)
      杉山彰教,田口洋介,長岡修平,三井正明,中嶋敦
    • Organizer
      ナノ学会第6回大会
    • Place of Presentation
      九州大学医学部百年記念講堂
    • Year and Date
      2008-05-07
  • [Presentation] 有機分子マトリクス基板を利用した有機金属サンドイッチクラスターのソフトランディング単離2007

    • Author(s)
      長岡修平,池本佳織,三井正明,中嶋敦
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      東北大学、仙台
    • Year and Date
      2007-09-18
  • [Presentation] カルボキシル末端アルカンチオール自己組織化単分子膜上における有機金属サンドイッチクラスターの吸着状態2007

    • Author(s)
      池本佳織,長岡修平,松本剛士,三井正明,中嶋敦
    • Organizer
      第23回化学反応討論会
    • Place of Presentation
      神戸大学、神戸
    • Year and Date
      2007-06-13
  • [Presentation] 有機分子マトリクス基板を利用した気相クラスターのソフトランディング単離法2007

    • Author(s)
      長岡修平,池本佳織,三井正明,中嶋敦
    • Organizer
      ナノ学会第5回大会
    • Place of Presentation
      つくば国際会議場、つくば
    • Year and Date
      2007-05-21
  • [Remarks] ホームページ等

    • URL

      http://sepia.chem.keio.ac.jp/Nakalab/

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

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