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2007 Fiscal Year Annual Research Report

CVD原子層積層による高キャリア濃度・高移動度IV族半導体人工結晶の創成

Research Project

Project/Area Number 19206032
Research InstitutionTohoku University

Principal Investigator

室田 淳一  Tohoku University, 電気通信研究所, 教授 (70182144)

Co-Investigator(Kenkyū-buntansha) 櫻庭 政夫  東北大学, 電気通信研究所, 准教授 (30271993)
Keywords化学気相成長(CVD) / IV族半導体 / 原子層積層 / 原子層ドーピング / 人工結晶
Research Abstract

本基盤研究では、異種原子層配列制御と同時に非平衡原子層ドーピングを極限まで高度化して、高キャリア濃度・高移動度IV族半導体人工結晶を創成し、Si-Ge系混晶、不純物ドープSiやGe結晶等でのランダムな異種原子配列に起因する局所的な構造・物性のばらつきを抑制する技術を確立しようとするものである。本年度は、原子層オーダで界面が制御された超高移動度IV族半導体異種原子層積層人工結晶膜の実現を目標とし、高Ge組成の高度歪IV族半導体ヘテロエピタキシャル積層について研究を進めた結果、Si_<1-x>Gex層表面の低温SiH_4処理の適用により、高Ge比率(48%)の表面ラフネスを効果的に抑制できることを見いだすと同時に、Ge比率変調構造共鳴トンネルダイオード製作プロセスへの適用により、230K付近まで負性抵抗特性を観測することに成功した。また、不純物ドープIV族半導体の超高キャリア濃度化を目標として、高清浄減圧CVD法による原子レベルで平坦な高濃度B原子層ドープSi薄膜形成について研究を進めた結果、180℃での低温B_2H_6処理とその後の180-300℃での低温SiH_4処理がBクラスタ化の抑制と超高キャリア濃度化に有効であることを明らかにした。さらに、IV族半導体原子層積層膜表面の安定化のために原子層窒化制御について研究を進めた結果、熱窒化SiGe表面においては、熱処理によりGe-N結合が減少し、Si-N結合が増加する傾向があり、窒化膜と基板界面での高Ge比率化が起こることを見いだした。以上のように、化学気相成長原子層積層技術による高キャリア濃度・高移動度IV族半導体人工結晶の創成のために重要な成果を得た。

  • Research Products

    (25 results)

All 2008 2007

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (18 results)

  • [Journal Article] Behavior of N Atoms in Atomic-Order Nitrided Si_<0.5>Ge_<0.5>(100)2008

    • Author(s)
      N. Akiyama
    • Journal Title

      Appl. Surf. Sci. 254(in press)

    • Peer Reviewed
  • [Journal Article] Heavy Atomic-Layer Doping of B in Low-Temperature Si Epitaxial Growth on Si(100)by Ultraclean Low-Pressure Chemical Vapor Deposition2008

    • Author(s)
      H. Tanno
    • Journal Title

      Appl. Surf. Sci. 254(in press)

    • Peer Reviewed
  • [Journal Article] Electrical Characteristics of Hole Resonant Tunneling Diodes with High Ge Fraction(x>0.4)Si/Strained Si_<1-x>Ge_x/Si(100)Heterostructure2008

    • Author(s)
      T. Seo
    • Journal Title

      Appl. Surf. Sci. 254(in press)

    • Peer Reviewed
  • [Journal Article] Self-Limited Growth of Si on B Atomic-Layer Formed Ge(100)by Ultraclean Low-Pressure CVD System2008

    • Author(s)
      T. Yokogawa
    • Journal Title

      Appl. Surf. Sci. 254(in press)

    • Peer Reviewed
  • [Journal Article] Hot Carrier Degradation of Site/Si Heterointerface and Experimental Estimation of Density of Locally Generated Heterointerface Traps2007

    • Author(s)
      T. Tsuchiya
    • Journal Title

      Jpn. J. Appl. Phys. 46

      Pages: 5015-5020

    • Peer Reviewed
  • [Journal Article] Strain Control of Si and Si_<1-x>Ge_x Layers in the Si/Si_<1-x>Ge_x/Si Heterostructures by Stripe-Shape Patterning for Future Si-Based Devices(Invited Paper)2007

    • Author(s)
      J. Murota
    • Journal Title

      ECS Trans. 11

      Pages: 91-99

    • Peer Reviewed
  • [Journal Article] Fabrication of Hole Resonant Tunneling Diodes with Nanometer Order Heterostructures of Si/Strained Si_<1-x>Ge_x Epitaxially Grown on Si(100)(Invited Paper)2007

    • Author(s)
      M. Sakuraba
    • Journal Title

      ECS Trans. 11

      Pages: 131-139

    • Peer Reviewed
  • [Presentation] Behavior of N Atoms on Atomic-Order Nitrided Si_<0.5>Ge_<0.5>(100)2007

    • Author(s)
      N. Akiyama
    • Organizer
      5th Int. Symp. Control of Semiconductor Interfaces(ISCSI-V)
    • Place of Presentation
      Hachioji, Japan
    • Year and Date
      20071112-14
  • [Presentation] Heavily Atomic-Layer Doping of B in Low-Temperature Si Epitaxial Growth on Si(100)by Ultraclean Low-Pressure Chemical Vapor Deposition2007

