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2009 Fiscal Year Final Research Report

Small region XRF in-situ analysis of solid-liquid interface analysis

Research Project

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Project/Area Number 19350042
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionOsaka City University

Principal Investigator

TSUJI Kouichi  Osaka City University, 大学院・工学研究科, 教授 (30241566)

Project Period (FY) 2007 – 2009
Keywords機器分析
Research Abstract

It is very important to investigate and control solid-liquid interfaces, where various chemical reactions such as corrosions occur. In this research, the primary x-rays were introduced in the solutions through the newly developed injection-needle type collimator. The XRF produced in the solution was also measured through the needle collimator by the x-ray detector. Finally, it was confirmed that a direct XRF analysis of the surface of solid materials in the solution could be performed as well as the direct XRF analysis of the liquid-liquid interfaces.

  • Research Products

    (43 results)

All 2010 2009 2008 2007 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (16 results) Book (5 results) Remarks (1 results)

  • [Journal Article] Nondestructive elemental depth profiling of Japanese lacquerware Tamamushi-nuri by confocal 3D-XRF analysis in comparison with micro GE-XRF2009

    • Author(s)
      K. Nakano, K. Tsuji
    • Journal Title

      X-Ray Spectrom 38

      Pages: 446-450

    • Peer Reviewed
  • [Journal Article] Effects of an X-ray absorber in grazing exit micro x-ray fluorescence analysis of arsenic attached to an aqueous leaf of Cammelia hiemalis2009

    • Author(s)
      T. Awane, K. Nakamachi, K. Tsuji
    • Journal Title

      e-Journal of Surface Science and Nanotechnology 7

      Pages: 841-846

    • Peer Reviewed
  • [Journal Article] A micro x-ray fluorescence analysis method using polycapillary x-ray optics and grazing exit geometry2009

    • Author(s)
      J. Yang, K. Tsuji, X. Lin, D. Han, X. Ding
    • Journal Title

      Thin Solid Films 517

      Pages: 3357-3361

    • Peer Reviewed
  • [Journal Article] Grazing Exit Micro X-ray Fluorescence Analysis of Hazardous Metal Attached to a Plant Leaf Surface Using an X-ray Absorber Method2009

    • Author(s)
      T. Awane, S. Fukuoka, K. Nakamachi, K. Tsuji
    • Journal Title

      Anal. Chem 81

      Pages: 3356-3364

    • Peer Reviewed
  • [Journal Article] Fundamental characteristics of polycapillary x-ray optics combined with glass conical pinhole for micro x-ray fluorescence spectrometry2009

    • Author(s)
      A. Matsuda, K. Nakano, S. Komatani, S. Ohzawa, H. Uchihara, K. Tsuji
    • Journal Title

      X-Ray Spectrom 38

      Pages: 258-262

    • Peer Reviewed
  • [Journal Article] Preconcentration of environmental waters by agar for XRF analysis2009

    • Author(s)
      K. Nakano, K. Okubo, K. Tsuji
    • Journal Title

      Powder Diffraction 24

      Pages: 135-139

    • Peer Reviewed
  • [Journal Article] X線発光分光2008

    • Author(s)
      辻幸一
    • Journal Title

      分光研究 57

      Pages: 29-41

    • Peer Reviewed
  • [Journal Article] Application of confocal 3D micro XRF for solid/liquid interface analysis2008

    • Author(s)
      K. Tsuji, T. Yonehara, K. Nakano
    • Journal Title

      Anal. Sci. 24

      Pages: 99-103

    • Peer Reviewed
  • [Journal Article] X-ray Energy Dependence of the Properties of the Focused Beams Produced by Polycapillary X-ray Lens2008

    • Author(s)
      A. Matsuda, Y. Nodera, K. Nakano, K. Tsuji
    • Journal Title

      Anal. Sci. 24

      Pages: 843-846

    • Peer Reviewed
  • [Journal Article] 照射・検出同軸型の微小部XRFプローブの開発2008

    • Author(s)
      米原翼、辻幸一
    • Journal Title

      X線分析の進歩 39

      Pages: 95-104

    • Peer Reviewed
  • [Journal Article] Development of a compact XRF probe using a ring-type secondary target2008

    • Author(s)
      T. Yonehara, K. Tsuji
    • Journal Title

      X-Ray Spectrom. 37

      Pages: 503-507

    • Peer Reviewed
  • [Journal Article] C.U. Ro, X-Ray Spectrometry2008

    • Author(s)
      K. Tsuji, K. Nakano, H. Hayashi
    • Journal Title

      Anal. Chem. 80

      Pages: 4421-4454

    • Peer Reviewed
  • [Journal Article] Milling characteristics and distribution of phytic acid and zinc in rice kernels2008

