• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2009 Fiscal Year Final Research Report

Creation of Specific Reactions within Self-Assembled Cages

Research Project

  • PDF
Project/Area Number 19205012
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

FUJITA Makoto  The University of Tokyo, 大学院・工学系研究科, 教授 (90209065)

Project Period (FY) 2007 – 2009
Keywords自己組織化 / ナノ空間 / 反応制御 / パラジウム / 光反応
Research Abstract

In this research, we developed novel and specific chemical reactions, employing self-assembled hollow complexes as molecular-sized flasks : (1) Self-assembled M_<24>L_<48> giant spherical complex, (2) Endohedral functionalization of spherical complexes towards unique, unprecedented confined space, (3) Cavity-directed chemical reactions within self-assembled cages, and (4) Direct observation of unstable and reactive intermediates in coordination networks.

  • Research Products

    (61 results)

All 2010 2009 2008 2007 Other

All Journal Article (23 results) (of which Peer Reviewed: 23 results) Presentation (33 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Self-Assembled M24L48 Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation2010

    • Author(s)
      Qing-Fu Sun, Junji Iwasa, Daichi Ogawa, Yoshitaka Ishido, Sota Sato, Tomoji Ozeki, Yoshihisa Sei, Kentaro Yamaguchi, Makoto Fujita
    • Journal Title

      Science DOI : 10. 1126/science.1188605(in press)

    • Peer Reviewed
  • [Journal Article] Naphthalene Diels-Alder in a Self-Assembled Molecular Flask2010

    • Author(s)
      Takashi Murase, Shinnosuke Horiuchi, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2866-2867

    • Peer Reviewed
  • [Journal Article] Coronene Nanophase within Coordination Spheres : Increased Solubility of C_<60>2010

    • Author(s)
      Kosuke Suzuki, Kiyotaka Takao, Sota Sato, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2544-2545

    • Peer Reviewed
  • [Journal Article] Regioselecitive Huisgen Cycloaddition within Porous Coordination Networks2010

    • Author(s)
      Takehide Kawamichi, Yasuhide Inokuma, Masaki Kawano, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49

      Pages: 2375-2377

    • Peer Reviewed
  • [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore2010

    • Author(s)
      Kazuaki Ohara, Masaki Kawano, Yasuhide Inokuma, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 30-31

    • Peer Reviewed
  • [Journal Article] Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities2010

    • Author(s)
      Yoshihiro Yamauchi, Michito Yoshizawa, Munetaka Akita, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 960-966

    • Peer Reviewed
  • [Journal Article] Template synthesis of precisely monodisperse silica nanoparticles within self-assembled organometallic spheres2010

    • Author(s)
      Kosuke Suzuki, Sota Sato, Makoto Fujita
    • Journal Title

      Nature Chem 2

      Pages: 25-29

    • Peer Reviewed
  • [Journal Article] Conformational Preferences of Short Peptide Fragments2009

    • Author(s)
      Yoshiyuki Hatakeyama, Tomohisa Sawada, Masaki Kawano, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 8695-8698

    • Peer Reviewed
  • [Journal Article] ON/OFF Red Emission from Azaporphine in a Coordination Cage in Water2009

    • Author(s)
      KosukeOno, Jeremy K. Klosterman, MichitoYoshizawa, Kentaro Sekiguchi, Tahei Tahara, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 12526-12527

    • Peer Reviewed
  • [Journal Article] Energy Transfer in a Mechanically Trapped Exciplex2009

    • Author(s)
      Jeremy K. Klosterman, Munetaka Iwamura, Tahei Tahara, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 9478-9479

    • Peer Reviewed
  • [Journal Article] X-ray observation of a transient hemiaminal trapped in a porous network2009

    • Author(s)
      Takehide Kawamichi, Tsuyoshi Haneda, Masaki Kawano, Makoto Fujita
    • Journal Title

      Nature 461

      Pages: 633-635

    • Peer Reviewed
  • [Journal Article] Engineering discrete stacks of aromatic molecules2009

    • Author(s)
      Jeremy K. Klosterman, Yoshihiro Yamauchi, Makoto Fujita
    • Journal Title

