Selective gas separation by nanoporous materials having flexible structures

2009 Fiscal Year Final Research Report

• Project/Area Number: 19350100
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Chiba University
• Principal Investigator: HIROFUMI Kanoh Chiba University, 大学院・理学研究科, 教授 (60334166)
• Project Period (FY): 2007 – 2009
• Keywords: 多孔体

Research Abstract

Novel porous coordination polymers (PCPs) showing gate phenomena in gas sorption were prepared by combining different building blocks consisting of transitional metal ions, organic ligand molecules, and counter anions based on the properties of [Cu(bpy)_2(BF_4)_2] (LPC), which is known to have a flexible structure having a 2 dimensional grid and its stacking structures. The novel PCPs showed unique gate phenomena according to the properties of the metal, ligand, or anion. The systematic studies enabled us to understand gas sorption properties of the PCPs.
Also the fundamental properties such as the effect of moisture or organic solvents and thermal stability on the structure and gas sorptivity of LPC were examined from the viewpoint of practical use. Fundamental data could be obtained for the application to separation of CO_2.

Research Products

• [Journal Article] Equilibration-time and pore-width dependent hysteresis of water adsorption isotherm on hydrophobic microporous carbons (2010)
  • Author(s): M. Nakamura, T. Ohba, P. Branton, H. Kanoh, K. Kaneko
  • Journal Title: Carbon 48 Pages: 305-312
• [Journal Article] Physico-Chemical Properties of Iodine-Adsorbed Single-Walled Carbon Nanotubes (2009)
  • Author(s): C. Hayakawa, K. Urita, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: Langmuir 25 Pages: 1795-1799
• [Journal Article] Reversible Structural Change of Cu-MOF on Exposure to Water and its CO_2 Adsorptivity (2009)
  • Author(s): Y. Cheng, A. Kondo, H. Noguchi, H. Kajiro, K. Urita, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: Langmuir 25 Pages: 4510-4513
• [Journal Article] Synthesis of nanoporous graphite-derived carbon/TiO_2-SiO_2 composites by a mechanochemical intercalation method (2009)
  • Author(s): Y.-H. Chu, M. Yamagishi, Z.-M. Wang, H. Kanoh, T. Hirotsu
  • Journal Title: Microporous Mesoporous Mater. 118 Pages: 496-502
• [Journal Article] Elastic Layer-structured metal organic frameworks (ELMs) (2009)
  • Author(s): H. Kanoh, A. Kondo, H. Noguchi, H. Kajiro, A. Tohdoh, Y. Hattori, W.-C. Xu, M. Inoue, T. Sugiura, K. Morita, H. Tanaka, T. Ohba, K. Kaneko
  • Journal Title: J.Colloid Interface Sci. 334 Pages: 1-7
• [Journal Article] Metal Ion-Dependent Gas Sorptivity of Elastic Layer-Structured MOFs (2009)
  • Author(s): A. Kondo, A. Chinen, H. Kajiro, T. Nakagawa, K. Kato, M. Takata, Y. Hattori, F. Okino, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: Chem.Eur.J. 15 Pages: 7549-7553
• [Journal Article] Quantum Effects on Hydrogen Isotopes Adsorption in Nanopores (2009)
  • Author(s): H. Tanaka, D. Noguchi, A. Yuzawa, T. Kodaira, H. Kanoh, K. Kaneko
  • Journal Title: J.Low.Temp.Phys. 157 Pages: 352-373
• [Journal Article] Enhanced Hydrogen Adsorptivity of Single-Wall Carbon Nanotube Bundles by One-Step C60-Pillaring (2009)
