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2007 Fiscal Year Annual Research Report

吸着剤の超微粒度化が拓く高効率・高速度浄水技術

Research Project

Project/Area Number 19360235
Research InstitutionHokkaido University

Principal Investigator

松井 佳彦  Hokkaido University, 大学院・工学研究科, 教授 (00173790)

Co-Investigator(Kenkyū-buntansha) 松下 拓  北海道大学, 大学院・工学研究科, 准教授 (30283401)
大野 浩一  北海道大学, 大学院・工学研究科, 助教 (00322834)
Keywords吸着 / 活性炭 / MF膜 / 膜分離 / 浄水 / ジェオスミン / クロラミン
Research Abstract

かび臭対策として,粉末活性炭により浄水処理を行っている浄水場では,長期化した場合,粉末活性炭の使用量増大によるコスト増だけでなく,排水処理施設への負荷の増大による浄水処理への影響など大きな課題がある.また,十分な接触時間をとれないことから,粉末活性炭の注入率を高めることによって対応するなど,吸着能力を有効活用できていないという課題も抱えている.オゾンや粒状活性炭による高度浄水処理においても,臭素酸など解決すべき課題を抱えており,新たな処理方法の解決が求められている.本研究では市販の粉末活性炭より遥かに粒径の小さい微粉炭を膜処理の前処理として用いた処理システムにおけるジェオスミンとその生成原因藻類であるアナベナの除去について検討した.その結果,サブミクロン粒度まで微小化した微粉炭は,少添加量,短時間で吸着が進行し,市販粉末活性炭に比べてジェオスミン除去性が格段に優れていることが分かった.さらに,膜の前処理としての微粉炭の添加は,薬品洗浄までの長期的膜間差圧上昇のみならず逆洗浄までの短期的膜間差圧上昇の抑制にも効果的なことが分かった.また,自然由来有機物質(NOM)の吸着性をポリスチレンスルホン酸(PSS)とポリエチレングリコール(PEG)をモデル物質に用いて検討した。その結果,活性炭の微粒度化によりPSS(分子量1800,4600)の吸着容量は増加するが,分子量の300,1500のPEGに対しては吸着量増加効果は見られず,分子量3000,8000のPEGにおいても吸着量増加はわずかであった。したがって,NOMに対する微粉炭の吸着量増加は,分子量のみならずNOMの親和性などの化学的性質によるものと考えられる。

  • Research Products

    (18 results)

All 2008 2007

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (13 results)

  • [Journal Article] Submicron-sized activated carbon particles for the rapid removal of chlorinous and earthy-musty compounds2008

    • Author(s)
      Matsui, Y., Murai K., Sasaki H., Ohno K. and Matsushita T.
    • Journal Title

      Journal of Water Supply: Research and Technology-AQUA, (印刷中)

    • Peer Reviewed
  • [Journal Article] Effects of reversible and irreversible membrane fouling on virus removal by a coagulation-microfiltration system2008

    • Author(s)
      Shirasaki, N., Matsushita, T., Matsui, Y. and Ohno, K.
    • Journal Title

      Journal of Water Supply: Research and Technology-AQUA (印刷中)

    • Peer Reviewed
  • [Journal Article] Simultaneous removal of cyanobacteria and an earthy odor compound by a combination of activated carbon adsorption,coagulation, and ceramic microfiltration2008

    • Author(s)
      Matsushita, T., Matsui, Y., Ohno, K. and Sawaoka, D.
    • Journal Title

      Journal of Water Supply: Research and Technology-AQUA (印刷中)

    • Peer Reviewed
  • [Journal Article] Effects of chlorine on organophosphorus pesticides adsorbed on activated carbon: Desorption and oxon formation2008

    • Author(s)
      Ohno, K., Minami, T., Matsui, Y., Magara, Y.
    • Journal Title

      WATER RESEARCH 42

      Pages: 1753-1759

    • Peer Reviewed
  • [Journal Article] Virus removal in a hybrid coagulation-microfiltration system-Investigating mechanisms of virus removal by a combination of PCR and PFU methods2007

    • Author(s)
      Shirasaki, N., Matsushita, T., Matsui, Y., Ohno, K. and Kobuke, M.
    • Journal Title

      Water Science and Technology: Water Supply 7(5-6)

      Pages: 1-8

    • Peer Reviewed
  • [Presentation] Release of a musty odor compound from cyanobacteria during ceramic microfiltration and its effective remove by a combination of activated carbon adsorption, coagulation, and ceramic microfiltration2007

    • Author(s)
      Matsushita, T., Matsui, Y., Sawaoka, D. and Ohno, K.
    • Organizer
      2nd IWA-ASPIRE Asia-Pacific Regional Group Conference & Exhibition
    • Place of Presentation
      Perth, Australia(Perth Convention Exhibition Center)
    • Year and Date
      20071028-1101
  • [Presentation] Desorption and oxon formation of organophosphorus pesticides once adsorbed on activated carbon surface as a result of contact with chlorine2007

