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2009 Fiscal Year Final Research Report

Development of ternary Ni_3Al-alloy catalysts for hydrogen production

Research Project

  • PDF
Project/Area Number 19360321
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

HIRANO Toshiyuki  National Institute for Materials Science, 燃料電池材料センター, NIMS特別研究員 (90354183)

Co-Investigator(Kenkyū-buntansha) XU Ya  独立行政法人物質・材料研究機構, 燃料電池材料センター, 主幹研究員 (00370304)
DEMURA Masahiko  独立行政法人物質・材料研究機構, 燃料電池材料センター, 主任研究員 (10354177)
Project Period (FY) 2007 – 2009
Keywords水素 / 触媒・化学プロセス / 構造・機能材料
Research Abstract

The proponents of this study have discovered a catalytic activity for hydrogen production via methanol decomposition. In this study we examined the effect of alloying elements on the catalytic activity. It was found that Fe enhances the activity and lowers the active temperature. Silicon and titanium were also found to show a similar effect, but have a disadvantage of accelerating carbon deposition. Chromium and vanadium were found to significantly decrease the activity.

  • Research Products

    (24 results)

All 2010 2009 2008 2007

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (10 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Characterization of surface structure evolution in Ni3Al foil catalysts by hard X-ray photoelectron spectroscopy2010

    • Author(s)
      Ya Xu, H. Yoshikawa, J.H. Jang, M. Demura, K. Kobayashi, S. Ueda, Y. Yamashita, D.M. Wee, T. Hirano
    • Journal Title

      Journal of Physical Chemistry C Vol.114

      Pages: 6047-6053

    • Peer Reviewed
  • [Journal Article] Catalytic properties of cold-rolled Ni3(Si, Ti) intermetallic foils for methanol decomposition2010

    • Author(s)
      Y. Kaneno, T. Kondo, Y. Fujimoto, H. Tsuda, Ya Xu, M. Demura, H. Iwai, T. Hirano, T. Takasugi
    • Journal Title

      Materials Transactions Vol.51

      Pages: 1002-1010

    • Peer Reviewed
  • [Journal Article] Catalytic activity of pre-activated Ni3Al foil catalysts for hydrogen production from methanol under steam addition2010

    • Author(s)
      J.H. Jang, Ya Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
    • Journal Title

      Catalysis Letters Vol.134

      Pages: 258-263

    • Peer Reviewed
  • [Journal Article] Evolution of surface morphology in Ni(gamma)/Ni3Al(gamma') two-phase foils during electrochemical etching2010

    • Author(s)
      H.Y. Lee, M. Demura, Ya Xu, D.M. Wee, T. Hirano
    • Journal Title

      ADVANCED MATERIALS RESEARCH Vol.89-91

      Pages: 331-336

    • Peer Reviewed
  • [Journal Article] Ni3Al Intermetallic catalysts for hydrogen production from methane steam reforming2010

    • Author(s)
      Ya Xu, D.H. Chun, J.H. Jang, M. Demura, D.M. Wee, T. Hirano
    • Journal Title

      ADVANCED MATERIALS RESEARCH Vol.89-91

      Pages: 645-650

    • Peer Reviewed
  • [Journal Article] Effects of steam addition on the spontaneous activation in Ni3Al foil catalysts during methanol decomposition2009

    • Author(s)
      J.H. Jang, Ya Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
    • Journal Title

      Journal of Molecular Catalysis A: Chemical Vol.307

      Pages: 21-28

    • Peer Reviewed
  • [Journal Article] Catalytic properties of chemically pretreated Ni3Al/Ni two-phase alloy foils for methane steam reforming2009

    • Author(s)
      D. Kamikihara, Y. Xu, M. Demura, T. Hirano
    • Journal Title

      Mat. Res. Soc., Proc. Vol.1128

      Pages: 263-268

    • Peer Reviewed
  • [Journal Article] Surface modification of Ni/Ni3Al two-phase foils by electrochemically selective etching2009

    • Author(s)
      H.Y. Lee, M. Demura, Y. Xu, D.M. Wee, T. Hirano
    • Journal Title

      Mat. Res. Soc., Proc. Vol.1128

      Pages: 269-274

    • Peer Reviewed
  • [Journal Article] Surface structure modification of Ni3Al foil catalysts by oxidation-reduction treatment2009

    • Author(s)
      J.H. Jang, Y. Xu, D.H. Chun, M. Demura, D.M. Wee, T. Hirano
    • Journal Title