  • Author(s): M. Arai, S. Utsumi, M. Kanamaru, K. Urita, T. Fujimori, N. Yoshizawa, D. Noguchi, K. Nishiyama, Y. Hattori, F. Okino, T. Ohba, H. Tanaka, H. Kanoh, K. Kaneko
  • Journal Title: Method Nano Lett. 9 Pages: 3694-3698
• [Journal Article] Unique Hydrogen-Bonded Structure of Water around Ca Ions Confined in Carbon Slit Pores (2009)
  • Author(s): T. Ohba, N. Kojima, H. Kanoh, K. Kaneko
  • Journal Title: J.Phys.Chem.C 113 Pages: 12622-12624
• [Journal Article] Coordinated NH_3-Removal-Induced Hydrogen Adsorption of Cu-Complex Crystals (2008)
  • Author(s): A. Kondo, H. Noguchi, H. Kajiro, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: Langmuir 24 Pages: 170-174
• [Journal Article] Organic-inorganic hybrid polymer-encapsulated magnetic nanobead catalysts (2008)
  • Author(s): T. Arai, T. Sato, H. Kanoh, K. Kaneko, K. Oguma, A. Yanagisawa
  • Journal Title: Chem.Eur.J. 14 Pages: 882-885
• [Journal Article] Catalytic activities of Pd-tailored single wall carbon nanohorns (2008)
  • Author(s): T. Itoh, H. Danjo, W. Sasaki, K. Urita, E. Bekyarova, M. Arai, T. Imamoto, M. Yudasaka, S. Iijima, H. Kanoh, K. Kaneko
  • Journal Title: Carbon 46 Pages: 172-175
• [Journal Article] Nanoporosities and catalytic activities of Pd-tailored single wall carbon nanohorns (2008)
  • Author(s): T. Itoh, K. Urita, E. Bekyarova, M. Arai, M. Yudasaka, S. Iijima, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: J.Colloid Interface Sci. 322 Pages: 209-214
• [Journal Article] Comparative examination of titania nanocrystals synthesized by peroxo titanic acid approach from different precursors (2008)
  • Author(s): Y.-J. Liu, M. Aizawa, Z.-M. Wang, H. Hatori, N. Uekawa, H. Kanoh
  • Journal Title: J.Colloid Interface Sci. 322 Pages: 497-504
• [Journal Article] Fine Nanostructure Analysis of Single-Wall Carbon Nanohorns by Surface-Enhanced Raman Scattering (2008)
  • Author(s): Fujimori, T.; Urita, K.; Aoki, Y.; Kanoh, H.; Ohba, T.; Yudasaka, M.; Iijima, S.; Kaneko, K.
  • Journal Title: J.Phys.Chem.C 112 Pages: 7552-7556
• [Journal Article] Quantum Sieving Effect of Three-Dimensional Cu-Based Organic Framework for H_2 and D_2 (2008)
  • Author(s): Noguchi, D.; Tanaka, H.; Kondo, A.;Kajiro, H.; Noguchi, H.; Ohba, T.; Kanoh, H.; Kaneko, K.
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 6367-6372
• [Journal Article] Mechanochemically induced sp3-bond-associated reconstruction of single-wall carbon nanohorns (2008)
  • Author(s): K. Urita, S. Seki, H. Tsuchiya, H. Honda, S. Utsumi, C. Hayakawa, H. Kanoh, T. Ohba, H. Tanaka, M. Yudasaka, S. Iijima, K. Kaneko
  • Journal Title: J.Phys.Chem.C 112 Pages: 8759-8762
• [Journal Article] High capacitance carbon-based xerogel film produced without critical drying (2008)
  • Author(s): Y. Tao, M. Endo, R. Ohsawa, H. Kanoh, K. Kaneko
  • Journal Title: Appl.Phys.Lett. 93 Pages: 193112
• [Journal Article] Mesoporous Ni-Fe Alloys (2008)
  • Author(s): Y. Okuno, Y. Hattori, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: Ads.Sci.Technol. 26 Pages: 581-588
• [Journal Article] Clathrate Formation Mechanism of Supercritical Hydrogen Adsorption on Copper (II) Benzoate Pyrazine (2007)
  • Author(s): K. Goto, M.; Furukawa, M.; Miyamoto, J.; Kanoh, H.; Kaneko, K.
