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2009 Fiscal Year Final Research Report

Passivation of semiconductor and metal surfaces with organic monolayers

Research Project

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Project/Area Number 19360024
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

YAMADA Taro  The Institute of Physical and Chemical Research, 川合表面化学研究室, 専任研究員 (10174723)

Co-Investigator(Renkei-kenkyūsha) SUTO Shozo  東北大学, 大学院・理学研究科, 教授 (40171277)
NISHIYAMA Katsuhiko  熊本大学, 工学部, 准教授 (10202243)
Project Period (FY) 2007 – 2009
Keywords有機単分子層 / 表面不動態化 / ナノテクノロジー / ケイ素ウエハ表面 / アルミニウム表面 / 赤外吸収スペクトル / 吸着種振動解析 / リン脂質単分子層
Research Abstract

Since the first year of this research period, FY2007, we continued the experiments collaborating with Tohoku Univ., Kumamoto Univ. and Stanford Univ. (USA). In FY2007, we ordered the equipments, and the equipments were delivered in the end. In FY2008, we achieved quite a few basic findings, led by the finding on the driving force of "hydrophohicity" of modified Si aided by synchrotron radiation. As for passivation of aluminum surfaces, a substantial progress was made until FY2009. This technology has been filed for patent application. The development infrared spectroscopy, despite some difficulties in sample preparation, ended up with strong signals of ultrathin molecular layers (less than 1 nm thick), which has been found to be applicable for organic molecules, such as phospholipids, in aqueous solution.

  • Research Products

    (22 results)

All 2010 2009 2008 2007 Other

All Journal Article (5 results) Presentation (13 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation and Characterization of Ultraclean H:Si(111)-(1×1) Surfaces Studied by HREELS, AFM and STM-STS2009

    • Author(s)
      H. Kato, T. Taoka, S. Suto, S. Nishikata, G. Sazaki, K. Nakajima, T. Yamada, R. Czajka, A. Wawro, A. Kasuya
    • Journal Title

      e-Journal of Surface Science and Nano-Technology 7

      Pages: 557-562

  • [Journal Article] Preparation of an Ultra-clean and Atomically Controlled Hydrogen-terminated Si(111)-(1×1) Surface Revealed by HREELS, AFM and STM : Aqueous NH_4F Etching Process of Si(111)2007

    • Author(s)
      H. Kato, T. Taoka, S. Nishikata, G. Sazaki, T. Yamada, R. Czajka, A. Wawro, K. Nakajima, A. Kasuya, S. Suto
    • Journal Title

      Jpn.J.Appl.Phys. 46

      Pages: 5701-5705

  • [Journal Article] Identification of Allylamine and Allylalcohol Adsorbate on Hydrogen-terminated Si(111)2007

    • Author(s)
      T. Yamada, R. Yokomori, K. Shirasaka, H.S. Kato, Maki Kawai
    • Journal Title

      ECS Transactions 3

      Pages: 15-23

  • [Journal Article] Direct interaction of water ice with hydrophobic methyl-terminated Si(111)

    • Author(s)
      I. Waluyo, H. Ogasawara, M. Kawai, A. Nilsson, T. Yamada
    • Journal Title

      J.Phys.Chem.C. in press

  • [Journal Article] Blocking Oxidation of Al Surfaces with Organic Thiol Monolayers Cured by Electron Beam

    • Author(s)
      S. Nomura, T. Yamada, M. Kawai
    • Journal Title

      Chem Lett. in press

  • [Presentation] 半導体及び金属表面の有機単分子層による修飾と不活性化2010

    • Author(s)
      山田太郎
    • Organizer
      平成21年度日本表面科学会東北北海道支部講演会
    • Place of Presentation
      仙台市
    • Year and Date
      2010-03-10
  • [Presentation] Al(111)の不動態化のための有機単分子層の探索2009

    • Author(s)
      野村周平、山田太郎、川合眞紀
    • Organizer
      表面・界面スペクトロスコピー2009
    • Place of Presentation
      札幌市
    • Year and Date
      2009-12-04
  • [Presentation] Passivation of Al(111) with organic and inorganic adlayers2009

    • Author(s)
      山田太郎, 川合眞紀
    • Organizer
      56th AVS
    • Place of Presentation
      米国サンホゼ市
    • Year and Date
      2009-11-15
  • [Presentation] Synchrotron X-ray spectroscopic study of H_2O interacting with methyl-terminated Si(111)2009

