2010 Fiscal Year Final Research Report
Development of Novel Molecular Transformation Reaction and Functionalization, Based on the Stabilization of Open-Shell Molecules
| Project/Area Number |
19350021
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
安倍 学 Hiroshima University, 大学院・理学研究科, 教授 (30273577)
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| Project Period (FY) |
2007 – 2010
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| Keywords | 中間体 / スピン多重度 / ビラジカル / 一重項 / 光反応 / 結合様式 / 置換基効果 / 元素効果 |
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| Research Abstract |
Basic research study on reactive intermediates provides opportunities not only to create functional molecules, but also to develop methods and apparatus that analyze the character of molecules. In this study, we investigated the reactivity of largely elusive localized singlet biradicals, which had been known as putative intermediates in homolytic reactions, and succeeded to generate long-lived singlet 2,2-dialkoxy substituted 1,3-biradicals. The basic research allowed us to open the new field of chemistry.
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[Journal Article] Oxidation of archaeal peroxiredoxin involves α hypervalent sulfur intermediate.2008
Author(s)
Nakamura, Tsutomu, Yamamoto, Takahiko, 安倍学, Matsumura, Hiroyoshi, Hagihara, Yoshihisa, Goto, Tadashi, Yamaguchi, Takafumi, Inoue, Tsuyoshi
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Journal Title
Proc.Natl.Acad.Sci.U.S.A. 105(17)
Pages: 6238-6242
Peer Reviewed
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