      Chem.Soc.Rev. 38

      Pages: 1714-1725

    • Peer Reviewed
  • [Journal Article] Remarkable Stabilization of M_<12>L_<24> Spherical Frameworks through the Cooperation of 48 Pd(II)-Pyridine Interactions2009

    • Author(s)
      Sota Sato, Yoshitaka Ishido, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 6064-6065

    • Peer Reviewed
  • [Journal Article] Discrete stack of an odd number of polarized aromatic compounds revealing the importance of net vs. local dipoles2009

    • Author(s)
      Yoshihiro Yamauchi, Michito Yoshizawa, Munetaka Akita, Makoto Fujita
    • Journal Title

      Proc.Natl.Acad.Sci., U.S.A. 26

      Pages: 10435-10437

    • Peer Reviewed
  • [Journal Article] Functional Molecular Flasks : New Properties and Reactions within Discrete, Self-Assembled Hosts2009

    • Author(s)
      Michito Yoshizawa, Jeremy K. Klosterman, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 3418-3438

    • Peer Reviewed
  • [Journal Article] Minimal nucleotide duplex formation in water through enclathration in self-assembled hosts2009

    • Author(s)
      Tomohisa Sawada, Michito Yoshizawa, Sota Sato, Makoto Fujita
    • Journal Title

      Nature Chem. 1

      Pages: 53-56

    • Peer Reviewed
  • [Journal Article] Spin Crossover by Encapsulation2009

    • Author(s)
      Kosuke Ono, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 2782-2783

    • Peer Reviewed
  • [Journal Article] Single-Crystalline Molecular Flasks : Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks2008

    • Author(s)
      Takehide Kawamichi, Tomoki Kodama, Masaki Kawano, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 47

      Pages: 8030-8032

    • Peer Reviewed
  • [Journal Article] Discrete and Well-Defined Hydrophobic Phases Confined in Self-Assembled Spherical Complexes2008

    • Author(s)
      Kosuke Suzuki, Junya Iida, Sota Sato, Masaki Kawano, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 47

      Pages: 5780-5782

    • Peer Reviewed
  • [Journal Article] Asymmetric [2+2] Olefin Cross Photoaddition in a Self-Assembled Host with Remote Chiral Auxiliaries2008

    • Author(s)
      Yuki Nishioka, Takumi Yamaguchi, Masaki Kawano, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 8160-8161

    • Peer Reviewed
  • [Journal Article] Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network2008

    • Author(s)
      Tsuyoshi Haneda, Masaki Kawano, Takehide Kawamichi, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 1578-1579

    • Peer Reviewed
  • [Journal Article] Highly Selective Photomediated 1,4-Radical Addition to o-Quinones Controlled by a Self-Assembled Cage2008

    • Author(s)
      Takumi Yamaguchi, Makoto Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 47

      Pages: 2067-2069

    • Peer Reviewed
  • [Journal Article] Engineering Stacks of Aromatic Rings by the Interpenetration of Self-Assembled Coordination Cages2008

    • Author(s)
      Yoshihiro Yamauchi, Michito Yoshizawa, Makoto Fujita
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 5832-5833

    • Peer Reviewed
  • [Presentation] Reaction control in self-assembled coordination host2010

    • Author(s)
      Makoto Fujita
    • Organizer
      239th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      San Francisco, USA.
    • Year and Date
      2010-03-23
  • [Presentation] Crystalline Molecular Flasks2010

    • Author(s)
      Makoto Fujita
    • Organizer
      239th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-03-22
  • [Presentation] Crystalline Molecular Flasks : Reactions in Crystalline, Finite and Infinite Coordination Hosts2010

    • Author(s)
      Makoto Fujita
    • Organizer
      The 14th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      Korea
    • Year and Date
      2010-03-19
  • [Presentation] Linked Ring Molecules2009

    • Author(s)
      Makoto Fujita
    • Organizer
      ULP Symposium
    • Place of Presentation
      Swiss
    • Year and Date
      20090500
  • [Presentation] Function through Architecture2009

    • Author(s)
      Makoto Fujita
    • Organizer
      2009 RSC Supramolecular and Macrocycles Meeting
    • Place of Presentation
      UK
    • Year and Date
      2009-12-16
  • [Presentation] Function through Architecture2009

