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2009 Fiscal Year Final Research Report

High rate synthesis of nano-size powders at non-equilibrium conditions by controlled thermal plasma processing and the complete dispersion of the powders

Research Project

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Project/Area Number 19360334
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionNational Institute for Materials Science

Principal Investigator

ISHIGAKI Takamasa  National Institute for Materials Science, 生命科学部, 教授 (40343842)

Co-Investigator(Kenkyū-buntansha) RI Jiguang  独立行政法人物質・材料研究機構, ナノセラミックスセンター, 主任研究員 (90354381)
SATO Kimitoshi  独立行政法人物質・材料研究機構, ナノセラミックスセンター, NIMS ポスドク研究員 (40421408)
KAMIYA Hidehiro  東京農工大学, 大学院・共生科学技術研究院, 教授 (20183783)
Project Period (FY) 2007 – 2009
Keywordsプラズマ処理 / ナノ粒子 / 発光特性 / 磁気特性 / 粒子分散
Research Abstract

Synthesis of functional nano-structured powders has been developed through reactive thermal plasma processing. Nano-sized titanium oxide powders has been prepared by the oxidation of solid and liquid precursors. The plasma-synthesized TiO_2 nano-particles showed phase preferences different from those synthesized by conventional wet processes. Nano-sized particles of high crystallinity and non-equilibrium chemical composition were formed by one-step via reactive thermal plasma processing. Also, high dispersion behavior of plasma-synthesized nanopowders was recognized. The ultrasonically irradiated suspensions show aggregate sizes close to the primary particle sizes evaluated by an image analysis. Ultrasonic irradiation was shown to be a powerful way to disperse nanoparticles even in concentrated aqueous suspensions.

  • Research Products

    (45 results)

All 2010 2009 2008 2007

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (20 results) Book (1 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Synthesis of Pure, Crystalline (Ba, Sr)TiO3Nano-Sized Powders in RF Induction Thermal Plasma2010

    • Author(s)
      小林法夫, 石垣隆正, 渡辺隆行, 李継光
    • Journal Title

      International Journal of Applied Ceramic Technology vol.7(印刷中)

    • Peer Reviewed
  • [Journal Article] Oxidation-Resistant Silica Coating on Gas-Phase-Reduced Iron Nanoparticles and Influence on Magnetic Properties2009

    • Author(s)
      冷永華, 佐藤仁俊, 李継光, 石垣隆正, 吉田貴行, 神谷秀博
    • Journal Title

      Journal of Physical Chemistry C vol.113

      Pages: 16681-16685

    • Peer Reviewed
  • [Journal Article] Iron nanoparticles Dispersible in Both Ethanol and Water for Direct Silica Coating2009

    • Author(s)
      冷永華, 佐藤仁俊, 李継光, 石垣隆正, 飯島志行, 神谷秀博, 吉田貴行
    • Journal Title

      Powder Technology vol.196

      Pages: 80-84

    • Peer Reviewed
  • [Journal Article] 針状鉄コバルトナノ粒子の耐酸化シリカ被覆2009

    • Author(s)
      佐藤仁俊, 飯島志行, 冷永華, 李継光, 倉嶋敬二, 吉田貴行, 神谷秀博, 石垣隆正
    • Journal Title

      粉体および粉末冶金 56巻

      Pages: 232-235

    • Peer Reviewed
  • [Journal Article] Cobalt-Doped TiO2 Nanocrysatallites: Radio-Frequency Thermal Plasma Processing, Phase Structure, and Magnetic Properties2009

    • Author(s)
      李継光、Robert Buechel、磯部雅朗、森孝雄、石垣隆正
    • Journal Title

      ournal of Physical Chemistry C vol.113

      Pages: 8009-8015

    • Peer Reviewed
  • [Journal Article] Synthesis of Functional TiO2-Based Nanoparticles in RF Induction Thermal Plasma2008

    • Author(s)
      石垣隆正、李継光
    • Journal Title

      Pure and Applied Chemistry vol.80

      Pages: 1971-1979

    • Peer Reviewed
  • [Journal Article] Ultrasonic Dispersion of TiO2 Nanoparticles in Aqueous Suspension2008

    • Author(s)
      佐藤仁俊、李継光、神谷秀博、石垣隆正
    • Journal Title

      Journal of the American Ceramic Society vol.91

      Pages: 2481-2487

    • Peer Reviewed
  • [Journal Article] Phase formation and luminescence properties in Eu3+-doped TiO2 nanoparticles prepared by thermal plasma pyrolysis of aqueous solutions2008