  • Journal Title: Langmuir 23 Pages: 5264-5266
• [Journal Article] Magnetism of Organic Radical Molecules Confined in Nanospace of Single-Wall Carbon Nanohorn (2007)
  • Author(s): T. Matsumura, H. Tanaka, K. Kaneko, M. Yudasaka, S. Iijima, H. Kanoh
  • Journal Title: J.Phys.Chem.C 111 Pages: 10213-10216
• [Journal Article] Conductive and Mesoporous Single-Wall Carbon Nanohorn/Organic Aerogel Composites (2007)
  • Author(s): Y. Tao, D. Noguchi, C.-M. Yang, H. Kanoh, H. Tanaka, M. Yudasaka, S. Iijima, K. Kaneko
  • Journal Title: Langmuir 23 Pages: 9155-9157
• [Journal Article] Double-Step Gas Sorption of a Two-Dimensional Metal-Organic Framework (2007)
  • Author(s): A. Kondo, H. Noguchi, L. Carlucci, D. M. Proserpio, G. Ciani, H. Kajiro, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: J.Am.Chem.Soc. 129 Pages: 12362-12363
• [Journal Article] Adsorption of water on three-dimensional pillared-layer metal organic frameworks (2007)
  • Author(s): A. Kondo, T. Daimaru, H. Noguchi, T. Ohba, K. Kaneko, H. Kanoh
  • Journal Title: J.Colloid Interface Sci. 314 Pages: 422-426
• [Presentation] 柔軟性配位高分子錯体 (ELM) のクラスレート生成に伴う二酸化炭素吸着速度解析 (2010)
  • Author(s): 近藤篤, 他
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪市
  • Year and Date: 20100326-20100329
• [Presentation] 二次元積層錯体のゲート現象の制御 (2010)
  • Author(s): 上代洋, 他
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪市
  • Year and Date: 20100326-20100329
• [Presentation] 柔軟性Ni高分子錯体の特異的ガス吸着性 (2010)
  • Author(s): 加納博文, 他
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪市
  • Year and Date: 20100326-20100329
• [Presentation] 化学架橋による有機無機ハイブリッド 錯体の高次集合体化 (2010)
  • Author(s): 本多高士, 他
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学、東大阪市
  • Year and Date: 20100326-20100329
• [Presentation] カーボンナノケージ中での細孔性配位高分子の生成 (2009)
  • Author(s): 藤島葉子, 他
  • Organizer: 第36回炭素材料学会年会
  • Place of Presentation: 仙台市戦災復興記念館
  • Year and Date: 20091201-20091203
• [Presentation] 有機-無機ハイブリッドナノ細孔体による二酸化炭素分離 (2009)
  • Author(s): 宋馳, 他
  • Organizer: 第23回日本吸着学会研究発表会
  • Place of Presentation: 豊橋技術科学大学、豊橋市
  • Year and Date: 20091127-20091128
• [Presentation] Elastic Layer-structured MOFs (ELMs) の多様なゲート現象 (2009)
  • Author(s): 加納博文, 他
  • Organizer: 第23回日本吸着学会研究発表会
  • Place of Presentation: 豊橋技術科学大学、豊橋市
  • Year and Date: 20091127-20091128
• [Presentation] A Novel Flexible Nanoporous Cu-MOF and its CO_2 (2009)
  • Author(s): Y. Cheng, et al.
  • Organizer: Adsorption Property
  • Place of Presentation: Rome, Italy
  • Year and Date: 20091019-20091022
• [Presentation] Elastic Layer-structured MOF (ELM) のゲート現象に及ぼす溶媒処理効果 (2009)
  • Author(s): 加納博文, 他
  • Organizer: 第62回コロイドおよび界面化学討論会
  • Place of Presentation: 岡山理科大学、岡山市
  • Year and Date: 20090917-20090919
• [Presentation] Changes In Dimensional Structures of a Co-MOF System (2009)
  • Author(s): H. Kanoh, et al.
  • Organizer: The Joint 13th IACIS International Conference on Surface and Colloid Science
  • Place of Presentation: コロンビア大学、New York, USA
  • Year and Date: 20090614-20090619
• [Presentation] Gas Sorption Properties of Elastic Layer-structured MOFs (ELMs) (2009)
  • Author(s): H. Kanoh, et al.