    • Author(s)
      Makoto Fujita
    • Organizer
      Tateshina conference
    • Place of Presentation
      Japan
    • Year and Date
      2009-11-15
  • [Presentation] Crystalline Molecular Flasks2009

    • Author(s)
      Makoto Fujita
    • Organizer
      The 2nd Asian Conference on Coordination Chemistry
    • Place of Presentation
      China
    • Year and Date
      2009-11-02
  • [Presentation] Crystalline Molecular Flasks2009

    • Author(s)
      Makoto Fujita
    • Organizer
      The 14th Japan-Korea Seminar on Organic Chemistry
    • Place of Presentation
      Japan
    • Year and Date
      2009-10-23
  • [Presentation] Crystalline Molecular Flasks : Reactions in Crystalline, Finite and Infinite Coordination Hosts2009

    • Author(s)
      Makoto Fujita
    • Organizer
      The 14th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Year and Date
      2009-10-09
  • [Presentation] Chirality enrichment through the heterorecognition of enantiomers in an achiral coordination host2009

    • Author(s)
      Makoto Fujita
    • Organizer
      ACS 238th National Meeting
    • Place of Presentation
      USA
    • Year and Date
      2009-08-17
  • [Presentation] Crystalline Molecular Flasks : Reactions in Crystalline, Finite and Infinite Coordination Hosts2009

    • Author(s)
      Makoto Fujita
    • Organizer
      Chirality and Supramolecular Chemical Synthesis
    • Place of Presentation
      Birmingham, UK
    • Year and Date
      2009-07-28
  • [Presentation] Creation of New Phases in Self-Assembled Organometallic Spheres2009

    • Author(s)
      Makoto Fujita
    • Organizer
      Organometallic Gordon Conference
    • Place of Presentation
      USA
    • Year and Date
      2009-07-16
  • [Presentation] Ractions in Self-Assembled Coordination Hosts2009

    • Author(s)
      Makoto Fujita
    • Organizer
      Calix2009
    • Place of Presentation
      Korea
    • Year and Date
      2009-07-14
  • [Presentation] Endo-Functionalization of M_<12>L_<24> Coordination Spheres2009

    • Author(s)
      Makoto Fujita
    • Organizer
      JaCCS
    • Place of Presentation
      Canada
    • Year and Date
      2009-07-10
  • [Presentation] Porous Coordination Networks as Single Crystalline Flasks2009

    • Author(s)
      Makoto Fujita
    • Organizer
      EAB Meeting
    • Place of Presentation
      China
    • Year and Date
      2009-04-27
  • [Presentation] Nanoscale, Hollow Coordination Architectures : Design, Self-assembly, and Functions2009

    • Author(s)
      Makoto Fujita
    • Organizer
      103rd KCS National Meeting
    • Place of Presentation
      Korea
    • Year and Date
      2009-04-16
  • [Presentation] Single Crystalline Molecular Flasks : Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks2009

    • Author(s)
      Makoto Fujita
    • Organizer
      WMSCI-2008
    • Place of Presentation
      India
    • Year and Date
      2009-02-26
  • [Presentation] Emulating Enzyme Pockets by Self-Assembled Hosts2008

    • Author(s)
      Makoto Fujita
    • Organizer
      Third Asian Summit Symposium on Supramolecular Chemistry
    • Place of Presentation
      Cambodia
    • Year and Date
      2008-11-05
  • [Presentation] Porous Coordination Networks as Crystalline Molecular Flasks2008

    • Author(s)
      Makoto Fujita
    • Organizer
      7th JCSMCC
    • Place of Presentation
      Japan
    • Year and Date
      2008-10-21
  • [Presentation] MnL2n Coordination Spheres : Self-assembly and Peripheral/Endohedral Functionalization2008

    • Author(s)
      Makoto Fujita
    • Organizer
      Yamada Conference
    • Place of Presentation
      Japan
    • Year and Date
      2008-09-02
  • [Presentation] Coordination Architectures : Design, Self-Assembly, and Functions2008

    • Author(s)
      Makoto Fujita
    • Organizer
      4th EuCheMS Conference
    • Place of Presentation
      Garmisch-Partenkirchen, Germany
    • Year and Date
      2008-08-24
  • [Presentation] Self-assembled molecular spheres2008