    • Author(s)
      池田征史、李継光、小林法夫、守吉佑介、浜中廣見、石垣隆正
    • Journal Title

      Thin Solid Films vol.516

      Pages: 6640-6644

    • Peer Reviewed
  • [Journal Article] Nonequilibrium Situations in a Pulse-Modulated Ar-H2 Inductively Coupled Thermal Plasma for Hydrogen Doping2008

    • Author(s)
      R. Ye、石垣隆正
    • Journal Title

      Thin Solid Films vol.516

      Pages: 4407-4414

    • Peer Reviewed
  • [Journal Article] Spherical Submicron-Size Copper Powders Coagulated from a Vapor Phase in RF Induction Thermal Plasma2008

    • Author(s)
      小林法夫、川上裕二、鎌田啓嗣、李継光、R. Ye、渡辺隆行、石垣隆正
    • Journal Title

      Thin Solid Films vol.516

      Pages: 4402-4406

    • Peer Reviewed
  • [Journal Article] Defect-Mediated Photoluminescence Dynamics of Eu3+-Doped TiO2 Nanocrystals Revealed at the Single-Particle or Single-Aggregate Level2008

    • Author(s)
      立川貴士、石垣隆正、李継光、藤塚守、真嶋哲朗
    • Journal Title

      Angewandte Chemie International Edition vol.47

      Pages: 5348-5352

    • Peer Reviewed
  • [Journal Article] 超音波分散した酸化チタンナノ粒子スラリーの安定性2008

    • Author(s)
      佐藤仁俊、李継光、神谷秀博、石垣隆正
    • Journal Title

      粉体および粉末冶金 55巻

      Pages: 263-269

    • Peer Reviewed
  • [Journal Article] Energy Transfer Enables 1. 53μm Photoluminescence from Erbium-Doped TiO2 Semiconductor Nanocrystals Synthesized by Ar/O2 RF Thermal Plasma2008

    • Author(s)
      李継光, X.H. Wang, C.C. Tang, 石垣隆正, S. Tanaka
    • Journal Title

      Journal of the American Ceramic Society vol.91

      Pages: 2032-2035

    • Peer Reviewed
  • [Journal Article] Synthesis of Ceramic Nanoparticles with Non-Equilibrium Crystal Structures and Chemical Compositions by Controlled Thermal Plasma Processing2008

    • Author(s)
      石垣隆正
    • Journal Title

      Journal of the Ceramic Society of Japan vol.116

      Pages: 462-470

    • Peer Reviewed
  • [Journal Article] nfluence of Solid Fraction on the Optimum Molecular Weight of Polymer Dispersants in Aqueous TiO2 Nanoparticle Suspensions2007

    • Author(s)
      佐藤仁俊、S. Kondo、M. Tsukada, 石垣隆正、神谷秀博
    • Journal Title

      Journal of the American Ceramic Society vol.90

      Pages: 3401-3406

    • Peer Reviewed
  • [Journal Article] Chlorinated nanocrystalline TiO2 Powders via One-Step Ar/O2 Radio Frequency Thermal Plasma Oxidizing Mists of TiCl3 Solution: Phase Structure and Photocatalytic Performance2007

    • Author(s)
      李継光、池田征史、C. Tang、守吉佑介、浜中廣見、石垣隆正
    • Journal Title

      Journal of Physical Chemistry C vol.111

      Pages: 18018-18024

    • Peer Reviewed
  • [Journal Article] Size Control of TiO2 Nanoparticles Prepared by Oxidative Pyrolysis of Liquid-Mist Precursors in RF Thermal Plasma2007

    • Author(s)
      石垣隆正、李継光, 他3名
    • Journal Title

      Key Engineering Materials vol.352

      Pages: 119-124

    • Peer Reviewed
  • [Journal Article] Synthesis of Functional Nanocrystallites through Reactive Thermal Plasma Processing2007

    • Author(s)
      石垣隆正、李継光
    • Journal Title

      Science and Technology of Advanced Materials vol.8

      Pages: 617-623

    • Peer Reviewed
  • [Journal Article] Numerical Modeling of an Ar-H2 Radio-Frequency Plasma Reactor under Thermal and Chemical Nonequilibrium Conditions2007

    • Author(s)
      R. Ye、Anthony B. Murphy、石垣隆正
    • Journal Title

      Plasma Chemistry and Plasma Processing vol.27

      Pages: 189-204

    • Peer Reviewed
  • [Journal Article] Control of Particle Size and Phase Formation of TiO2 Nanoparticles Synthesized in RF Induction Plasma2007

    • Author(s)
      李継光、池田征史、R. Ye、守吉佑介、石垣隆正
    • Journal Title

      Journal of Physics D-Applied Physics vol.40

      Pages: 2348-2353

    • Peer Reviewed
  • [Presentation] Oxidation-resistant silica coating on iron nanoparticles2009

