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2009 Fiscal Year Final Research Report

Functionalization of Organic Nanomesh Materials Templated by Molecular Gel Network

Research Project

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Project/Area Number 19350113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKumamoto University

Principal Investigator

TAKAFUJI Makoto  Kumamoto University, 大学院・自然科学研究科, 准教授 (50332086)

Co-Investigator(Kenkyū-buntansha) IHARA Hirotaka  熊本大学, 大学院・自然科学研究科, 教授 (10151648)
SAWADA Tsuyoshi  熊本大学, 大学院・自然科学研究科, 准教授 (90240902)
Project Period (FY) 2007 – 2009
Keywords自己組織化 / 多孔質 / 有機・無機ハイブリッド / 分子会合体 / コンポジット
Research Abstract

Self-assembled molecular gels have been recognized as promising materials for bottom-up nanofabrication tools in various fields. The glutamide-derived lipids formed molecular gel in both of aqueous and organic solutions. Their chiroptical properties and morphological features can be controlled by the chemical modifications of the lipid molecules. The lipid molecules with various functional groups such as ionic and chromic groups were newly synthesized and the molecular gels from those lipids were characterized by spectroscopic measurements and microscopic observations. To increase the physical property of molecular gels, polymerization method and polymer composite method were applied. Furthermore, their morphological features and highly-oriented structures were used as templates to create functional materials and devices for various applications such as molecular sensor, optical device and solar cell.

  • Research Products

    (32 results)

All 2010 2009 2008 2007 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (20 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Hybrid self-assembly of p-gelator and fullerene derivative with photoinduced electron transfer for photocurrent generation2010

    • Author(s)
      P. Xue, R. Lu, L. Zhao, D. Xu, X. Zhang, K. Li, Z. Song, X. Yang, M. Takafuji, H. Ihara
    • Journal Title

      Langmuir Vol.26

      Pages: 6669-6675

    • Peer Reviewed
  • [Journal Article] Versatile chiroptics of peptide-induced assemblies of metalloporphyrins2010

    • Author(s)
      H. Jintoku, T. Sagawa, T. Sawada, M. Takafuji, H. Ihara
    • Journal Title

      Organic & Biomolecular Chemistry Vol.8

      Pages: 1344-1350

    • Peer Reviewed
  • [Journal Article] Enclosure of secondary chirality based on highly-oriented lipid aggregates into polymer sheet by photo-induced polymerization of polymerizable monomer gels2010

    • Author(s)
      M. Takafuji, Y. Kira, A. Ishiordori, H. Hachisako, T. Sawada, H. Ihara
    • Journal Title

      Macromolecular Symposia Vol.291

      Pages: 330-336

    • Peer Reviewed
  • [Journal Article] Polycondensation and stabilization of chirally-ordered molecular organogels derived from alkoxysilyl group-containing2009

    • Author(s)
      M. Takafuji, N. Azuma, K. Miyamoto, S. Maeda, H. Ihara
    • Journal Title

      L-glutamide lipid. Langmuir Vol.25

      Pages: 8428-8433

    • Peer Reviewed
  • [Journal Article] Self-Assembly of a Chiral Lipid Gelator Controlled by Solvent and Speed of Gelation2009

    • Author(s)
      P. Xue, R. Lu, X. Yang, L. Zhao, D. Xu, Y. Liu, H. Zhang, H. Nomoto, M. Takafuji, H.
    • Journal Title

      Chemistry-A European Journal Vol.15

      Pages: 9824-9835

    • Peer Reviewed
  • [Journal Article] Chirally self-assembled porphyrin nanowires assisted by L-glutamide-derived lipid for excitation energy transfer2009

    • Author(s)
      H. Jintoku, T. Sagawa, M. Takafuji, H. Ihara
    • Journal Title

      Organic, Biomolecular Chemistry Vol.7

      Pages: 2430-2434

    • Peer Reviewed
  • [Journal Article] Reversible and hierarchical composite gels with CdSe nanocrystals2008

    • Author(s)
      P. Xue, H. Nomoto, N. Ueki, M. Takafuji, H. Ihara
    • Journal Title