    • Author(s)
      山田太郎, I. Waluyo, H. Ogasawara, 川合眞紀, A. Nilsson
    • Organizer
      2009 SSRL/LCLS Workshop
    • Place of Presentation
      米国メンロパーク市
    • Year and Date
      2009-10-19
  • [Presentation] Synchrotron X-ray spectroscopic study of H_2O interacting with methyl-terminated Si(111)2009

    • Author(s)
      山田太郎, I. Waluyo, H. Ogasawara, 川合眞紀, A. Nilsson
    • Organizer
      ICESS-11
    • Place of Presentation
      奈良市
    • Year and Date
      2009-10-07
  • [Presentation] H:Si(111)-(1×1)表面の初期酸化過程2009

    • Author(s)
      加藤大樹、瀧川知昭、中矢博樹、山田太郎、粕谷厚生、須藤彰三
    • Organizer
      2009年秋季日本物理学会
    • Place of Presentation
      熊本市
    • Year and Date
      2009-09-25
  • [Presentation] メチル終端Si(111)表面上の水分子の軌道放射X線分光による研究2009

    • Author(s)
      山田太郎、I. waluyo、小笠原寛人、川合眞紀、A. Nilsson
    • Organizer
      2009年秋季応用物理学会
    • Place of Presentation
      富山市
    • Year and Date
      2009-09-10
  • [Presentation] Synchrotron X-ray spectroscopic study of H_2O interacting with methyl-terminated Si(111)2009

    • Author(s)
      山田太郎, I. Waluyo, H. Ogasawara, 川合眞紀, A. Nilsson
    • Organizer
      ECOSS 26
    • Place of Presentation
      イタリア パルマ市
    • Year and Date
      2009-09-01
  • [Presentation] 水素及び重水素終端Si(111)-(1×1)の表面フォノン2009

    • Author(s)
      加藤大樹、山田太郎、粕谷厚生、須藤彰三
    • Organizer
      2009年春季日本物理学会
    • Place of Presentation
      東京都豊島区
    • Year and Date
      2009-03-27
  • [Presentation] Preparation and Characterization of Ultra-clean H:Si(111)-(1×1) Surfaces Studied by HREELS, AFM and STM-STS2008

    • Author(s)
      H. Kato, 田岡琢巳, S. Nishikata, G. Sazaki, 山田太郎, R. Czajka, A. Wawro, K. Nakajima, 粕谷厚生, S. Suto
    • Organizer
      The 8th Japan-Russia Seminar on Semiconductor Surfaces
    • Place of Presentation
      仙台市
    • Year and Date
      2008-10-21
  • [Presentation] H:Si(111)-(1×1)表面の初期酸化過程の研究II2008

    • Author(s)
      瀧川知昭、中矢博樹、山田太郎、粕谷厚生、須藤彰三
    • Organizer
      2008年秋季日本物理学会
    • Place of Presentation
      盛岡市
    • Year and Date
      2008-09-21
  • [Presentation] Reactivity of n-type/p-type H:Si(111) for Photoadsorption of CH_3Br2007

    • Author(s)
      山田太郎, Ozawa, H.S. Kato, 川合眞紀
    • Organizer
      54th AVS
    • Place of Presentation
      米国シアトル市
    • Year and Date
      2007-10-08
  • [Presentation] 高品位H:Si(111)1×1表面作成法と表面フォノン2007

    • Author(s)
      加藤大樹, 田岡琢巳, 西方督, 佐崎元, 山田太郎、R. Czajka、A. wawro、中嶋一雄、粕谷厚生、須藤彰三
    • Organizer
      第62回日本物理学会
    • Place of Presentation
      札幌市
    • Year and Date
      2007-09-21
  • [Book] Modified Electrodes(Modification of Silicon Wafer Surfaces with Small Organic Moieties)(T. Yamada)Encyclopedia of Electrochemistry Vol.102007

    • Author(s)
      A.J. Bard, M. Staratmann, M. Fujihira, I. Rubinstein, J.F. Rusling eds.
    • Total Pages
      157-170
    • Publisher
      Wiley
  • [Book] 表面・界面(日本化学会編)第5版実験化学講座 第24巻2007

    • Author(s)
      谷口功・山田太郎編
    • Publisher
      丸善
  • [Remarks] ホームページ

    • URL

      http://www.riken.jp/lab-www/surf-chem/bio/IndexJ/index.html

  • [Patent(Industrial Property Rights)] 酸化防止膜皮膜金属の製造方法および酸化防止膜皮膜金属2010

    • Inventor(s)
      山田太郎
    • Industrial Property Rights Holder
      独立行政法人理化学研究所
    • Industrial Property Number
      特許出願,2010-172083
    • Filing Date
      2010-07-30

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Published: 2012-01-26   Modified: 2016-04-21  

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