    • Author(s)
      J. Liang, Z. Li, K. Tsuji, K. Nakano, M.J.R. Nout, R.J. Hamer
    • Journal Title

      Journal of Cereal Science 48

      Pages: 83-91

    • Peer Reviewed
  • [Journal Article] Micro and imaging x-ray analysis by using polycapillary x-ray optics2008

    • Author(s)
      K. Tsuji, K. Nakano, M. Yamaguchi, T. Yonehara
    • Journal Title

      Proc. SPIE 7077

      Pages: 70770W-1~8

    • Peer Reviewed
  • [Journal Article] Improvement of spatial resolution ofμ-XRF by using a thin metal filter2008

    • Author(s)
      K. Nakano, A. Matsuda, Y. Nodera, K. Tsuji
    • Journal Title

      X-Ray Spectrom. 37

      Pages: 642-645

    • Peer Reviewed
  • [Journal Article] GE-MXRF analysis of multilayer films2008

    • Author(s)
      J. Yang, K. Tsuji, D. Han, X. Ding
    • Journal Title

      X-Ray Spectrom. 37

      Pages: 625-628

    • Peer Reviewed
  • [Journal Article] Development of Confocal Micro-XRF Instrument using Two X-ray Beams2007

    • Author(s)
      K. Tsuji, K. Nakano, X. Ding
    • Journal Title

      Spectrochim. Acta B 62

      Pages: 549-553

    • Peer Reviewed
  • [Journal Article] Development of Confocal 3D micro XRF Spectrometer with Cr-Mo Dual Excitation2007

    • Author(s)
      K. Tsuji, K. Nakano
    • Journal Title

      X-Ray Spectrom. 36

      Pages: 145-149

    • Peer Reviewed
  • [Journal Article] 固液界面用蛍光X線分析法の提案と化学めっき過程の観察2007

    • Author(s)
      堤本薫、辻幸一
    • Journal Title

      分析化学 56

      Pages: 499-504.

    • Peer Reviewed
  • [Journal Article] 共焦点型3次元蛍光X線分析装置の開発と微小部深さ方向分析への応用2007

    • Author(s)
      辻幸一、野寺雄太、中野和彦
    • Journal Title

      表面科学 28

      Pages: 447-452

    • Peer Reviewed
  • [Journal Article] Time-resolved X-ray fluorescence for monitoring the intake of mineral nutrients in living plants2007

    • Author(s)
      K. Tsutsumimoto, K. Tsuji
    • Journal Title

      X-Ray Spectrom. 36

      Pages: 324-327

    • Peer Reviewed
  • [Presentation] Micro and Trace X-ray Fluorescence Analysis in Laboratory2009

    • Author(s)
      K. Tsuji, K. Nakano
    • Organizer
      FACSS2009
    • Place of Presentation
      Louisville, KY, USA(oral)
    • Year and Date
      20091118-20091022
  • [Presentation] 微少量溶液サンプリングと全反射蛍光X線分析2009

    • Author(s)
      西田吉彦、宮垣祐志、辻幸一
    • Organizer
      第45回X線分析討論会
    • Place of Presentation
      大阪市立大学学術情報総合センター(口頭)
    • Year and Date
      20091105-20091106
  • [Presentation] 全反射蛍光x線分析のための微少量溶液サンプリング方法の検討2009

    • Author(s)
      西田吉彦、宮垣裕志、辻幸一
    • Organizer
      日本分析化学会第58年会in札幌
    • Place of Presentation
      北海道大学高等教育機能開発総合センター、北海道(口頭)
    • Year and Date
      20090924-20090926
  • [Presentation] 玩具表面層の微小部蛍光X線分析とその溶出液の時間依存型全反射蛍光X線分析2009

    • Author(s)
      今西由紀子、西田吉彦、粟根徹、中野和彦、辻幸一
    • Organizer
      日本分析化学会第58年会in札幌
    • Place of Presentation
      北海道大学高等教育機能開発総合センター、北海道(ポスター)
    • Year and Date
      20090924-20090926
  • [Presentation] 注射針型コリメーターを用いた蛍光X線分析装置の試作及び腐食プロセスのモニタリング2009

    • Author(s)
      西田吉彦、辻幸一
    • Organizer
      第70回分析化学会討論会
    • Place of Presentation
      和歌山大学栄谷キャンパス、和歌山(ポスター)
    • Year and Date
      20090516-20090517
  • [Presentation] Micro XRF analysis in the solutions by using needle-type X-ray collimators2009

    • Author(s)
      Y. Nishida, K. Nakano, K. Tsuji
    • Organizer
      JST International Symposium on "Micro and Trace X-ray Analysis"
    • Place of Presentation
      Osaka City University, Osaka, JAPAN(poster)
    • Year and Date
      20090212-20090214
  • [Presentation] 水溶液中の微小部蛍光X線分析2009

