2009 Fiscal Year Final Research Report
Development of nanoporous metal coordination compounds for resolution of environment and energy issues
| Project/Area Number |
19350077
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
MORI Wasuke Kanagawa University, 理学部, 教授 (60029709)
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| Co-Investigator(Kenkyū-buntansha) |
KIHARA Nobuhiro 神奈川大学, 理学部, 教授 (30214852)
SAITO Taro 神奈川大学, 理学部, 非常勤講師 (90011006)
NISHIMOTO Yuko 神奈川大学, 理学部, 准教授 (70241114)
MATSUNAGA Satoshi 神奈川大学, 理学部, 助手 (80451516)
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| Project Period (FY) |
2007 – 2009
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| Keywords | グリーンケミストリー / 機能性細孔物質 / 水素吸蔵 / 水素発生触媒 |
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| Research Abstract |
Porous complexes which we found have been extensively studied in recent years because of their intriguing structures and, more importantly, for their potential applications in gas storage, separation, and catalysis. In this project, we have synthesized the novel porous complexes and evaluated hydrogen adsorption properties and the hydrogen production-catalytic activities of the porous complexes in order to construct a clean energy system. The hydrogen adsorption properties depended upon the node-metals, and the porous complexes having small pore size showed a highly hydrogen-adsorption capability. In the Ru- and Rh-based porous complexes showed a hydrogen production-catalytic activity under the existing co-catalysts.
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[Journal Article] Hydrogen Adsorption Properties of Lantern-Type Dinuclear M(BDC)(DABCO)1/22008
Author(s)
T. Takei, J. Kawashima, T. Ii, A. Maeda, M. Hasegawa, T. Kitagawa, T. Ohmura, M. Ichikawa, M. Hosoe, I. Kanoya, W. Mori
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Journal Title
Bull. Chem. Soc. Jpn. 81巻
Pages: 847-856
Peer Reviewed
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[Journal Article] Synthesis Structures, and Magnetic Properties of Dinuculer Nickel(II) Complexes Containing, N, N, N', N'-Tetrakis[(1-methyl-2-bensimidazolyl)methyl ]-2-hydroxy-1, 3-diaminopropane and a Thiocyanate Ion2008
Author(s)
Y. Nakao, T. Sato, W. Mori, S. Goto, M. Issiki, M. Fujii, M. Shiro, R. Tanaka, K. Matsumoto
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Journal Title
CHUGOKUGAKUEN J. 7巻
Pages: 11-17
Peer Reviewed
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[Journal Article] Three-Dimensionally Ordered CDW State in Quasi-One-Dimensional Iodo-Bridged Dinuclear Platinum Mixed-valence Compounds, A4[Pt2I(pop)4]・nH2O (A = Aromaic Ammonium Cations)2008
Author(s)
S. Matsunaga, K. Takizawa, D. Kawakami, H. Iguchi, S. Takaishi, T. Kajiwara, H. Miyasaka, M. Yamashita, H. Matsuzaki, H. Okamoto
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Journal Title
Eur. J. Inorg. Chem.
Pages: 3269-3273
Peer Reviewed
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[Journal Article]2008
Author(s)
N, Motokawa, T. Oyama, S. Matsunaga, H. Miyasaka, K. Sugimoto, M. Yamashita, N. Lopez, K.R. Dunbar
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Journal Title
Dalton Trans.
Pages: 4099-4102
Peer Reviewed
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