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2009 Fiscal Year Final Research Report

Development of novel oxide protonics materials based on low-temperature fabrication processes

Research Project

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Project/Area Number 19206080
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionThe University of Tokyo

Principal Investigator

YAMAGUCHI Shu  The University of Tokyo, 大学院・工学系研究科, 教授 (10182437)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Kiyoshi  物材機構, 燃料電池センター, 主任研究員 (90357020)
OYAMA Yukiko  東京大学, 大学院・工学系研究科, 助教 (00345373)
TANAKA Kazuhiko  東京大学, 大学院・工学系研究科, 技術専門職員 (20456156)
MIYOSHI Shogo  東京大学, 大学院・工学系研究科, 助教 (30398094)
Project Period (FY) 2007 – 2009
Keywords低温合成 / プロトン伝導 / 酸化物プロトニクス / 反応性スパッタ / ゾル-ゲル法
Research Abstract

In order to develop a new class of proton-conducting oxide materials, investigations have been made on low-temperature fabrication process, which avoids loss of protonic carrier during high-temperature treatment for synthesis. New proton-conducting materials have been developed, which retain appreciable amount of protons in their bulk structure incorporated during synthesis. In addition, a feasibility has been demonstrated for development of new proton-conducting materials based on nano-structured ceramics which make use of their weakly bonded grain boundary as a possible conduction path.

  • Research Products

    (38 results)

All 2010 2009 2008 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (33 results) Remarks (1 results)

  • [Journal Article] ヘテロ界面イオン物性のナノスケール制御:ナノイオニクスの新展開2010

    • Author(s)
      山口周
    • Journal Title

      ふぇらむ 15巻

      Pages: 776-784

    • Peer Reviewed
  • [Journal Article] Powder neutron diffraction of La-apatite under low temperature2009

    • Author(s)
      Y.Matsushita, K.Kobayashi, S.Miyoshi, S.Yamaguchi, et.al.
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section A : Accelerators, Spectrometers, Detectors and Associated Equipment Vol.600

      Pages: 319-321

    • Peer Reviewed
  • [Journal Article] Water-based sol-gel synthesis and crystal structure refinement of lanthanum silicate apatite2008

    • Author(s)
      K.Kobayashi, S.Miyoshi, S.Yamaguchi, et.al.
    • Journal Title

      Solid State Ionics Vol.179

      Pages: 2209-2215

    • Peer Reviewed
  • [Journal Article] Structural study and proton transport of bulk nanograined Y-doped BaZrO_3 oxide protonics materials2008

    • Author(s)
      R.B.Cervera, S.Miyoshi, K.Kobayashi, S.Yamaguchi
    • Journal Title

      Solid State Ionics Vol.179

      Pages: 236-242

    • Peer Reviewed
  • [Presentation] ジルコニアナノ構造体における表面プロトン伝導機構2010

    • Author(s)
      赤尾泰秋, 三好正悟, 桑田直明, 河村純一, 尾山由紀子, 山口周
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-26
  • [Presentation] ペロブスカイト型酸化物BaPrO_3における電子構造・電気輸送特性と反応活性2010

    • Author(s)
      菊池健夫, 三好正悟, 三室伸, 尾山由紀子, 樋口透, 山口周
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-24
  • [Presentation] ナノイオニクス概論:ナノイオニクスが描く夢の技術2010

    • Author(s)
      山口周
    • Organizer
      第46回学際領域セミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-11-05
  • [Presentation] Water Uptake and Conduction Property of Nano-Grained Fluorite-Type Oxides2010

    • Author(s)
      赤尾泰秋, 三好正悟, 桑田直明, 河村純一, 山口周
    • Organizer
      Materials Science & Technology 2010 Conference & Exhibition(MS&T'10)
    • Place of Presentation
      ヒューストン
    • Year and Date
      2010-10-20
  • [Presentation] Electrical Transport Properties and Strong Correlations of Donor/Acceptor Doped BaPrO_32010

    • Author(s)
      菊池健夫, 三好正悟, 三室伸, 尾山由紀子, 樋口透, 山口周
    • Organizer
      Materials Science & Technology 2010 Conference & Exhibition(MS&T'10)
    • Place of Presentation
      ヒューストン
    • Year and Date
      2010-10-19
  • [Presentation] BaPrO_3の強相関性電荷移動現象と電気化学特性2010

    • Author(s)
      菊池健夫, 三好正悟, 三室伸, 尾山由紀子, 樋口透, 山口周
    • Organizer
      第6回固体イオニクスセミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-09-20
  • [Presentation] Water uptake and conduction property of nano-grained yttria-doped zirconia2010

