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2008 Fiscal Year Annual Research Report

次元性を制御したナローギャップ半導体の機能デバイス化

Research Project

Project/Area Number 19206067
Research InstitutionTohoku University

Principal Investigator

梶谷 剛  Tohoku University, 大学院・工学研究科, 教授 (80134039)

Co-Investigator(Kenkyū-buntansha) 藤原 巧  東北大学, 大学院・工学研究科, 教授 (10278393)
宮崎 譲  東北大学, 大学院・工学研究科, 准教授 (40261606)
林 慶  東北大学, 大学院・工学研究科, 助教 (70360625)
湯蓋 邦夫  東北大学, 金属材料研究所, 助教 (00302208)
Keywords半導体 / 熱電物性 / ナローギャップ / 合成 / 結晶構造 / 中性子回折 / インターカレーション
Research Abstract

本年度成果を得た研究は次の通りである。
1. Delafossite型構造を持った酸化物半導体の開発
林等はCuCrO_2化合物にMgなどをドーピングし、熱電性を詳細に研究した。また、中性子回折実験を行って低温における磁気構造も研究した。
2. ドーピングしたC0系三角格子酸化物半導体の結晶構造の精密解析
湯蓋等による研究であり、高分解能電子顕微鏡を用いてBiを含むCa-121と命名されているC0O_2三角格子酸化物半導体における長周期構造を研究し、この化合物が3つの岩塩構造格子と5つのC0O_2底面心格子を基本格子単位としたDiscommensurate構造を持つことを発見した。
3. 酸化物半導体の焼結助剤による焼結密度向上
酸化物半導体の緻密なバルク体を作ることが実用上重要であり、適切な焼結助剤により、焼結密度を上げることに成功した。
4. C0O2三角格子化合物へのインターカレーション
Na_xC0O_2(0.3≦x≦0.8)をハロゲン還元法で作製し、結晶構造と物理的性質を研究した.X=0.58付近に√<7>a×√<7>a相を発見した。
5. MnSi_x(x〓1.7)系半導体へのドーピング効果
ドーピングをした場合の長周期変調構造の変化を詳しく調べた。

  • Research Products

    (34 results)

All 2009 2008

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (26 results)

  • [Journal Article] Effect of Doping on Thermoelectric Properties of Delafossite-Type Oxide CuCrO_22008

    • Author(s)
      K. Hayashi
    • Journal Title

      Jpn. J. Appl. Phys 47

      Pages: 59-63

    • Peer Reviewed
  • [Journal Article] High-Resolution Electron Micrsoscopy Study of [(Ca, Bi)_2C0O_3]_<0.62>CoO_22008

    • Author(s)
      K. Yubuta
    • Journal Title

      J. Phys. Soc. Jpn. 77

      Pages: 094603-1, 097603-6

    • Peer Reviewed
  • [Journal Article] High temperature thermoelectric Properties of Ca_<1-x>Bi_xMn<1-y>V_yO_<3-δ>(0≦x=y≦0.08)2008

    • Author(s)
      X. Y. Huang
    • Journal Title

      Solid State Comm 145

      Pages: 132-136

    • Peer Reviewed
  • [Journal Article] Triclinic Crystal Structure of[(Bi_<1-x>Co_x)2(Sr_<1-y>Bi_y)_2O_<4+δ>]_p[CoO_2]_2 with p〓1.05 and δ〓0.72008

    • Author(s)
      T. Kajitani
    • Journal Title

      Proceedings of 26th International Conference on Thermoelectrics (ICT2007) Jeju, Korea, June 3-5, 2007 (CD-ROM)

      Pages: Oxides_03, 1-3

    • Peer Reviewed
  • [Journal Article] Preparation, Crystal Structure and Thermoelectric Properties of La_<2-2x>Ca_<1+2x>Mn_2O_72008

    • Author(s)
      Y. Miyazaki
    • Journal Title

      Proceedings of 26th International Conference on Thermoelectrics (ICT2007) Jeju, Korea, June 3-5, 2007. (CD-ROM)

      Pages: Oxides_08, 1-3

    • Peer Reviewed
  • [Journal Article] High temperature thermoelectric properties of delafossite-type oxides CuFe_<0.98>M_<0.02>O_2 (M=Mg, Zn, Ni, Co, Mn, or Ti)2008

    • Author(s)
      T. Nozaki
    • Journal Title

      Proceedings of 26th International Conference on Thermoelectrics (ICT2007) Jeju, Korea, June 3-5, 2007 (CD-ROM)

      Pages: Oxides_17, 1-3

    • Peer Reviewed
  • [Journal Article] Disorder-Order Transitions in Na_xCoO_2(x〓0.58)2008

    • Author(s)
      D. Igarashi
    • Journal Title

      Phys. Rev. B 78

      Pages: 184112-1, 184112-6

    • Peer Reviewed
  • [Journal Article] Modulated Crystal Structure of Chimney-Ladder Type Higher Manganese Silicide MnSi_γ(γ〓1.74)2008

    • Author(s)
      Y. Miyazaki
    • Journal Title

      Phys. Rev. B 78

      Pages: 214104-1, 214104-8

    • Peer Reviewed
  • [Presentation] hermoelectric properties of Al/Mg doped ZnO thin films on a-sapphire substrate2009

    • Author(s)
      Y. Kanomata
    • Organizer
      4^<th> Int. Symp. Med. Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] Thermoelectric properties of Al/Mg doped ZnO thin films on a-sapphire substrate2009

