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2009 Fiscal Year Final Research Report

Synthesis and Shape Control of Gold・Silver Core Shell Nanocrystals Using Microwave-polyol Method

Research Project

  • PDF
Project/Area Number 19310064
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionKyushu University

Principal Investigator

TSUJI Masaharu  Kyushu University, 先導物質化学研究所, 教授 (30038608)

Co-Investigator(Kenkyū-buntansha) TSUJI Takeshi  九州大学, 先導物質化学研究所, 助教 (50284568)
Co-Investigator(Renkei-kenkyūsha) AGO Hiroki  九州大学, 先導物質化学研究所, 准教授 (10356355)
Project Period (FY) 2007 – 2009
Keywordsナノ材料 / マイクロ波加熱 / 結晶成長 / 複合金属材料 / コアシェル構造
Research Abstract

Syntheses of various shapes of Au@Ag core-shell particles with FCC structures were studied using microwave-polyol method. We succeeded in the shape selective syntheses of new Au@Ag nanocrystals with {100} Ag shells using DMF as solvent and reductant. New Au@Ag and Au/Ag@Ag particles were also prepared using icosahedral and branched Au cores and their growth mechanisms were clarified on the basis of TEM-EDS and SEM observations.

  • Research Products

    (54 results)

All 2010 2009 2008 2007 Other

All Journal Article (28 results) (of which Peer Reviewed: 27 results) Presentation (21 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Synthesis of Ag@Cu core shell nanoparticles in high yield using a polyol method2010

    • Author(s)
      M. Tsuji, S. Hikino, 他2名
    • Journal Title

      Chem. Lett. 39

      Pages: 334-336

    • Peer Reviewed
  • [Journal Article] Stepwise growth of decahedral and icosahedral silver nanocrystals in DMF2010

    • Author(s)
      M. Tsuji, M. Ogino, 他5名
    • Journal Title

      Crystal Growth & Design 10

      Pages: 296-301

    • Peer Reviewed
  • [Journal Article] Shape evolution of octahedral and triangular-plate-like silver nanocrystals from cubic and right bipyramidal seeds in DMF2009

    • Author(s)
      M. Tsuji, Y. Maeda, S. Hikino, 他6名
    • Journal Title

      Crystal Growth & Design 9

      Pages: 4700-4705

    • Peer Reviewed
  • [Journal Article] Roles of chloride anions in the shape evolution of anisotropic silver nanostructures in PVP-assisted polyol process2009

    • Author(s)
      X.-L. Tang, M. Tsuji, 他2名
    • Journal Title

      Bull. Chem. Soc. Jpn. 82

      Pages: 1304-1312

    • Peer Reviewed
  • [Journal Article] Synthesis of bicompartmental Ag/Cu nanoparticles using a two-step polyol process2009

    • Author(s)
      M. Tsuji, S. Hikino, 他2名
    • Journal Title

      Chem. Lett. 38

      Pages: 860-861

    • Peer Reviewed
  • [Journal Article] Effects of bubbling N2 or O2 gas in syntheses of gold nanocrystals using a polyol method2009

    • Author(s)
      M. Tsuji, 他2名
    • Journal Title

      Chem. Lett. 38

      Pages: 618-619

    • Peer Reviewed
  • [Journal Article] Shape-controlled preparation of gold nanocrystals using a microwave-polyol method2009

    • Author(s)
      M. Tsuji, D. Ueyama, 他2名
    • Journal Title

      Chem. Lett. 38

      Pages: 478-479

    • Peer Reviewed
  • [Journal Article] Preparation of Cu@Ag core-shell nanoparticles using a two-step polyol process under bubbling of N2 gas2009

    • Author(s)
      M. Tsuji, 他3名
    • Journal Title

      Chem. Lett. 38

      Pages: 518-519

    • Peer Reviewed
  • [Journal Article] Rapid and high-yield synthesis of silver nanowires using air-assisted polyol method with chloride ions2009

    • Author(s)
      X.-L. Tang, M. Tsuji, 他4名
    • Journal Title

      Colloids and Surfaces A: Physicochem. Eng. Aspects 338

      Pages: 33-39

    • Peer Reviewed
  • [Journal Article] One-step preparation of superlattices and nanocrystals using laser ablation2009

    • Author(s)
      M. Tsuji, M. Tsuji (5番目), 他3名
    • Journal Title

      J. Appl. Phys. 106

      Pages: 054313

    • Peer Reviewed
  • [Journal Article] Preparation of nano-sized functional materials using laser ablation in liquids2009

