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2009 Fiscal Year Final Research Report

Electrolysis in solid particles disperse water systems directed toward environmental stress O processes

Research Project

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Project/Area Number 19310053
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionOkayama University

Principal Investigator

TANAKA Hideo  Okayama University, 大学院・自然科学研究科, 教授 (60032950)

Co-Investigator(Kenkyū-buntansha) KUROHOSHI Manabu  岡山大学, 大学院・自然科学研究科, 准教授 (30242316)
MITSUDO Koichi  岡山大学, 大学院・自然科学研究科, 助教 (40379714)
Project Period (FY) 2007 – 2009
Keywords環境負荷低減技術 / 環境負荷O合成プロセス / 固体粒子分散-水系電解 / 水系電解 / シリカゲル / ポリマー粒子 / ナノエマルジョン
Research Abstract

Electrosyntheses in disperse systems with aqueous solutions of mediator (I) as disperse media and substrates and mediator (II)-adsorbed and/or-immobilized solid particles (silica gel, polymer particles, and active carbon) as disperse phases have been intensively investigated, thereby, offering totally closed electrolysis systems without consumption of any chemicals.

  • Research Products

    (11 results)

All 2010 2009 2007 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Design of Redox-Mediatory Systems for Electro-Organic Synthesis2009

    • Author(s)
      H. Tanaka, M. Kuroboshi, K. Mitsudo
    • Journal Title

      Electrochemistry Vol.77

      Pages: 1002-1009

    • Peer Reviewed
  • [Journal Article] 電極での電子移動を駆動力とするクリーンな水中酸化法の開発と応用2009

    • Author(s)
      田中秀雄、黒星学
    • Journal Title

      科学と工業 Vol.83、No.5

      Pages: 206-214

    • Peer Reviewed
  • [Journal Article] Electrooxidation of Alcohols in N-Oxyl-Immobilized Silica Gel/Water Disperse System: Approach to Totally Closed System2009

    • Author(s)
      M. Kuroboshi, K. Goto, H. Tanaka
    • Journal Title

      SYNTHESIS No.6

      Pages: 903-908

    • Peer Reviewed
  • [Journal Article] Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/TEMPO Double-Mediatory Electrooxidative Wacker-Type Reaction2009

    • Author(s)
      K. Mitsudo, T. Kaide, E. Nakamoto, K. Yoshida, H. Tanaka
    • Journal Title

      Journal of the American Chemical Society Vol.77

      Pages: 1002-1009

    • Peer Reviewed
  • [Journal Article] Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water: halide-free oxidation directed towards a totally closed system2007

    • Author(s)
      K. Mitsudo, H. Kumagai, F. Takabatake, J. Kubota, H. Tanaka
    • Journal Title

      Tetrahedron Letter Vol.48

      Pages: 8994-8997

    • Peer Reviewed
  • [Journal Article] Electroorganic Synthesis in Oil-in-Water Nanoemulsion: TEMPO-Mediated Electrooxidation of Amphiphilic Alcohols in Water2007

    • Author(s)
      T. Yoshida, M. Kuroboshi, J. Oshitani, K. Goto, H. Tanaka
    • Journal Title

      SYNLETT No.17

      Pages: 2691-2694

    • Peer Reviewed
  • [Presentation] Amphiphilic Viologen in Water: Electro-generation of Organic Reductants in Water and Application to Reductive Coupling of Ar-X2010

    • Author(s)
      T. Yamamoto, M. Kuroboshi, H. Tanaka
    • Organizer
      217th ECS Meeting
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-26
  • [Presentation] Ni-Catalyzed Electroreductive Dehalogenation of Aryl Halides on an Activated Carbon Adsorbing Layer2009

    • Author(s)
      M. Kuroboshi, N. Hara, H. Tanaka
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      20091004-20091009
  • [Presentation] ビオロゲン誘導体の水中での電解還元による有機還元剤の調製と反応2009

    • Author(s)
      黒星学、山本貴嗣、青木孝之、田中秀雄
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都大学
    • Year and Date
      20090329-20090331
  • [Presentation] Pd/TEMPO複合メディエータ系を用いたアリールボロン酸及びアリールボロン酸エステルの電解ホモカップリング反応2009

    • Author(s)
      家現大輔、白神卓也、光藤耕一、田中秀雄
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学、船橋
    • Year and Date
      20090327-20090330
  • [Remarks]

    • URL

      http://achem.okayama-u.ac.jp/eoc/index.html

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Published: 2011-06-18   Modified: 2012-08-07  

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