      Journal of Nanoscience and Nanotechnology Vol.8

      Pages: 314-320

    • Peer Reviewed
  • [Journal Article] Optical active polymer film tuned by chirally self-assembled molecular organogel2007

    • Author(s)
      M. Takafuji, Y. Kira, H. Tsuji, S. Sawada, H. Hachisako, H. Ihara
    • Journal Title

      Tetrahedron Vol.63

      Pages: 7489-7494

    • Peer Reviewed
  • [Journal Article] Functional organogel based on salicylideneaniline derivative with enhanced fluorescence emission and photochromism2007

    • Author(s)
      P. Xue, R. Lu, G. Chen, Y. Zhang, H. Nomoto, M. Takafuji, H. Ihara
    • Journal Title

      Chemistry-A European Journal Vol.13

      Pages: 8231-3289

    • Peer Reviewed
  • [Journal Article] Amphiphilic molecular gels from omega-aminoalkylated L-glutamic acid derivatives with unique chiroptical property

    • Author(s)
      Y. Kira, Y. Okazaki, T. Sawada, M. Takafuji, H. Ihara
    • Journal Title

      Amino Acids (available online)

    • Peer Reviewed
  • [Presentation] Peptide-functionalized zinc porphyrin assembly with multi-responsiveness based on selective axial coordination2010

    • Author(s)
      H. Jintoku, T. Sagawa, T. Sawada, M. Takafuji, H. Ihara
    • Organizer
      ACS Spring 2010 National Meeting, Exposition
    • Place of Presentation
      The Moscone Center (San Francisco)
    • Year and Date
      2010-03-22
  • [Presentation] Design of high-conjugate nanostructure from self-assembled molecular gel with L-glutamide-functionalized thiophene derivatives2010

    • Author(s)
      K. Miyamoto, H. Jintoku, T. Sagawa, T. Sawada, M. Takafuji, H. Ihara
    • Organizer
      ACS Spring 2010 National Meeting, Exposition
    • Place of Presentation
      The Moscone Center (San Francisco)
    • Year and Date
      2010-03-22
  • [Presentation] Self-assembled porphyrin-fullerene complex for energy transfer2009

    • Author(s)
      H. Jintoku, T. Sagawa, M. Takafuji, H. Ihara
    • Organizer
      11th Pacific Polymer Conference, Cairns
    • Place of Presentation
      Convention Centre (Cairns)
    • Year and Date
      2009-12-07
  • [Presentation] Stabilization of nano-fibrous network structures constatructed from chirally-oriented lipid aggregates2009

    • Author(s)
      N. Azuma, K. Miyamoto, M. Takafuji, H. Ihara
    • Organizer
      11th Pacific Polymer Conference, Cairns
    • Place of Presentation
      Convention Centre (Cairns), Australia
    • Year and Date
      2009-12-07
  • [Presentation] Nano-fabrication by polymerization in chiral molecular gel system2009

    • Author(s)
      Y. Okazaki, Y. Kira, T. Sawada, M. Takafuji, H. Ihara
    • Organizer
      The 1st FAPS Polymer Congress, Nagoya
    • Place of Presentation
      Congress Center (Nagoya)
    • Year and Date
      2009-10-21
  • [Presentation] グルタミド分子ゲルにおけるナノ構造と不斉構造2009

    • Author(s)
      吉良佳子, 岡崎豊, 澤田剛, 高藤誠, 伊原博隆
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-16
  • [Presentation] 不斉ナノ繊維会合体中での重合と有機ナノ構造形成への応用2009

    • Author(s)
      岡崎豊, 吉良佳子, 澤田剛, 高藤誠, 伊原博隆
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-16
  • [Presentation] シロキサンネットワーク形成によるキラル配向性分子ゲルの安定化2009

    • Author(s)
      東奈央子, 宮本皓史, 前田哲, 高藤誠, 伊原博隆
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-16
  • [Presentation] Enclosure of chirally-oriented achiral dye induced by self-assembled lipid aggregates into polymer matrix2009

    • Author(s)
      M. Takafuji, Y. Kira, H. Tsuji, H. Hachisako, H. Ihara
    • Organizer
      IUPAC 45th General Assembly, IUPAC 42nd Congress
    • Place of Presentation
      The Scottish Exhibition and Conference Centre (Glasgow), UK
    • Year and Date
      2009-08-07
  • [Presentation] シリル化グルタミド脂質からのキラル分子ゲルの形成と重合2009