    • Author(s)
      F. Kawashima
    • Organizer
      4^<th> Int. Symp. Med. Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] hermoelectric properties of sputtered Zn_<1-x>Al_xO_42009

    • Author(s)
      M. Nishiguchi
    • Organizer
      4^<th> Int. Symp. Med. Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] High temperature thermoelectric properties of Ni-ferrite, Ni_xFe_<3-x>O_42009

    • Author(s)
      R. Fukatsu
    • Organizer
      4^<th> Int. Symp. Med.Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] Surface treatment effect on thermoelectric properties of delafossite-typeoxide CuFe_<0.98>Ni_<0.02>O_22009

    • Author(s)
      T. Nozaki
    • Organizer
      4^<th> Int. Symp. Med. Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] Rubbing effect on surface morphology and thermoelectric performance of TTF-TCNQ thin films2009

    • Author(s)
      E. Tamayo
    • Organizer
      4^<th> Int. Symp. Med. Bio- & Nano-Elec
    • Place of Presentation
      Sendai
    • Year and Date
      20090305-06
  • [Presentation] Mo置換したペロブスカイト型CaMn_<1-x>Mo_xO_3の高温熱電特性2009

    • Author(s)
      川島史也
    • Organizer
      第56回応用物理学関連講演会
    • Place of Presentation
      筑波大学、つくば市
    • Year and Date
      2009-03-31
  • [Presentation] a面サファイア基板上に成膜したc軸配向Zn_<0.98>Al_<0.02>薄膜の熱電性能2009

    • Author(s)
      鹿又靖裕
    • Organizer
      第56回応用物理学関連講演会
    • Place of Presentation
      筑波大学、つくば市
    • Year and Date
      2009-03-31
  • [Presentation] [(Ca, Bi)_2CoO_3]_<0.62>CoO_2の高分解能電子顕微鏡観察2009

    • Author(s)
      湯蓋邦夫
    • Organizer
      第56回応用物理学関連講演会
    • Place of Presentation
      筑波大学、つくば市
    • Year and Date
      2009-03-31
  • [Presentation] Chimney-ladder型化合物(Mn_<1-x>Fe_x)Si_γ(γ〜1.7)2009

    • Author(s)
      齋藤祥二
    • Organizer
      第56回応用物理学関連講演会
    • Place of Presentation
      筑波大学、つくば市
    • Year and Date
      2009-03-31
  • [Presentation] High temperature thermoelectric properties of layered oxide Ca_<2-x>Bi_xMnO_42008

    • Author(s)
      F. Kawashima
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      20080805-07
  • [Presentation] (3+1)-Dimensional superspace group approach to the crystal structure of chimney-ladder compound MnSi_γ(γ〓1.74)2008

    • Author(s)
      Y. Miyazaki
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      20080805-07
  • [Presentation] Surface Morphology and Thermoelectric Properties of Copper Phthalocyanine Thin Films on Si(001)2008

    • Author(s)
      K. Hayashi
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-13
  • [Presentation] (3+1)-Dimensionai Superspace Group Approach to the Crystal Structure of Higher Manganese Silicid6 MnSi_γ2008

    • Author(s)
      Y. Miyazaki
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-11
  • [Presentation] Crystal Structure of K_xRhO_2 Single Crystal2008

    • Author(s)
      D. Igarashi
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-11
  • [Presentation] High Temperature Thermoelectric Properties of Double-Doped CuFeO_22008

    • Author(s)
      T. Nozaki
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-10
  • [Presentation] (Mn_<1-x>Fe_x)Si_γの合成と熱電特性2008

    • Author(s)
      齋藤祥二
    • Organizer
      第63回応用物学会東北支部学術講演会
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2008-12-04
  • [Presentation] Na_xCoO_2におけるNa規則配列転移温度と組成の関係2008

    • Author(s)
      五十嵐大
    • Organizer
      第63回応用物学会東北支部学術講演会
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2008-12-04
  • [Presentation] Ca_2Mn_<1-x>Mo_xO_4の合成と熱電特性2008

    • Author(s)
      川島史也
    • Organizer
      第63回応用物学会東北支部学術講演会
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2008-12-04
  • [Presentation] 層状酸化物Ca_<1.9-x>Bi_<0.1>Sr_xMnO_4の高温熱電特性2008

    • Author(s)
      川島史也
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学、春日井市
    • Year and Date
      2008-09-03
  • [Presentation] n型透明半導体AgInO_2の熱電特性に対するSn添加効果2008

    • Author(s)
      佐藤弘典
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学、春日井市
    • Year and Date
      2008-09-03
  • [Presentation] 超空間群を用いたChimney-Ladder型化合物MnSi_γ(γ〓1.74)2008

    • Author(s)
      宮崎譲
    • Organizer
      第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学、春日井市
    • Year and Date
      2008-09-03
  • [Presentation] Electric structure and transport property of delafossite-type oxide CuFeO_2 system2008

    • Author(s)
      T. Nozaki
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      2008-08-07
  • [Presentation] Excess oxygen in rock-salt-type layers of misfit-layered Bi-based oxides2008

    • Author(s)
      K. Yubuta
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      2008-08-07
  • [Presentation] Effect of Na atom ordering on the physical properties in Na0.58Co022008

    • Author(s)
      D. Igarashi
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      2008-08-05
  • [Presentation] Discommensuration of doped Co-1212008

    • Author(s)
      T. Kajitani
    • Organizer
      27^<th> International Conference on Thermoelectrics ICT2008
    • Place of Presentation
      Corvallis, Oregon, USA
    • Year and Date
      2008-08-05

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Published: 2010-06-11   Modified: 2016-04-21  

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