    • Author(s)
      Ohno, K., Shiratori, Y., Minami, T., Matsui, Y. and Matsushita, T.
    • Organizer
      2nd IWA-ASPIRE Asia-Pacific Regional Group Conference & Exhibition
    • Place of Presentation
      Perth, Australia(Perth Convention Exhibition Center)
    • Year and Date
      20071028-1101
  • [Presentation] Submicron-sized activated carbon particles for the rapid removal of chlorinous and earthy-musty compounds2007

    • Author(s)
      Matsui, Y., Murai, K., Sasaki, H., Ohno, K. and Matsushita, T.
    • Organizer
      IWA International Conference on Particle Separation(PS 2007)
    • Place of Presentation
      Toulouse, France,(Universite Paul Sabatier)
    • Year and Date
      20070709-12
  • [Presentation] Simultaneous removal of cyanobacteria and a musty odor compound by a combination of activated carbon adsorption, coagulation, and ceramic microfiltration2007

    • Author(s)
      Matsushita, T., Matsui, Y., Ohno, K. and Sawaoka, D.
    • Organizer
      IWA International Conference on Particle Separation(PS 2007)
    • Place of Presentation
      Toulouse, France,(Universite Paul Sabatier)
    • Year and Date
      20070709-12
  • [Presentation] Effects of reversible and irreversible membrane fouling on virus removal by a coagulation-microfiltration system2007

    • Author(s)
      Shirasaki, N., Matsushita, T., Matsui, Y. and Ohno, K.,
    • Organizer
      IWA International Conference on Particle Separation(PS 2007)
    • Place of Presentation
      Toulouse, France,(Universite Paul Sabatier)
    • Year and Date
      20070709-12
  • [Presentation] Reaction of chlorine with organophosphorus pesticides adsorbed on activated carbon surface2007

    • Author(s)
      Ohno, K., Minami, T., Matsui, Y.
    • Organizer
      IWA Specialised Conference on Assessment & Control of Micropolluntants/Hazardous Substances in Water
    • Place of Presentation
      Frankfurt/Main, Germany(DECHEMA-House)
    • Year and Date
      20070617-20
  • [Presentation] 活性炭の微粉化によるジェオスミン除去性の向上2007

    • Author(s)
      佐々木洋志, 村井謙二, 栗原沙織, 大野浩一, 松下拓, 松井佳彦
    • Organizer
      第58回全国水道研究発表会,
    • Place of Presentation
      釧路(釧路市観光国際交流センター)
    • Year and Date
      20070523-25
  • [Presentation] 塩素による有機リン系農薬等の酸化と活性炭からの脱着2007

    • Author(s)
      白鳥良樹, 南岳宏, 大野浩一, 松下拓, 松井佳彦
    • Organizer
      第58回全国水道研究発表会
    • Place of Presentation
      釧路(釧路市観光国際交流センター)
    • Year and Date
      20070523-25
  • [Presentation] ファウリングガ凝集MF膜処理におけるウイルス除去に与える影響2007

    • Author(s)
      小泓誠, 白崎伸隆, 松下拓, 松井佳彦, 大野浩一
    • Organizer
      第58回全国水道研究発表会
    • Place of Presentation
      釧路(釧路市観光国際交流センター)
    • Year and Date
      20070523-25
  • [Presentation] 超微粉化活性炭添加がセラミック膜ろ過性に及ぼす影響2007

    • Author(s)
      長谷川広樹, 澤岡大輔, 大野浩一, 松下拓, 松井佳彦
    • Organizer
      第58回全国水道研究発表会
    • Place of Presentation
      釧路(釧路市観光国際交流センター)
    • Year and Date
      20070523-25
  • [Presentation] Removal of geosmin and algae by ceramic membrane filtration with super-powdered activated carbon adsorption pretreatment2007

    • Author(s)
      Matsui, Y., Aizawa, T., Suzuki, M. and Kawase, Y.
    • Organizer
      IWA 4th International Conference on Membranes for Water and Wastewater Treatment
    • Place of Presentation
      Harrogate, UK(Harrogate International Conference Centre)
    • Year and Date
      20070514-17
  • [Presentation] Virus removal in a hybrid coagulation-microfiltration system-Investigating mechanisms of virus removal by a combination of PCR and PFU methods2007

    • Author(s)
      Shirasaki, N., Matsushita, T., Matsui, Y., Ohno, K., Kobuke, M.
    • Organizer
      IWA 4th International Conference on Membranes for Water and Wastewater Treatment
    • Place of Presentation
      Harrogate, UK(Harrogate International Conference Centre)
    • Year and Date
      20070514-17
  • [Presentation] Application and research of ceramic microfiltration in Japan2007

    • Author(s)
      Matsui, Y.
    • Organizer
      Workshop on Ceramic Membranes
    • Place of Presentation
      Nieuwegein, The Netherlands(Kiwa Water Research)
    • Year and Date
      2007-09-24

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Published: 2010-02-04   Modified: 2016-04-21  

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