    • Author(s)
      T. Tsuji, M. Tsuji (4番目), 他5名
    • Journal Title

      Appl. Surf. Sci. 255

      Pages: 9626-9629

    • Peer Reviewed
  • [Journal Article] Laser-induced silver nanocrystal formation in polyvinylpyrrolidone solutions2009

    • Author(s)
      T. Tsuji, T. Mizuki, S. Oozono, M. Tsuji
    • Journal Title

      Journal of Photochemistry and Photobiology A Chemistry 206

      Pages: 134-139

    • Peer Reviewed
  • [Journal Article] DMF還元溶媒を用いた新規形状金コア銀シェルナノ微結晶の合成2009

    • Author(s)
      松尾亮一、辻正治
    • Journal Title

      ナノ学会会報 8

      Pages: 57-63

    • Peer Reviewed
  • [Journal Article] Role of chloride ions in the formation of Au@Ag Core-shell crystal structures by using a microwave-polyol method2009

    • Author(s)
      M. Tsuji, M. Nishio, P. Jiang, 他5名
    • Journal Title

      Colloids & Surf. A: Physicochem. Eng. Aspects 317

      Pages: 247-255

    • Peer Reviewed
  • [Journal Article] Crystal structures and growth mechanism of Au@Ag core-shell nanoparticles prepared by microwave-polyol method2008

    • Author(s)
      M. Tsuji, N. Miyamae, 他3名
    • Journal Title

      Chimica Oggi/Chemistry Today 26

      Pages: 52-55

    • Peer Reviewed
  • [Journal Article] Shape-dependent evolution of Au@Ag core-shell nanocrystals by PVP-assisted N, N-dimethylformamide reduction2008

    • Author(s)
      M. Tsuji, R. Matsuo, P. Jiang, N. Miyamae, 他6名
    • Journal Title

      Crystal Growth & Design 8

      Pages: 2528-2536

  • [Journal Article] The Role of adsorption species for the formation of Ag nanostructures by a microwave-polyol route2008

    • Author(s)
      M. Tsuji, 他5名
    • Journal Title

      Bull. Chem. Soc. Jpn. 81

      Pages: 393-400

    • Peer Reviewed
  • [Journal Article] Toward to branched platinum nanoparticles by polyol reduction: A role of poly(vinylpyrrolidone) molecules2008

    • Author(s)
      M. Tsuji, P. Jiang, 他8名
    • Journal Title

      Colloids & Surf. A: Physicochem. Eng. Aspects 317

      Pages: 23-31

    • Peer Reviewed
  • [Journal Article] Roles of Pt seeds and chloride anions in the preparation of silver nanorods and nanowires by microwave-polyol method2008

    • Author(s)
      M. Tsuji, 他5名
    • Journal Title

      Colloids & Surf. A: Physicochem. Eng. Aspects 316

      Pages: 266-277

    • Peer Reviewed
  • [Journal Article] Poly(N-vinyl-2-pyrrolidone) (PVP)-capped dendritic gold nanoparticles by one-step hydrothermal route and their high SERS eff ect2008

    • Author(s)
      X.-L. Tang, M. Tsuji (4番目), 他4名
    • Journal Title

      Langmuir 24

      Pages: 1763-1768

    • Peer Reviewed
  • [Journal Article] Preparation of silver nanoparticles by laser ablation in polyvinylpyroridone solutions2008

    • Author(s)
      T. Tsuji, D.-H. Thang, M. Tsuji (6番目), 他3名
    • Journal Title

      Applied Surface Science 254

      Pages: 5224-5230

    • Peer Reviewed
  • [Journal Article] Shape selective oxidative etching and growth of single-twin plate and multiple-twin decahedral and icosahedral gold nanocrystals in the presence of Au seeds under microwave heating2007

    • Author(s)
      M. Tsuji, 他4名
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 2024-2038

    • Peer Reviewed
  • [Journal Article] Shape and size controlled synthesis of gold nanocrystals using oxidative etching by AuCl4-and Cl-anions in microwave-polyol process2007

    • Author(s)
      M. Tsuji, N. Miyamae, 他5名
    • Journal Title

      Colloids & Surf. A: Physicochem. Eng. Aspects 302

      Pages: 587-598

    • Peer Reviewed
  • [Journal Article] Synthesis and growth mechanism of bipyramid-shaped gold based Au/Ag alloys2007

    • Author(s)
      X. Zhang, M. Tsuji, 他5名
    • Journal Title

      Langmuir 23

      Pages: 6372-6376

    • Peer Reviewed
  • [Journal Article] Rapid preparation of silver nanorods and nanowires by a microwave-polyol method in the presence of Pt catalyst and polyvinylpyrrodidone2007

    • Author(s)
      M. Tsuji, K. Matsumoto, T. Tsuji, 他2名
    • Journal Title

      Crystal Growth & Design 7

      Pages: 311-320

    • Peer Reviewed
  • [Journal Article] Rapid synthesis of silver nanostructures by using microwave-polyol method with the assistance of Pt seeds and polyvinylpyrrolidone2007

    • Author(s)
      M. Tsuji, Y. Nishizawa, T. Tsuji, 他3名
    • Journal Title

      Colloids & Surf. A: Physicochem. Eng. Aspects. 293

      Pages: 185-194

    • Peer Reviewed
  • [Journal Article] Fast preparation of PtRu catalysts supported on carbon nanofibers by microwave-polyol method and their application to fuel cells2007

    • Author(s)
      M. Tsuji, T. Tsuji, 他8名
    • Journal Title

      Langmuir 23

      Pages: 387-390

    • Peer Reviewed
  • [Journal Article] Preparation of LiMn2O4 nanoparticles for Li ion secondary batteries by laser ablation in water2007

    • Author(s)
      T. Tsuji, Y. Tatsuyama, M. Tsuji, 他3名
    • Journal Title

      Materials Letters 61

      Pages: 2062-2065

    • Peer Reviewed
  • [Presentation] ポリオール法によるAu@Cuコア・シェルナノ結晶の合成2010

    • Author(s)
      山口大樹, 辻正治
    • Organizer
      第8回ナノ学会
    • Place of Presentation
      岡崎
    • Year and Date
      2010-05-15
  • [Presentation] 樹枝状Auコアを用いたAuコアAu/Ag合金コア・シェルナノ微結晶の合成2010

    • Author(s)
      辻正治, 唐新玲
    • Organizer
      第8回ナノ学会
    • Place of Presentation
      岡崎
    • Year and Date
      2010-05-14
  • [Presentation] Au@Agコア・シェルナノ微結晶の高収率合成と成長機構2010

    • Author(s)
      辻正治, 荻野政利, 松永美香
    • Organizer
      第8回ナノ学会
    • Place of Presentation
      岡崎
    • Year and Date
      2010-05-13
  • [Presentation] 導電性ペースト用Ag/Cu二元系ナノ微粒子の合成2010

    • Author(s)
      辻正治, 引野幸枝, 田辺竜一
    • Organizer
      第8回ナノ学会
    • Place of Presentation
      岡崎
    • Year and Date
      2010-05-13
  • [Presentation] Preparation of Au@Cu core shell nanocrystals by a polyol method2010

    • Author(s)
      D. Yamaguchi, M. Tsuji
    • Organizer
      第3回物質合成国際会議
    • Place of Presentation
      名大
    • Year and Date
      2010-01-07
  • [Presentation] マイクロ波加熱による銅/銀2元系ナノ微粒子の合成2009

    • Author(s)
      辻正治, 吾郷浩樹, 辻剛志
    • Organizer
      大学間連携第5回物質合成シンポジウム
    • Place of Presentation
      京大化研
    • Year and Date
      2009-11-19
  • [Presentation] マイクロ波加熱による銅/銀2元系ナノ微粒子の合成2009

    • Author(s)
      辻正治, 引野幸枝, 田辺竜一
    • Organizer
      第3回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      東京理科大
    • Year and Date
      2009-11-19
  • [Presentation] マイクロ波加熱による銀/銅複合ナノ微粒子の迅速合成2009

    • Author(s)
      辻正治, 引野幸枝
    • Organizer
      第53回放射線化学討論会
    • Place of Presentation
      福井工大
    • Year and Date
      2009-09-04
  • [Presentation] 金属ナノ微粒子の液相合成と応用2009

    • Author(s)
      辻正治
    • Organizer
      第84回ひびきのサロン
    • Place of Presentation
      北九州
    • Year and Date
      2009-09-04
  • [Presentation] マイクロ波・レーザーによる金属ナノ微粒子の合成と応用2009

    • Author(s)
      辻正治
    • Organizer
      第3回日本電磁波エネルギー応用学会
    • Place of Presentation
      東京理科大
    • Year and Date
      2009-05-29
  • [Presentation] 金属ナノ粒子の合成と触媒への応用2008

    • Author(s)
      辻正治
    • Organizer
      日本化学会九州支部第29回支部シンポジウムナノ材料が創り出す新しい機能性
    • Place of Presentation
      九大筑紫キャンパス
    • Year and Date
      2008-11-28
  • [Presentation] Shape and Size Controlled Syntheses of Metallic Nanoparticles and Their Application2008

    • Author(s)
      M. Tsuji, R. Matsuo, P. Jiang, N. Miyamae, D. Ueyama, M. Nishio
    • Organizer
      The 3rd International Carbon Festival, 7th Asian Forum on Carbon to Save the Earth
    • Place of Presentation
      全州(Korea)
    • Year and Date
      2008-11-11
  • [Presentation] 多角形金コア銀シェルナノ微結晶の合成と結晶成長に関する研究2008

    • Author(s)
      松尾亮一, 植山大輔, 西尾倫子, 宮前治広, 江鵬, 辻正治
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-25
  • [Presentation] 新規形状多角形金コア銀シェルナノ微結晶の合成と結晶成長2008

    • Author(s)
      松尾亮一, 植山大輔, 西尾倫子, 宮前治広, 江鵬, 辻正治
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-09
  • [Presentation] Shape-Dependent Evolution of Au@Ag Core-Shell Nanocrystals by PVP-Assisted N, N-dimethylformamide Reduction2008

    • Author(s)
      M. Tsuji, R. Matsuo, P. Jiang, N. Miyamae, 他6名
    • Organizer
      GCMEA 2008- MAJIC 1st (Global congress on microwave energy applications)
    • Place of Presentation
      琵琶湖
    • Year and Date
      2008-08-07
  • [Presentation] 新規形状多角形金コア銀シェルナノ微結晶の合成と結晶構造2008

    • Author(s)
      松尾亮一, 西尾倫子, 宮前治広, 辻正治
    • Organizer
      第45回化学関連支部合同九州大会
    • Place of Presentation
      福岡
    • Year and Date
      2008-07-05
  • [Presentation] DMF還元溶媒を用いた新規形状金コア銀シェルナノ微結晶の合成2008

    • Author(s)
      松尾亮一, 辻正治
    • Organizer
      第6回ナノ学会
    • Place of Presentation
      福岡
    • Year and Date
      2008-05-08
  • [Presentation] マイクロ波加熱およびオイルバス加熱による金コア銀シェルナノ微結晶の合成2008

    • Author(s)
      西尾倫子, 宮前治広, 松尾亮一, 辻正治
    • Organizer
      第6回ナノ学会
    • Place of Presentation
      福岡
    • Year and Date
      2008-05-08
  • [Presentation] Preparation of Au, Ag, and Au@Ag Core-shell Nanocrystals by Microwave-polyol Method2008

    • Author(s)
      M. Tsuji
    • Organizer
      第2回九大先導研・英国・東北大多元研ジョイントワークショップ
    • Place of Presentation
      仙台
    • Year and Date
      2008-03-10
  • [Presentation] マイクロ波-ポリオール法によるAu@Agコアシェルナノ微結晶の合成におけるハロゲンイオン効果2007

    • Author(s)
      西尾倫子, 宮前信広, P. Jiang, 辻正治
    • Organizer
      第1回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      大垣
    • Year and Date
      2007-09-26
  • [Presentation] Au@Agコアシェルナノ微結晶の成長に及ぼすCl-のエッチングの効果2007

    • Author(s)
      西尾倫子, 宮前治広, 辻正治
    • Organizer
      第5回ナノ学会
    • Place of Presentation
      筑波
    • Year and Date
      2007-05-21
  • [Book] Nanowires, Nicoleta Lupu (Ed.) in TEK webbook, Chapter 22010

    • Author(s)
      X.-L. Tang, M. Tsuji
    • Total Pages
      25-42
    • Publisher
      Syntheses of Silver Nanowires in Liquid Phase
  • [Book] 金属ナノ・マイクロ粒子の形状・構造制御技術, 第6章4. コア・シェル微粒子2009

    • Author(s)
      辻正治、米澤徹監修
    • Total Pages
      166-177
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://133.5.181.45/TSUJI/

  • [Patent(Industrial Property Rights)] 半球合体型複合金属ナノ粒子およびその製造方法2009

    • Inventor(s)
      辻正治、引野幸枝、佐野義之
    • Industrial Property Rights Holder
      九州大学-DIC
    • Industrial Property Number
      特許, 2009-177680
    • Filing Date
      2009-07-30
    • Acquisition Date
      2009-07-30
  • [Patent(Industrial Property Rights)] コアシェル型金属ナノ粒子の製造方法2009

    • Inventor(s)
      辻正治、引野幸枝、佐野義之
    • Industrial Property Rights Holder
      九州大学-DIC
    • Industrial Property Number
      特許,特願2009-5568
    • Filing Date
      2009-01-14
    • Acquisition Date
      2009-01-14

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Published: 2011-06-18   Modified: 2016-04-21  

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