    • Author(s)
      Makoto Fujita
    • Organizer
      ICCC38
    • Place of Presentation
      Jerusalem, Israel
    • Year and Date
      2008-07-22
  • [Presentation] Reactions in self-assembled organometallic hosts2008

    • Author(s)
      Makoto Fujita
    • Organizer
      ICOMC2008
    • Place of Presentation
      Rennes, France
    • Year and Date
      2008-07-18
  • [Presentation] MnL2n Coordination Shperes : self-Assembly and Peripheral/Endohedral Functionalization2008

    • Author(s)
      Makoto Fujita
    • Organizer
      ISMSC
    • Place of Presentation
      Las Vegas, USA
    • Year and Date
      2008-07-14
  • [Presentation] Single-crystalline Flasks : Chemical Transformations in the Pore of Porous Coordination Networks2008

    • Author(s)
      Makoto Fujita
    • Organizer
      CBNM-Chiba
    • Place of Presentation
      Japan
    • Year and Date
      2008-07-11
  • [Presentation] Porous Coordination Networks as Single Crystalline Molecular Flasks2008

    • Author(s)
      Makoto Fujita
    • Organizer
      UCLA
    • Place of Presentation
      Los Angels, USA
    • Year and Date
      2008-07-03
  • [Presentation] Function through Architecture : New Properties and Reactions in Self-Assembled Coordination Hosts2008

    • Author(s)
      Makoto Fujita
    • Organizer
      Scripps Research Institute
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2008-07-02
  • [Presentation] Nanoscopic Self-assembly via Coordination2008

    • Author(s)
      Makoto Fujita
    • Organizer
      WMSCI-2008
    • Place of Presentation
      Orlando, USA
    • Year and Date
      2008-06-30
  • [Presentation] Reactions in self-assembled hosts2008

    • Author(s)
      Makoto Fujita
    • Organizer
      ICREA+ICIQ Conference on Supramolecular Approaches to Catalysis
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2008-03-03
  • [Presentation] Metal-directed Self-assembly : Function through Architecture2007

    • Author(s)
      Makoto Fujita
    • Organizer
      MTIC-XII
    • Place of Presentation
      India
    • Year and Date
      2007-12-07
  • [Presentation] Noncovalent Assemblies : Design and Synthesis2007

    • Author(s)
      Makoto Fujita
    • Organizer
      Solvay Conference on Chemistry "From Nancovalent Assemblies to Molecular Machines"
    • Place of Presentation
      Brussel Belgium
    • Year and Date
      2007-11-28
  • [Presentation] Metal-Directed Self-Assembly : Function through Architecture2007

    • Author(s)
      Makoto Fujita
    • Organizer
      BSOC
    • Place of Presentation
      Canada
    • Year and Date
      2007-11-12
  • [Presentation] Metal-directed Self-assembly : Function through Architecture2007

    • Author(s)
      Makoto Fujita
    • Organizer
      Nanoscience Days 2007
    • Place of Presentation
      Finland
    • Year and Date
      2007-10-25
  • [Book] In Organic Nanostructures (Eds. J. L. Atwood and J. W. Steed), Chapter 8(Endochemistry of self-assembled hollow spherical cages)2008

    • Author(s)
      Takashi Murase, Makoto Fujita
    • Total Pages
      205-222
  • [Book] In Modern Supramolecular Chemistry, (Eds. F. Diederich, P. J. Stang, and R. R. Tykwinski), Chapter 8(New properties and reactions in self-assembled M6L4 coordination cages)2008

    • Author(s)
      Makoto Fujita, Michito Yoshizawa
    • Total Pages
      277-313
  • [Remarks] ホームページ等

  • [Patent(Industrial Property Rights)] 多面体状遷移金属錯体、超微粒子内包遷移金属錯体およびその製造方法2010

    • Inventor(s)
      藤田誠・佐藤宗太・鈴木康介
    • Industrial Property Rights Holder
      藤田誠
    • Industrial Property Number
      特許, PCT/JP2010/54008
    • Filing Date
      2010-03-10
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2009

    • Inventor(s)
      藤田誠・猪熊泰英・荒井達彦
    • Industrial Property Rights Holder
      藤田誠
    • Industrial Property Number
      特許, 特願2009-265505
    • Filing Date
      2009-11-20

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi