Development of Novel Molecular Transformation Reaction and Functionalization, Based on the Stabilization of Open-Shell Molecules

2009 Fiscal Year Self-evaluation Report

• Project/Area Number: 19350021
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Hiroshima University
• Principal Investigator: ABE Manabu Hiroshima University, 大学院・理学研究科, 教授 (30273577)
• Project Period (FY): 2007 – 2010
• Keywords: 反応有機化学

Research Abstract

本研究では、開殻系一重項分子の長寿命化に基づく新しい有機化学反応の開発とその開殻系分子を機能性材料として用いる研究を精力的に行い、有機化学分野の中で新しい幹となる研究領域の構築に積極的に取り組む。

Research Products

• [Journal Article] Generation and Intermolecular Trapping of 1,2-Diaza-4-silacyclopentane-3,5-diyls in the Denitrogenation of 2,3,5,6-Tetraaza-7-silabicyclo[2.2.1]hept-2-ene : An Experimental and Computational, Study (2010)
  • Author(s): Nakamura, T., Takegami, A., Abe, M.
  • Journal Title: J.Org.Chem. 75 Pages: 1956-1960
  • Peer Reviewed
• [Journal Article] Computational Study of the Cooperative Effects of Nitrogen and Silicon Atoms on the Singlet-Triplet Energy Spacing in 1,3-Diradicals and the Reactivity of their Singlet States (2010)
  • Author(s): Nakamura, T., Gagliardi, L., Abe, M.
  • Journal Title: J.Phys.Org.Chem. Special Issue, 23 Pages: 300-307
  • Peer Reviewed
• [Journal Article] Notable Effect of an Electron-Withdrawing Group at C3 on the Selective Formation of Alkylidenecyclobutanes in the Thermal Denitrogenation of 4-Spirocyclopropane-1-Pyrazolines. Nonstatistical Dynamics Effects in the Denitrogenation Reactions (2007)
  • Author(s): Hamaguchi M., Nakaishi, M., Nagai, T., Nakamura, T., Abe, M.
  • Journal Title: J.Am.Chem.Soc. 129 Pages: 12981-12988
  • Peer Reviewed
• [Presentation] Generation of Long-lived Singlet Diradicals and Related Chemistry (2009)
  • Author(s): Abe Manabu
  • Organizer: ISNA-13 Satellite Meeting
  • Place of Presentation: Namur(Belgium)
  • Year and Date: 2009-07-27
• [Presentation] Cooperative Effect of Nitrogen and Silicon Atoms on the Singlet-Triplet Energy Spacing in 1,3-Diradicals and Reactivity of Their Singlet States (2009)
  • Author(s): Abe Manabu
  • Organizer: Gordon Research Conferences on Physical Organic Chemistry
  • Place of Presentation: New Hampsher(USA)
  • Year and Date: 2009-07-02
• [Remarks] ホームページ
  • URL: http://home.hiroshima-u.ac.jp/roc/