    • Author(s)
      赤尾泰秋, 三好正悟, 桑田直明, 河村純一, 尾山由紀子, 山口周
    • Organizer
      The 15^<th> International Conference on Solid State Protonic Conductors (SSPC-15)
    • Place of Presentation
      サンタバーバラ
    • Year and Date
      2010-08-19
  • [Presentation] Oxide Protonics : Electronic Structure and Acid Base Reactions in Bulk and Surface2010

    • Author(s)
      山口周
    • Organizer
      The 15^<th> International Conference on Solid State Protonic Conductors (SSPC-15)
    • Place of Presentation
      サンタバーバラ
    • Year and Date
      2010-08-16
  • [Presentation] Correlated Charge Transport and RedOx Buffer Effect by Hole-Electron Pair via Auto-Ionization2010

    • Author(s)
      T.Kikuchi, M.Tamaru, S.Miyoshi, T.Higuchi, J.Guo, S.Yamaguchi
    • Organizer
      in Perovskite Oxide with Multivalent Cation on B-Site
    • Place of Presentation
      バンクーバー
    • Year and Date
      2010-04-27
  • [Presentation] Strong Correlation in Transport Properties Between Holes/Protons and B-site Multivalent Cations in Perovskite Oxides for SOFC Materials2010

    • Author(s)
      T.Kikuchi, M.Tamaru, T.Higuchi, J.Guo, S.Yamaguchi
    • Organizer
      XAS and RPES/RIXS, 2010 MRS Spring Meeting
    • Place of Presentation
      サンフランシスコ
    • Year and Date
      2010-04-06
  • [Presentation] Ba(Zr,Pr)O_3系酸化物の欠陥・電子構造と電気化学特性2010

    • Author(s)
      田丸奏, 三好正悟, 尾山由紀子, 樋口透, 山口周
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-30
  • [Presentation] 蛍石型酸化物ナノ粒子バルク体の特異な水吸着とプロトン伝導2010

    • Author(s)
      赤尾泰秋, Rinlee Butch Cervera, 三好正悟, 尾山由紀子, 河村純一, 山口周, et.al.
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-29
  • [Presentation] 固体酸化物半導体BaPrO_3の電気輸送特性と強相関性2010

    • Author(s)
      菊池健夫, 三好正悟, 三室伸, 田丸奏, 尾山由紀子, 樋口透, 山口周
    • Organizer
      第5回固体イオニクスセミナー
    • Place of Presentation
      宮城
    • Year and Date
      2010-03-05
  • [Presentation] 金属原子包接型固体酸化物半導体薄膜の光吸収特性2010

    • Author(s)
      伊藤崇広, 尾山由紀子, 三好正悟, 山口周
    • Organizer
      第5回固体イオニクスセミナー
    • Place of Presentation
      宮城
    • Year and Date
      2010-03-05
  • [Presentation] Pt-(Ce,Gd)O_2系ナノ構造体の酸化還元挙動と電気化学特性2009

    • Author(s)
      吉村憲治, 三好正悟, 尾山由紀子, 丹司敬義, 八木健彦, 山口周
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪
    • Year and Date
      2009-12-07
  • [Presentation] BaO-ZrO_2-YO_<1.5>系における相関係の解明と微細構造解析2009

    • Author(s)
      尾山由紀子, 鶴井隆雄, 三好正悟, 山口周
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪
    • Year and Date
      2009-12-07
  • [Presentation] Novel Proton Conductivity in Hydrated Nano- Grained Zirconia and Ceria2009

    • Author(s)
      山口周
    • Organizer
      The 17^<th> Conference on Solid State Ionics
    • Place of Presentation
      トロント
    • Year and Date
      2009-06-30
  • [Presentation] ゲル前駆体合成法によるオキシアパタイト型ランタンシリケートの反応生成過程2009

    • Author(s)
      小林清, 西村睦, 三好正悟, 尾山由紀子, 山口周
    • Organizer
      電気化学会第76大会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-30
  • [Presentation] アクセプターおよびドナーをドープしたBaPrO_3の電気輸送特性と電子構造2009

    • Author(s)
      三好正悟, 菊池健夫, 三室伸, 尾山由紀子, 樋口透, 山口周
    • Organizer
      電気化学会第76大会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-30
  • [Presentation] 混合原子価のPrをドープしたBaZrO_3の電気伝導特性と欠陥・電子構造2009

    • Author(s)
      田丸奏, 三好正悟, 尾山由紀子, 樋口透, 山口周
    • Organizer
      電気化学会第76大会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-30
  • [Presentation] Ionic/ Electronic Transport Properties and Defect/Electronic Structure of Ba(Zr, Pr)O_32009

    • Author(s)
      田丸奏, 三好正悟, 尾山由紀子, 樋口透, 山口周
    • Organizer
      Engineering Conf.Int.(ECI), Nonstoichiometric Compounds
    • Place of Presentation
      済州島
    • Year and Date
      2009-03-10
  • [Presentation] Redox Reaction and Electrochemical Characteristic of Pt-(Ce,Gd)O_2 Mixedsystem2009