    • Author(s)
      石垣隆正
    • Organizer
      The 18th International Simposium on Processing and Fabrication of Advanced Materials
    • Place of Presentation
      東北大学、仙台市
    • Year and Date
      2009-12-14
  • [Presentation] 高周波熱プラズマの無機材料合成への応用2009

    • Author(s)
      石垣隆正
    • Organizer
      電気学会北陸支部学術講演会
    • Place of Presentation
      金沢大学, 金沢市
    • Year and Date
      2009-12-02
  • [Presentation] Phase Structure and Photoluminescent Properties of TiO2: (Eu3+-Nb5+) Nanopowders Synthesized via Ar/O2 Radio Frequency Thermal Plasma2009

    • Author(s)
      張晨寧, 李継光, 冷永華, 打越哲郎, 渡辺隆行, 石垣隆正
    • Organizer
      The 26th International Japan-Korea Seminar on Ceramics
    • Place of Presentation
      つくば国際会議場、つくば市
    • Year and Date
      2009-11-24
  • [Presentation] Synthesis of functional TiO2 nanoparticles in RF induction thermal plasma and their dispersion behavior (Invited lecture)2009

    • Author(s)
      石垣隆正
    • Organizer
      6th China International Conference on High-Performance Ceramics
    • Place of Presentation
      Victories Hotel, Harbin, China
    • Year and Date
      2009-08-17
  • [Presentation] Synthesis of TiO2 Nano-Size Powders in Reactive Thermal Plasma and Their Dispersion Behavior2009

    • Author(s)
      石垣隆正
    • Organizer
      NIMS Symposium on the Social Acceptance of Nanomaterials
    • Place of Presentation
      つくば国際会議場, つくば市
    • Year and Date
      2009-07-24
  • [Presentation] (Eu3+-Nb5+)-Codoped TiO2 Nanopowders Synthesized via Ar/O2 Radio Frequency Thermal Plasma Oxidation Processing: Phase composition and Photoluminescence Properties through energy transfer2009

    • Author(s)
      張晨寧, 李継光, 打越哲郎, 渡辺隆行, 石垣隆正
    • Organizer
      第22回プラズマ材料科学シンポジウム
    • Place of Presentation
      東京大学、文京区
    • Year and Date
      2009-06-16
  • [Presentation] Non-Equilibrium Conditions in Plasma-Synthesized TiO2 Nanoparticles and Their Excellent Dispersion Properties2008

    • Author(s)
      石垣隆正
    • Organizer
      The 1st International Symposium on Advanced Synthesis and Processing Technology for Materials (ASPT08)
    • Place of Presentation
      武漢、中国
    • Year and Date
      20081114-20081117
  • [Presentation] Synthesis of Barium Titanate Nano-Size Powders in RF Thermal Plasma from Liquid Precursor2008

    • Author(s)
      小林法夫、李継光、渡辺隆行、石垣隆正
    • Organizer
      2nd International Conference on Science and Technology for Advanced Ceramics
    • Place of Presentation
      OVTA、千葉
    • Year and Date
      20080530-20080601
  • [Presentation] 高度制御熱プラズマによるセラミック材料の非平衡・高速合成2008

    • Author(s)
      石垣隆正
    • Organizer
      日本セラミックス協会2008年年会
    • Place of Presentation
      長岡技術科学大学、長岡市
    • Year and Date
      2008-03-22
  • [Presentation] Room temperature magnetic properties of thermal plasma synthesized cobalt-doped TiO2 nanopowders2008

    • Author(s)
      李継光、石垣隆正, 他2名
    • Organizer
      第46回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋国際会議場、名古屋
    • Year and Date
      2008-01-11
  • [Presentation] 高分散した鉄ナノ粒子への耐酸化シリカ被覆2007

    • Author(s)
      石垣隆正、佐藤仁俊、李継光、神谷秀博, 他1名
    • Organizer
      粉体粉末冶金協会平成19年度秋季大会
    • Place of Presentation
      京都工芸繊維大学、京都市
    • Year and Date
      2007-11-19
  • [Presentation] Non-Equilibrium Doping, Phase Selection and Functionalization in TiO2 Nanopaticles Prepared by RF Thermal Plasma Methods2007

    • Author(s)
      石垣隆正
    • Organizer
      IUPAC 3rd International Symposium on Novel Materials and Synthesis
    • Place of Presentation
      Tianyi Hotel、上海、中国
    • Year and Date
      2007-11-18
  • [Presentation] Dispersion stability under ultrasonication of TiO2 nanoparticles in water2007