      Mat. Res. Soc., Proc. Vol.1128

      Pages: 275-280

    • Peer Reviewed
  • [Journal Article] Catalytic properties of Atomized Ni3Al Powder for Methane Steam Reforming2009

    • Author(s)
      Y. Ma, Y. Xu, M. Demura, T. Hirano
    • Journal Title

      Mat. Res. Soc., Proc. Vol.1128

      Pages: 381-386

    • Peer Reviewed
  • [Presentation] Surface Modification of Ni (γ) / Ni3Al (γ´) Two-Phase Foils by Selective Etching and alkali leaching for catalitic activity enhancement2010

    • Author(s)
      H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      日本金属学会2010年春期大会
    • Place of Presentation
      筑波大学
    • Year and Date
      20100328-20100330
  • [Presentation] Behavior of Ni particle formation on Ni3Al foil surface by oxidation-reduction treatment2010

    • Author(s)
      J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      日本金属学会2010年春期大会
    • Place of Presentation
      筑波大学
    • Year and Date
      20100328-20100330
  • [Presentation] Effects of steam addition on spontaneous activation of Ni3Al foils2009

    • Author(s)
      J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      20091207-20091209
  • [Presentation] Ni3Al金属間化合物箔の水素製造触媒特性2009

    • Author(s)
      許亜, D.H. Chun, J.H. Jang, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      第104回日本触媒討論会
    • Place of Presentation
      宮崎大学
    • Year and Date
      20090927-20090930
  • [Presentation] Surface modification of Ni (γ) / Ni3Al (γ´) two-phase foil by electrochemical selective etching2009

    • Author(s)
      H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      日本金属学会2009秋期大会
    • Place of Presentation
      京都大学
    • Year and Date
      20090915-20090917
  • [Presentation] プラズマ法によるNi-Al系金属間化合物のナノ粒子触媒の作製とその触媒特性2009

    • Author(s)
      許亜, 楊君友, 出村雅彦, 平野敏幸, 原徹
    • Organizer
      日本金属学会2009秋期大会
    • Place of Presentation
      京都大学
    • Year and Date
      20090915-20090917
  • [Presentation] Catalytic Properties of Ni3Al Foils for Methane Steam Reforming2009

    • Author(s)
      馬雁, 許亜, 出村雅彦, 平野敏幸
    • Organizer
      ISHHC XIV
    • Place of Presentation
      Stockholm University, Stockholm, Sweden
    • Year and Date
      20090913-20090918
  • [Presentation] Catalytic properties of Ni3Al foil catalysts modified by oxidation-reduction for methanol decomposition2009

    • Author(s)
      J.H. Jang, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      ISHHC XIV
    • Place of Presentation
      Stockholm University, Stockholm, Sweden
    • Year and Date
      20090913-20090918
  • [Presentation] Ni3Al INTERMETALLIC CATALYSTS FOR HYDROGEN PRODUCTION FROM METHANE STEAM REFORMING2009

    • Author(s)
      許亜, D.H. Chun, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      THERMEC'2009
    • Place of Presentation
      Techincal University-Berlin, Berlin, Germany
    • Year and Date
      20090825-20090829
  • [Presentation] Evolution of surface morphology in Ni (γ) / Ni3Al (γ') two-phase foils during electrochemical etching.2009

    • Author(s)
      H.Y. Lee, 許亜, 出村雅彦, D.M. Wee, 平野敏幸
    • Organizer
      THERMEC'2009
    • Place of Presentation
      Techincal University-Berlin, Berlin, Germany
    • Year and Date
      20090825-20090829
  • [Patent(Industrial Property Rights)] メタンの水蒸気改質触媒2009

    • Inventor(s)
      許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・特願2009-047471
    • Filing Date
      2009-03-02
  • [Patent(Industrial Property Rights)] CO酸化触媒2008

    • Inventor(s)
      許亜, 揚君友, 出村雅彦, 平野敏幸, 原徹
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・特願2008-313902
    • Filing Date
      2008-12-10
  • [Patent(Industrial Property Rights)] メタノール分解触媒2008

    • Inventor(s)
      許亜、揚君友、出村雅彦、平野敏幸、原徹
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・特願2008-313931
    • Filing Date
      2008-12-10
  • [Patent(Industrial Property Rights)] Ni3(Si,Ti)系金属間化合物からなるメタノールからの水素製造用触媒,水素製造方法、水素製造装置2007

    • Inventor(s)
      高杉隆幸、金野康幸、許亜、出村雅彦、平野敏幸
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・特願2007-192525
    • Acquisition Date
      2007-07-24

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Published: 2011-06-18   Modified: 2016-04-21  

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