    • Author(s)
      H. Tanno
    • Organizer
      5th Int. Symp. Control of Semiconductor Interfaces(ISCSI-V)
    • Place of Presentation
      Hachioji, Japan
    • Year and Date
      20071112-14
  • [Presentation] Electrical Characteristics of Hole Resonant Tunneling Diodes with High Ge Fraction(x>0.4)Si/Strained Si_<1-x>Ge_<x>/Si(100)Heterostructure2007

    • Author(s)
      T. Seo
    • Organizer
      5th Int. Symp. Control of Semiconductor Interfaces(ISCSI-V)
    • Place of Presentation
      Hachioji, Japan
    • Year and Date
      20071112-14
  • [Presentation] Self-Limited Growth of Si on B Atomic-Layer Formed Ge(100)by Ultraclean Low-Pressure CVD System2007

    • Author(s)
      T. Yokogawa
    • Organizer
      5th Int. Symp. Control of Semiconductor Interfaces(ISCSI-V)
    • Place of Presentation
      Hachioji, Japan
    • Year and Date
      20071112-14
  • [Presentation] Instability of a SiGe/Si-hetereo-interface in hetero-channel MOSFETs due to Joule heating(Invited Paper)2007

    • Author(s)
      T. Tsuchiya
    • Organizer
      3rd Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20071108-09
  • [Presentation] Characterization of B Incorporation in B Atomic Layer Doping at Si/Ge(100)Heterointerface2007

    • Author(s)
      T. Yokogawa
    • Organizer
      3rd Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20071108-09
  • [Presentation] Heat-Treatment Effect on Structure of Atomic-Order Nitrided Si_<0.5>Ge_<0.5>(100)Using Low Pressure CVD2007

    • Author(s)
      N. Akiyama
    • Organizer
      3rd Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20071108-09
  • [Presentation] Effect of Low-Temperature SiH_4 Exposure on Heavily Atomic-Layer Doping of B in Si Epitaxial Growth on Si(100)by Ultraclean Low-Pressure CVD2007

    • Author(s)
      H. Tanno
    • Organizer
      3rd Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20071108-09
  • [Presentation] Characterization of Temperature-Dependent Hole Resonant Tunneling Properties with High Ge Fraction(x>0.4)Si/Strained Si_<1-x>Ge_x/Si(100)Heterostructure2007

    • Author(s)
      T. Seo
    • Organizer
      3rd Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20071108-09
  • [Presentation] Strain Control of Si and Si_<1-x>Ge_x Layers in the Si/Si_<1-x>Ge_x/Si Heterostructures by Stripe-Shape Patterning for Future Si-Based Devices(Invited Paper)2007

    • Author(s)
      J. Murota
    • Organizer
      Symp. E9: ULSI Process Integration5(212th Meeting of the Electrochem. Soc.)
    • Place of Presentation
      Washington, DC, USA
    • Year and Date
      20071007-12
  • [Presentation] Fabrication of Hole Resonant Tunneling Diodes with Nanometer Order Heterostructures of Si/Strained Si_<1-x>Ge_x Epitaxially Grown on Si(100)(Invited Paper)2007

    • Author(s)
      M. Sakuraba
    • Organizer
      Symp. E9: ULSI Process Integration5(212th Meeting of the Electrochem. Soc.)
    • Place of Presentation
      Washington, DC, USA
    • Year and Date
      20071007-12
  • [Presentation] Reliability and Instability of a SiGe/Si-Hetero-Interface in Hetero-Channel MOSFETs(Invited Paper)2007

    • Author(s)
      T. Tsuchiya
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] Impact of Ge Fraction Modulation upon Electrical Characteristics of Hole Resonant Tunneling Diodes with Si/Strained Si<1-x>Ge_x/Si(100)Heterostructure2007

    • Author(s)
      T. Seo
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] Structural Change of Atomic-Order Nitride Formed on Si_<1-x>Ge_x(100)and Ge(100)by Heat Treatment2007

    • Author(s)
      N. Akiyama
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] Si Epitaxial Growth on Self-Limitedly B Adsorbed Si_<1-x>Ge_x(100)by Ultraclean Low-Pressure CVD System2007

    • Author(s)
      K. Ishibashi
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] Local Strain in Si/Si_<0.6>Ge_<0.4>/Si(100)Heterostructures by Stripe-Shape Patterning2007

    • Author(s)
      J. Uhm
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] High Ge Fraction Intrinsic SiGe-Heterochannel MOSFETs with Embedded SiGe Source/Drain Electrode Formed by In-Situ Doped Selective CVD Epitaxial Growth2007

    • Author(s)
      S. Takehiro
    • Organizer
      5th Int. Conf. Silicon Epitaxy and Heterostructures(ICSI-5)
    • Place of Presentation
      Marseille, France
    • Year and Date
      20070520-24
  • [Presentation] Atomically Controlled Technology for Group IV Semiconductors(Invited Paper)2007

    • Author(s)
      J. Murota
    • Organizer
      4th Int. Workshop on Nanoscale Semiconductor Devices
    • Place of Presentation
      Jeju,Korea
    • Year and Date
      20070405-06

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Published: 2010-02-04   Modified: 2016-04-21  

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