    • Author(s)
      東奈央子, 高藤誠, 澤田剛, 伊原博隆
    • Organizer
      第46回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州)
    • Year and Date
      2009-07-11
  • [Presentation] Versatility ofβ-Ala-L-Gln-derivatives for creation of chiral nano-superstructures2008

    • Author(s)
      Y. Kira, M. Takafuji, H. Hachisako, H. Ihara
    • Organizer
      IUMRS International Conference in Asia 2008 (IUMRS-ICA 2008)
    • Place of Presentation
      Nagoya Congress Center (Nagoya)
    • Year and Date
      2008-12-09
  • [Presentation] Tunability of secondary chirality in L-glutamide-derived molecular organogel system2008

    • Author(s)
      K. Miyamoto, M. Takafuji, T. Sawada, H. Ihara
    • Organizer
      30th Australasian Polymer Symposium (30APS)
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2008-12-01
  • [Presentation] Induction of chiral assembly by axial coordination on L-glutamide-assisted porphyrin2008

    • Author(s)
      H. Jintoku, N. Watanabe, T. Sawada, M. Takafuji, T. Sagawa, H. Ihara
    • Organizer
      30th Australasian Polymer Symposium (30APS)
    • Place of Presentation
      The Sebel Albert Park Hotel Melbourne (Melbourne), Australia
    • Year and Date
      2008-12-01
  • [Presentation] Polycondensation of Self-assembled network structure from glutamide-derived lipid with alkoxysilyl group2008

    • Author(s)
      M. Takafuji, M. Czaun, S. Maeda, T. Sawada, H. Hachisako, H. Ihara
    • Organizer
      Polymer Network Group Conference 2008
    • Place of Presentation
      Lordos Beach Hotel (Larnaka), Cyprus
    • Year and Date
      2008-06-23
  • [Presentation] グルタミド脂質超構造体を利用したピレンエキサイマーの形成制御2008

    • Author(s)
      宮本皓史, 高藤誠, 澤田剛, 伊原博隆
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜(横浜)
    • Year and Date
      2008-05-28
  • [Presentation] Silica fabrication using self-assembled molecular gels from silyl L-glutamide lipids2008

    • Author(s)
      M. Takafuji, S. Maeda, H. Hachisako, H. Ihara
    • Organizer
      91st Canadian Chemistry Conference and Exhibition (CSC 2008)
    • Place of Presentation
      Shaw Conference Centre (Edmonton), Canada
    • Year and Date
      2008-05-25
  • [Presentation] Formation of nano-tubular aggregates in fullerene-induced molecular gels from L-glutamide derivative in organic media2007

    • Author(s)
      Y. Kira, M. Takafuji, T. Sawada, H. Ihara
    • Organizer
      10th Pacific Polymer Conference (PPC 10)
    • Place of Presentation
      Kobe Convention Center (Kobe)
    • Year and Date
      2007-12-05
  • [Presentation] シリル化グルタミド脂質による分子ゲルの形成と重合2007

    • Author(s)
      前田哲, 高藤誠, 伊原博隆
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      岡山大学(岡山)
    • Year and Date
      2007-11-10
  • [Presentation] Chirally self-assembled nanofibrillar aggregates from glutamide-derived lipids2007

    • Author(s)
      H. Ihara, M. Takafuji, T. Sagawa
    • Organizer
      2007 International Conference on Advanced Fibers and Polymer Materials
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-10-16
  • [Presentation] 配向性キラル分子からの有機ナノファイバーの形成と機能化2007

    • Author(s)
      高藤誠
    • Organizer
      第18回繊維学会西部支部セミナー
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2007-09-25
  • [Book] Chirally self-assembled nanofibrils and their applications. "Bottom-up Nanofabrication: Supramolecules, Self-Assemblies and Organized Films2009

    • Author(s)
      T. Sagawa, M. Takafuji, H. Ihara
    • Total Pages
      36-65
    • Publisher
      American Scientific Publishers
  • [Remarks]

    • URL

      http://www.chem.kumamoto-u.ac.jp/~wildcats/takafuji/index-j.html

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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