    • Author(s)
      K.Yoshimura, S.Miyoshi, Y.Oyama, S.Yamaguchi
    • Organizer
      Engineering Conf.Int.(ECI), Nonstoichiometric Compounds
    • Place of Presentation
      済州島
    • Year and Date
      2009-03-10
  • [Presentation] YドープBaZrO_3相の相安定性と結晶多形体2008

    • Author(s)
      尾山由紀子,李新宇, R.B.Cervera, 三好正悟, 山口周
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-04
  • [Presentation] BaScO_2(OH) as a new class of nanograined proton conducting solid electrolyte2008

    • Author(s)
      R.B.Cervera, 尾山由紀子, 三好正悟, 小林清, 八木健彦, 山口周
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-03
  • [Presentation] Bulk-Nanograined BaScO_2(OH) as a New Class of Oxide Protonics Materials2008

    • Author(s)
      R.B.Cervera, Y.Oyama, S.Miyoshi, K.Kobayashi, S. Yamaguchi, et.al.
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME 2008)
    • Place of Presentation
      ホノルル
    • Year and Date
      2008-10-16
  • [Presentation] Water-based Soft Chemical Synthesis of Apatite Type Lanthanum Silicate Powder in Nano- scale2008

    • Author(s)
      K.Kobayashi, S.Miyoshi, Y.Oyama, S.Yamaguchi, M.Nishimura
    • Organizer
      Pacific Rim Meeting on Electro- chemical and Solid-State Science (PRiME 2008)
    • Place of Presentation
      ホノルル
    • Year and Date
      2008-10-15
  • [Presentation] Grain Boundary Protonic Conduction in Nanograined Oxides2008

    • Author(s)
      R.B.Cervera, Y.Oyama, S.Miyoshi, S.Yamaguchi, et.al.
    • Organizer
      The 14^<th> Int.Conf.on Solid State Protonic Conductors (SSPC-14)
    • Place of Presentation
      京都
    • Year and Date
      2008-09-11
  • [Presentation] Proton Dis- solution and Transport Properties of Oxy- and Hydroxy- Apatites2008

    • Author(s)
      H.Yoshida, K.Kobayashi, S.Miyoshi, Y.Oyama, S.Yamaguchi, et.al.
    • Organizer
      The 14^<th> Int.Conf.on Solid State Protonic Conductors(SSPC-14)
    • Place of Presentation
      京都
    • Year and Date
      2008-09-09
  • [Presentation] Site Perco- lation of Hole and Proton Strongly Correlated with Pr^<3+> in Pr-Doped BaZr O_32008

    • Author(s)
      M.Tamaru, R.B.Cervera, Y.Oyama, S.Miyoshi, S.Yamaguchi, et.al.
    • Organizer
      The 14^<th> Int.Conf.on Solid State Protonic Conductors (SSPC-14)
    • Place of Presentation
      京都
    • Year and Date
      2008-09-09
  • [Presentation] Stability and Transformation of Ba_3 Zr_2O_<8.5> Phase2008

    • Author(s)
      尾山由紀子, 李新宇, 三好正悟, 山口周
    • Organizer
      The 14^<th> Int.Conf.on Solid State Protonic Conductors (SSPC-14)
    • Place of Presentation
      京都
    • Year and Date
      2008-09-08
  • [Presentation] Protonic Conduction in Nano-Grained Fluorite Oxides of Y-Doped ZrO_2 and Yb-Doped CeO_22008

    • Author(s)
      Y.Akao, S.Miyoshi, Y.Oyama, T.Yagi, S.Yamaguchi, et.al.
    • Organizer
      The 14^<th> Int.Conf.on Solid State Protonic Conductors (SSPC-14)
    • Place of Presentation
      京都
    • Year and Date
      2008-09-08
  • [Presentation] 水溶液中からのアノード分極による酸化セリウム薄膜合成2008

    • Author(s)
      川井章浩, 尾山由紀子, 三好正悟, 山口周
    • Organizer
      資源・素材2008春季大会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
  • [Presentation] Protonic transport of BaZrO_3-BaScO_3 nanograined solid electrolytes2008

    • Author(s)
      R.B.Cervera, Y.Oyama, S.Miyoshi, K.Kobayashi, T.Yagi, S. Yamaguchi
    • Organizer
      電気化学会第75大会
    • Place of Presentation
      山梨
    • Year and Date
      2008-03-20
  • [Remarks] ホームページ等

    • URL

      http://www.ionics.t.u-tokyo.ac.jp/

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Published: 2012-01-26   Modified: 2016-04-21  

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