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2009 Fiscal Year Self-evaluation Report

Luminescent Materials Functionalized by Heteroatom-Mixed System

Research Project

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Project/Area Number 19350095
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionOsaka Prefecture University

Principal Investigator

OGAWA Akiya  Osaka Prefecture University, 工学研究科, 教授 (30183031)

Project Period (FY) 2007 – 2010
Keywordsパイ共役系分子 / ヘテロ元素 / 複合同時導入法 / 有機発光素子 / ラジカル反応 / 遷移金属触媒反応 / ヘテロ原子複合材料 / ヘテロ環化合物
Research Abstract

近年、有機超伝導に代表される伝導性有機化合物の応用展開は多様性を増してきており、特に、セレン、イオウ、窒素、テルルなどの孤立電子対を有するヘテロ環化合物は、それらの電子状態に基づいた新機能を有する魅力的な研究対象であるだけでなく、材料、医療といった精密合成を必要とする学問領域の発展には欠くことのできない構造体となっている。しかし、ヘテロ原子を複合化させた材料開発は、その合成の複雑さ、困難さから普遍的な製造法が確立されておらず、ヘテロ元素含有パイ共役系分子の効率的な創生がこの分野の発展に大きな意義を持つと考えられる。本研究では、これまでに開発してきた遷移金属触媒、光照射によるヘテロ原子複合同時導入法を駆使し、新規ヘテロ原子複合発光材料の創生を行うものである。

  • Research Products

    (14 results)

All 2010 2009 2008 2007 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (4 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Highly Selective Phosphinotelluration of Terminal Alkynes Using a (Ph_2P)_2-(PhTe)_2 Mixed System upon Visible Light Irradiation : Straightforward Access to 1-Phosphino-2-telluro-alkenes2010

    • Author(s)
      Kawaguchi S., Ohe T., Shirai T., Nomoto A., Sonoda M., Ogawa A.
    • Journal Title

      Organometallics 29

      Pages: 312-316

    • Peer Reviewed
  • [Journal Article] (PhTe)_2-Mediated Intramolecular Radical Cyclization of o-Ethynylaryl Isocyanides Leading to Bistellurated Quinolines upon Visible-Light Irradiation2009

    • Author(s)
      Mitamura T., Iwata K., Ogawa A.
    • Journal Title

      Organic Letters 11

      Pages: 3422-3424

    • Peer Reviewed
  • [Journal Article] Transition-Metal-Catalyzed Hydrothiolation of Cyclohexylallene with Benzenethiol or Diphenyl Disulfide : Controlling the Reaction Courses and Regioselectivity2009

    • Author(s)
      Kodama S., Nomoto A., Kajitani M., Nishinaka E., Sonoda M., Ogawa A.
    • Journal Title

      Journal of Sulfur Chemistry 30

      Pages: 309-318

    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed regioselective introduction of chalcogen moieties into porphyrin bearing an ethynyl group2009

    • Author(s)
      Nomoto A., Shiino G., Ogawa A.
    • Journal Title

      Research on Chemical Intermediates 35

      Pages: 965-971

    • Peer Reviewed
  • [Journal Article] A Highly Regioselective Palladium-Catalyzed Hydrophosphination of Alkynes Using a Diphosphine-Hydrosilane Binary System2008

    • Author(s)
      Kawaguchi S., Nagata S., Nomoto A., Sonoda M., Ogawa A.
    • Journal Title

      Journal of Organic Chemistry 73

      Pages: 7928-7933

    • Peer Reviewed
  • [Presentation] ビニルスルフィド骨格を有するパイ共役系分子の合成と発光特性2009

    • Author(s)
      野元昭宏, 湊邉悠太, 小川昭弥
    • Organizer
      第36回有機典型元素化学討論会
    • Place of Presentation
      とりぎん文化会館 (鳥取県)
    • Year and Date
      2009-12-10
  • [Presentation] Photoinduced Radical Addition Reactions of Ditellurides to Unsaturated Bonds and their Application to Radical Cyclization2009

    • Author(s)
      Ogawa A.
    • Organizer
      The 4^<th> Pacific Symposium on Radical Chemistry
    • Place of Presentation
      Hope Hotel (上海、中国)
    • Year and Date
      2009-11-20
  • [Presentation] Coordination Behavior of Divinylbenzene Derivatives and Complexes Including Calcogen Moiety2009

    • Author(s)
      Nomoto A., Minatobe Y., Ogawa A.
    • Organizer
      The 4^<th> East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      大阪国際交流センター (大阪府)
    • Year and Date
      2009-06-04
  • [Presentation] Highly Selective Introduction of Heteroatom Groups into Unsaturated Bonds by Using Heteroatom-Mixed System2008

    • Author(s)
      Nomoto A., Ogawa A.
    • Organizer
      10^<th> International Symposium on Organic Free Radicals and 3rd Pacific Symposium on Radical Chemistry
    • Place of Presentation
      Heron Island (オーストラリア)
    • Year and Date
      2008-08-04
  • [Book] Carbonylation of allenes (In Modern Carbonylation Methods) (Ed by L. Kollar, VCH-Wiley)2008

    • Author(s)
      A. Nomoto, A. Ogawa
    • Total Pages
      291-300
  • [Book] Heneicosafluoro-n-decyl Iodide (In Handbook of Reagents for Organic Synthesis ; Fluorine-Containing Reagents) (Ed by L. Paquette, P. Fuchs, D. Crich, G. Molander, John Wiley & Sons)2007

    • Author(s)
      A. Nomoto, A. Ogawa
    • Total Pages
      289-292
  • [Remarks]

    • URL

      www.osakafu-u.ac.jp/research/pdf

  • [Patent(Industrial Property Rights)] カルボニル化合物の製造方法2007

    • Inventor(s)
      小川昭弥, 野元昭宏, 上田幸弘
    • Industrial Property Rights Holder
      公立大学法人大阪府立大学
    • Patent Publication Number
      特開2008-303159
    • Filing Date
      2007-06-06
  • [Patent(Industrial Property Rights)] アミン化合物の酸化方法及びイミン化合物製造方法2007

    • Inventor(s)
      小川昭弥, 野元昭宏, 上田幸弘
    • Industrial Property Rights Holder
      公立大学法人大阪府立大学
    • Patent Publication Number
      特開2008-303158
    • Filing Date
      2007-06-06

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Published: 2011-06-18   Modified: 2016-04-21  

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