    • Author(s)
      佐藤仁俊、李継光、石垣隆正、神谷秀博
    • Organizer
      7th Pacific Rim International Conference on Ceramic and Glass Technology
    • Place of Presentation
      Shanghai International Convention Center、上海、中国
    • Year and Date
      2007-11-13
  • [Presentation] Phase structure and photocatalytic properties of TiO2 nanopowders synthesized by Ar/O2 RF thermal plasma oxidization of atomized TiCl3 solution2007

    • Author(s)
      李継光、石垣隆正, 他2名
    • Organizer
      7th Pacific Rim International Conference on Ceramic and Glass Technology
    • Place of Presentation
      Shanghai International Convention Center、上海、中国
    • Year and Date
      2007-11-12
  • [Presentation] Phase Formation and Magnetic Properties of TiO2 Nanoparticles Doped with Transient Metals Prepared in Thermal Plasma2007

    • Author(s)
      石垣隆正、李継光
    • Organizer
      6th Pacific Rim International Conference on Advanced Materials
    • Place of Presentation
      ICC Jeju、Jeju Island、韓国
    • Year and Date
      2007-11-08
  • [Presentation] Influence of Quenching Condition on the Phase Formation and Luminescence Property of Eu3+-Doped TiO2 Prepared in Thermal Plasma2007

    • Author(s)
      池田征史、李継光, 他3名、石垣隆正
    • Organizer
      6th Pacific Rim International Conference on Advanced Materials
    • Place of Presentation
      ICC Jeju、Jeju Island、韓国
    • Year and Date
      2007-11-06
  • [Presentation] 高分散した針状鉄ナノ粒子への耐酸化シリカ被覆2007

    • Author(s)
      佐藤仁俊、李継光, 他1名、石垣隆正、神谷秀博
    • Organizer
      日本セラミックス協会第20回秋季シンポジウム
    • Place of Presentation
      名古屋工業大学、名古屋市
    • Year and Date
      2007-09-12
  • [Presentation] RF thermal plasma processing and room temperature ferromagnetic properties of cobalt doped TiO2 nanopowders2007

    • Author(s)
      李継光、石垣隆正, 他2名
    • Organizer
      18th International Symposium on Plasma Chemistry
    • Place of Presentation
      京都大学、京都市
    • Year and Date
      2007-08-28
  • [Presentation] Synthesis of functional TiO2-based nanoparticles in RF induction thermal plasma2007

    • Author(s)
      石垣隆正、李継光
    • Organizer
      8th International Symposium on Plasma Chemistry
    • Place of Presentation
      京都大学、京都市
    • Year and Date
      2007-08-27
  • [Presentation] 光熱プラズマによる高結晶性酸化チタンナノ粒子の一段プロセス合成2007

    • Author(s)
      石垣隆正
    • Organizer
      粉体工学会第42回技術討論会
    • Place of Presentation
      アルカディア市ヶ谷、千代田区
    • Year and Date
      2007-06-19
  • [Book] 最新フィラー技術全集(分担執筆;超音波照射による酸化チタンナノ粒子の液中への分散技術)2008

    • Author(s)
      佐藤仁俊、神谷秀博、石垣隆正、技術情報協会
    • Total Pages
      227-233
  • [Patent(Industrial Property Rights)] 炭素被覆形強磁性金属球形粒子及びその製造方法2010

    • Inventor(s)
      石垣隆正, シュー・ジアヤン, 田中秀樹
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・第4457227号
    • Acquisition Date
      2010-02-19
  • [Patent(Industrial Property Rights)] Zinc oxide phosphor, process for producing the same and light emitting device2009

    • Inventor(s)
      大橋直樹、石垣隆正、田口広之、羽田肇、関口孝司
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      US・7,535,162 B2
    • Acquisition Date
      2009-05-19
  • [Patent(Industrial Property Rights)] ブルッカイト型二酸化チタンを製造する方法、単分散ブルッカイト型二酸化チタン団粒、光触媒及びフォトニック結晶2009

    • Inventor(s)
      李継光、石垣隆正
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許・第4411385号
    • Acquisition Date
      2009-11-29
  • [Patent(Industrial Property Rights)] 磁性超微粒子及びその製造方法2007

    • Inventor(s)
      神谷秀博、飯島志行、石垣隆正、佐藤仁俊
    • Industrial Property Rights Holder
      国立大学法人東京農工大学、独立行政法人物質・材料研究機構
    • Industrial Property Number
      特許、特願・2007-1559
    • Filing Date
      2007-06-13

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Published: 2011-06-18   Modified: 2016-04-21  

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