  • Organizer: 15th International Symposium on Intercalation Compounds (ISIC15)
  • Place of Presentation: 清華大学、中国北京
  • Year and Date: 20090510-20090514
• [Presentation] コバルト配位高分子の階層的次元構造の変化 (2009)
  • Author(s): 加納博文, 他
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学 船橋
  • Year and Date: 20090327-20090330
• [Presentation] Solvent-substituted dehydration and the induced shift of CO_2 gate adsorption of a Cu-MOF (2009)
  • Author(s): チェンェン, 他
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学 船橋
  • Year and Date: 20090327-20090330
• [Presentation] 異なる次元性を有する配位高分子錯体のガス吸着特性 (2009)
  • Author(s): 近藤篤, 他
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 日本大学 船橋
  • Year and Date: 20090327-20090330
• [Presentation] Pd/Niナノメタル担持単層カーボンナノホーンを用いるメタン分解触媒 (2008)
  • Author(s): 加納博文, 他
  • Organizer: 第35回 炭素材料学会年会
  • Place of Presentation: 筑波大学 つくば
  • Year and Date: 20081203-20081206
• [Presentation] カーボンナノケージ中での細孔性配位高分子の成長 (2008)
  • Author(s): 藤島葉子, 他
  • Organizer: 第22回日本吸着学会研究発表会
  • Place of Presentation: 九州大学 福岡
  • Year and Date: 20081024-20081025
• [Presentation] 分子オーダーの結晶性1次元細孔への吸着現象 (2008)
  • Author(s): 加納博文, 他
  • Organizer: 第22回日本吸着学会研究発表会
  • Place of Presentation: 九州大学 福岡
  • Year and Date: 20081024-20081025
• [Presentation] Co系MOFの次元構造変化におけるダイナミクス (2008)
  • Author(s): 加納博文, 他
  • Organizer: 第61回コロイドおよび界面化学討論会
  • Place of Presentation: 九州大学福岡
  • Year and Date: 20080907-20080909
• [Presentation] Clathrate Formations of Metal Organic Frameworks by Expansive Modulation (2008)
  • Author(s): Hirofumi Kanoh, et al.
  • Organizer: Symposium on Future Challenges for Carbon-Based Nanooprous Materials
  • Place of Presentation: 千葉大学
  • Year and Date: 20080711-20080712
• [Presentation] Effects of Rehydration on the Structure and Gas Adsorptivity of a Cu-MOF (2008)
  • Author(s): Yan Cheng, et al.
  • Organizer: Symposium on Future Challenges for Carbon-Based Nanooprous Materials
  • Place of Presentation: 千葉大学
  • Year and Date: 20080711-20080712
• [Presentation] Framework Dimensionality-dependent Gas Adsorption Properties of Flexible Porous Coordination Polymers, Symposium on Future Challenges for Carbon-Based Nanoporous Materials (2008)
  • Author(s): Atsushi Kondo, et al.
  • Organizer: Symposium On Future Challenges for Carbon-Based Nanooprous Materials
  • Place of Presentation: 千葉大学
  • Year and Date: 20080711-20080712
• [Presentation] Structural Characterization of A Two-Dimensional Metal-Organic Framework indicating Stepwise Gas Adsorption properties (2008)
  • Author(s): A. Kondo, et al.
  • Organizer: 8^<th> International Symposium on the Characterisation of Porous Solids (COPS8)
  • Place of Presentation: Univ. Edinburgh, UK
  • Year and Date: 20080610-20080613
• [Presentation] Cooperative Gas Sorption of a 2-dimensional Cu-organic framework (2008)
  • Author(s): Hirofumi Kanoh, et al.
  • Organizer: 8^<th> International Symposium on the Characterisation of Porous Solids (COPS8)
  • Place of Presentation: Univ. Edinburgh, UK
  • Year and Date: 20080610-20080613
• [Presentation] CH_4 Storage and CO_2 Separation through Expansive Modulation of a Porous Coordination Polymer (2008)
  • Author(s): Hirofumi Kanoh, et al.
  • Organizer: 5th International Conference Interfaces Against Pollution 2008
  • Place of Presentation: 京都大学
  • Year and Date: 20080601-20080604
• [Presentation] The Change of morphology and CO_2 adsorptivity of a Cu-MOF on Rehydration (2008)
  • Author(s): Yan Cheng, et al.