    • Author(s)
      辻幸一、西田吉彦、中野和彦
    • Organizer
      平成20年度大阪市立大学重点研究「ヒューマンアダプティブ・マテリアルの開拓」第4回シンポジウム
    • Place of Presentation
      大阪市立大学学術情報総合センター10階、大阪(口頭)
    • Year and Date
      2009-02-12
  • [Presentation] ニードル型コリメーターを用いた液液界面近傍の蛍光X線分析2008

    • Author(s)
      西田吉彦、辻幸一
    • Organizer
      第44回X線分析討論会
    • Place of Presentation
      日本女子大学、東京(ポスター)
    • Year and Date
      20081018-20081019
  • [Presentation] 溶液および液-液界面近傍の微小部蛍光X線分析2008

    • Author(s)
      中野和彦、西田吉彦、辻幸一
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大学七隈キャンパス、福岡
    • Year and Date
      20080910-20080912
  • [Presentation] 蛍光X線分析法による液液界面・固液界面近傍の元素分布測定2008

    • Author(s)
      西田吉彦、中野和彦、辻幸一
    • Organizer
      日本分析化学会第57年会
    • Place of Presentation
      福岡大学七隈キャンパス、福岡
    • Year and Date
      20080910-20080912
  • [Presentation] 3D-XRF Analysis of Solutions in Micro Chemical Chip2008

    • Author(s)
      K. Tsuji, K. Nakano
    • Organizer
      XRM2008 (PSI 9th International Conference on X-Ray Microscopy)
    • Place of Presentation
      Zurich, Swizerland(poster)
    • Year and Date
      20080721-20080725
  • [Presentation] X-ray Fluorecenece Analysis of Liquid/Solid Samples2008

    • Author(s)
      K. Tsuji, Y. Nishida
    • Organizer
      EXRS2008
    • Place of Presentation
      Cavtat, Dubrovnik, CROATIA(oral)
    • Year and Date
      20080616-20080620
  • [Presentation] 液体中の固体材料分析装置の試作2008

    • Author(s)
      西田吉彦、辻幸一
    • Organizer
      日本鉄鋼協会第155回春季講演大会学生ポスターセッション
    • Place of Presentation
      武蔵工業大学
    • Year and Date
      2008-03-27
  • [Presentation] Development of compact XRF probe and solid-liquid interface XRF analysis2007

    • Author(s)
      T. Yonehara, K. Tsuji
    • Organizer
      The 9th Asian Conference on Analytical Sciences (Asianalysis)
    • Place of Presentation
      Jeju, Korea(poster)
    • Year and Date
      20071104-20071108
  • [Presentation] Solid-Liquid Interface Analysis by Compact XRF Probe2007

    • Author(s)
      Y. Nishida, T. Yonehara, K. Tsuji
    • Organizer
      19th International Conference on X-Ray Optics and Microanalysis (ICXOM2007)
    • Place of Presentation
      Kyoto, Japan(poster)
    • Year and Date
      20070916-20070921
  • [Presentation] SOLID-LIQUID INTERFACE ANALYSIS BY LABORATORY-MADE 3D-MICRO-XRF INSTRUMENT2007

    • Author(s)
      K. Tsuji, T. Yonehara, K. Nakano
    • Organizer
      EMAS2007
    • Place of Presentation
      Antwerp, Belgium(poster)
    • Year and Date
      20070506-20070510
  • [Book] eds. R. A. Meyers, John Wiley: Chichester.2010

    • Author(s)
      K. Tsuji
    • Publisher
      "Micro-X-ray Fluorescence" in Encyclopedia of Analytical Chemistry
    • URL

      DOI:10.1002/9780470027318.a9067.

  • [Book] 実験室における微小部高感度蛍光X線分析, ナノイメージング2008

    • Author(s)
      辻幸一、中野和彦
    • Total Pages
      305-320
    • Publisher
      エヌ・テイー・エス
  • [Book] 共焦点三次元蛍光X線分析, ナノイメージング2008

    • Author(s)
      中野和彦、辻幸一
    • Total Pages
      450-457
    • Publisher
      エヌ・テイー・エス
  • [Book] 蛍光X線法, 表面物性工学ハンドブック第2版2007

    • Author(s)
      辻幸一
    • Total Pages
      184-188
    • Publisher
      丸善
  • [Book] X-ray Technology2007

    • Author(s)
      K. Tsuji
    • Total Pages
      411-444
    • Publisher
      in Kirk-Othmer Encyclopedia of Chemical Technology
  • [Remarks]

    • URL

      http://www.a-chem.eng.osaka-cu.ac.jp/tsujilab/

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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