2009 Fiscal Year Final Research Report
Development of metal complexes having active oxygen species by controlling of reaction cavity
| Project/Area Number |
19350029
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kanazawa University |
|---|
Principal Investigator |
SUZUKI Masatatsu Kanazawa University, 物質化学系, 教授 (20091390)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
FUJINAMI Shuhei 金沢大学, 物質化学系, 准教授 (10115272)
FURUTACHI Hideki 金沢大学, 物質化学系, 准教授 (40332663)
|
|---|
| Project Period (FY) |
2007 – 2009
|
| Keywords | 金属錯体化学 / 生物無機化学 / 合成化学 / 酸素活性種 / 機能モデル / 反応活性種 |
|---|
| Research Abstract |
(μ-η^2:η^2-Peroxo)dicopper(II), bis(μ-oxo)dinickel(III), and (μ-1,2-peroxo)Fe(III)_2 complexes having a variety of dinucleating ligands were prepared. The copper complexes are capable of initiating the oxidation of aliphatic C-H bonds having BDEs from ～74-～92 kcal mol^<-1>. The nickel complexes are also capable of hydroxylating the m-xylyl linker of the supporting ligands. Oxidation ability of the diiron complexes was also investigated.
|
-
-
[Journal Article] Oxidation Reactivity of a Bis(μ-oxo)- dinickel(III) Complex : Arene Hydroxylation of the Supporting Ligand.2009
Author(s)
K.Honda, J.Cho, T.Matsumoto, J.Roh, H.Furutachi, T.Tosha, M.Kubo, S.Fujinami, T.Ogura, T.Kitagawa, M.Suzuki
-
Journal Title
Angew.Chem.Int.Ed. 48
Pages: 3304-3307
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