  • Organizer: 5th International Conference Interfaces Against Pollution 2008
  • Place of Presentation: 京都大学
  • Year and Date: 20080601-20080604
• [Presentation] 柔軟性配位高分子錯体の構造とガス吸着特性 (2008)
  • Author(s): 近藤篤, 他
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 立教大学、池袋
  • Year and Date: 2008-03-29
• [Presentation] ゲート吸着能を示す新規コバルト細孔体, 柔軟性配位高分子錯体の構造とガス吸着特性 (2008)
  • Author(s): 中川智洋, 他
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 立教大学、池袋
  • Year and Date: 2008-03-29
• [Presentation] 新規2次元コバルト配位高分子の2段階分子吸着挙動 (2008)
  • Author(s): 知念亜矢子, 他
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 立教大学、池袋
  • Year and Date: 2008-03-29
• [Presentation] ゲート現象による効率的気体分離・貯蔵 (2007)
  • Author(s): 野口浩志, 他
  • Organizer: 第21回日本吸着学会研究発表会
  • Place of Presentation: 東京大学 駒場
  • Year and Date: 2007-09-28
• [Presentation] ゲート吸着機能性がある新規Co高分子錯体結晶 (2007)
  • Author(s): 中川智洋, 他
  • Organizer: 第21回日本吸着学会研究発表会
  • Place of Presentation: 東京大学 駒場
  • Year and Date: 2007-09-27
• [Presentation] 配位高分子の協同的気体吸収現象 (2007)
  • Author(s): 加納博文, 他
  • Organizer: 第60回コロイドおよび界面化学討論会
  • Place of Presentation: 信州大学松本市
  • Year and Date: 2007-09-20
• [Presentation] Antiferromagnetic One-Dimensional O_2 Arrays on Groove Sites of DWCNT (2007)
  • Author(s): T. Matsumura, H. Tanaka, T. Ohba, M. Endo, K. Kaneko, H. Kanoh
  • Organizer: NanoteC07 : International Conference on carbon nanoscience and nanotechnology
  • Place of Presentation: Brighton, UK
  • Year and Date: 2007-09-01
• [Presentation] Gas Sorption of a Future Foreseeing Two Dimensional Metal-Organic Framework Exhibiting Explicit Multi-Sorption Jump (2007)
  • Author(s): A. Kondo, H. Noguchi, L. Carlucci, D. M. Proserpio, G. Ciani, H. Kajiro, H. Kanoh, K. Kaneko
  • Organizer: the 9^<th> International Conference on Fundamentals of Adsorption (FOA9)
  • Place of Presentation: Giardini Naxos, Sicily, Italy
  • Year and Date: 2007-05-21
• [Presentation] Magnetism and Structures of One-dimensional Arrays of Oxygen Molecules Confined in Nanospaces (2007)
  • Author(s): H. Kanoh, T. Matsumura, H. Li, H. Noguchi, H. Tanaka, Y. Fujiyama, A. Tohdoh, T. Ohba, T. Kodaira, K. Kaneko
  • Organizer: the 9^<th> International Conference on Fundamentals of Adsorption (FOA9)
  • Place of Presentation: Giardini Naxos, Sicily, Italy
  • Year and Date: 2007-05-20
• [Presentation] Formation of Specific Crystal Structures by Quasi-high Pressure Effect in Nanospaces (2007)
  • Author(s): K. Urita, Y. Shiga, Y. Hattori, T. Ohba, H. Kanoh, K. Kaneko
  • Organizer: the 9^<th> International Conference on Fundamentals of Adsorption (FOA9)
  • Place of Presentation: Giardini Naxos, Sicily, Italy
  • Year and Date: 2007-05-20
• [Book] 吸着技術の産業応用ハンドブック (2009)
  • Author(s): 加納博文
  • Publisher: リアライズ理工センター
• [Book] 配位空間の化学-最新技術と応用- (2009)
  • Author(s): 近藤篤, 加納博文
  • Publisher: シーエムシー出版
• [Book] 炭素材料の新展開 (2007)
  • Author(s): 加納博文, 金子克美
  • Publisher: 学振第117委員会
• [Book] ナノカーボンハンドブック (2007)
  • Author(s): 加納博文, 金子克美
  • Publisher: エヌ・ティー・エス
• [Remarks] ホームページ等
  • URL: http://pchem2.s.chiba-u.ac.jp/jpn/index.html
• [Patent(Industrial Property Rights)] メソ細孔性ゼオライトの合成方法 (2008)
  • Inventor(s): 陶有勝, 加納博文, 金子克美
  • Industrial Property Rights Holder: 国立大学法人千葉大学
  • Industrial Property Number: 特許権特許第4134031号
  • Acquisition Date: 2008-06-06