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2008 Fiscal Year Final Research Report

Synthesis of Mordenite Nanocrystals and its Application to Structured Catalytic Reactor for Complicated Reactions

Research Project

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Project/Area Number 19360356
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

MASUDA Takao  Hokkaido University, 大学院工学研究科, 教授 (20165715)

Co-Investigator(Kenkyū-buntansha) TAGO Teruoki  北海道大学, 大学院・工学研究科, 准教授 (20304743)
Project Period (FY) 2007 – 2008
Keywords反応装置 / 構造体触媒反応器 / 触媒膜 / ゼオライトナノクリスタル / モルデナイト / 界面活性剤 / アルキル化反応 / ナフタレン
Research Abstract

水/界面活性剤/有機溶媒を利用するゼオライト合成法により, モルデナイト結晶のナノサイズ化に成功した. ナノサイズモルデナイト結晶の外表面酸点を, 有機シラン化合物由来シリカにより選択的に不活性化させた構造性活性点を有する触媒の開発, およびモルデナイトナノクリスタルを積層させた膜型構造体触媒反応器の開発に成功した. 同モルデナイト触媒はナフタレンからの2,6-ジメチルナフタレン選択合成に高活性を示した.

  • Research Products

    (18 results)

All 2009 2008 2007 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (12 results)

  • [Journal Article] Synthesis of Mono-Dispersed Silicalite-1Nanocrystals in Water-Surfactant-Organic Solvent2009

    • Author(s)
      Tago T., Iwakai K., Nishi M., and Masuda T.
    • Journal Title

      J. Nanosc. Nanotechnol 9(1)

      Pages: 612-617

    • Peer Reviewed
  • [Journal Article] Measurement of Intracrystalline Diffusivityof Benzene within MFI-type Zeolite from Bulk Benzene/ Cyclohexane Liquid Phase2008

    • Author(s)
      Nakasaka Y., Tago T., Odate K., and Masuda T.
    • Journal Title

      Micropor. Mesopor. Mater 112

      Pages: 162-169

    • Peer Reviewed
  • [Journal Article] ゼオライトナノクリスタル新規合成法の開発2008

    • Author(s)
      多湖輝興・岩貝和幸・増田隆夫
    • Journal Title

      ケミカルエンジニヤリング 53(6)

      Pages: 432-439

  • [Journal Article] Preparation of hydrophilicsilicalite-1 nanocrystal-layered membranesand their application to separating waterfrom water-acetone solution2008

    • Author(s)
      Tago T., Nakasaka Y., Kayoda A., and Masuda T.
    • Journal Title

      Micropor. Mesopor. Mater. 115

      Pages: 176-183

    • Peer Reviewed
  • [Journal Article] Control of Acid-Site Location of MFIZeolite by Catalytic Cracking of Silane andits Application to Olefin Synthesis from Acetone

    • Author(s)
      Tago T., Sakamoto M., Iwakai K., Nishihara H., Mukai S. R., Tanaka T. and Masuda T
    • Journal Title

      J. Chem. Eng. Jpn. (印刷中)

    • Peer Reviewed
  • [Journal Article] Preparation for Size-Controlled MOR Zeolite Nanocrystal using Water/Surfactant/Organic Solvent

    • Author(s)
      Tago T., Aoki D., Iwakai K., and Masuda T
    • Journal Title

      J. Nanosc. Nanotechnol Top. Cat. (印刷中)

    • Peer Reviewed
  • [Presentation] Measurement of liquid phasebenzene diffusivity within porous materialsusing Raman spectroscopy2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Year and Date
      20081206-07
  • [Presentation] Preparation of ZSM-5 nanocrystal-layeredmembrane and its application to MTOreaction2008

    • Author(s)
      K. Iwakai, T. Tago and T. Masuda
    • Organizer
      21th International Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Year and Date
      20081206-07
  • [Presentation] Preparation ofnano-crystalline BEA type zeolite byhydrothermal synthesis inwater/surfactant/organic solvent2008

    • Author(s)
      A. Hyojo, D. Aoki, K. Iwakai, T. Tagoand and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Year and Date
      20081206-07
  • [Presentation] Olefin synthesis fromacetone over BEA zeolite2008

    • Author(s)
      S. Ikeda, M. Sakamoto, H. Konno, T. Tagoand and T. Masuda
    • Organizer
      21thInternational Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Saga University, Japan
    • Year and Date
      20081206-07
  • [Presentation] Control of Acid-Site Location of MFI zeolite by Catalytic Cracking of Silaneand its Application of olefin Synthesis from Acetone2008

    • Author(s)
      T. Tago, M. Sakamoto, K. Iwakai1, H.Nishihara, S. R. Mukai, T. Tanaka and T.Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Year and Date
      20080907-11
  • [Presentation] Liquid phase Diffusivity of Benzene within Mesoporous Materials Measured by Laser Raman Technique2008

    • Author(s)
      Y. Nakasaka, T. Tago, K. Yano and T.Masuda
    • Organizer
      20th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      Kyoto, Kyoto International Conference Center, Japan
    • Year and Date
      20080907-11
  • [Presentation] Synthesis of hydrophilicsilicalite-1 nanocrystal-layered membranesfor separation of water from aqueous alcoholsolutions by pervaporation2008

    • Author(s)
      Y. Nakasaka, T. Tago, T. Ichikawa, and T. Masuda
    • Organizer
      10th International Conferences on Inorganic Membranes
    • Place of Presentation
      Tokyo, Waseda University, Japan
    • Year and Date
      20080818-22
  • [Presentation] Synthesis of Nano-Sized MORZeolite in Water/Surfactant/Organic Solvent2008

    • Author(s)
      T. Tago, D. Aoki, M. Ohori, K. Iwakai, T.Masuda
    • Organizer
      ICC14 Pre-Symposium
    • Place of Presentation
      Kyoto, Kyoto University, Japan
    • Year and Date
      20080709-11
  • [Presentation] Preparation of Mono-Dispersed MFI-type Zeolite Nanocrystals via Hydrothermal Synthesis in Water/ Surfactant/Oil Solution2007

    • Author(s)
      K. Iwakai, D. Aoki, T. Tago and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, HanbatNational University, Korea
    • Year and Date
      20071130-1202
  • [Presentation] In-situ measurement of intracrystalline diffusivity of benzene withinsilicalite-1 in liquid phase2007

    • Author(s)
      Y. Nakasaka, T. Tago, K. Odate and T. Masuda
    • Organizer
      20th International Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Hanbat National University, Korea (2007)
    • Year and Date
      20071130-1202
  • [Presentation] Preparation of hydrophilicsilicalite-1 nanocrystal-layered membranesand their application to separating waterfrom water-acetone solution2007

    • Author(s)
      T. Tago, A. Kayoda, K. Iwakai, Y. Nakasaka and T. Masuda
    • Organizer
      4th International Zeolite Membrane Meeting
    • Place of Presentation
      Zaragoza, University of Zaragoza, Spain
    • Year and Date
      20070722-25
  • [Presentation] Preparation of Size-controlled ZSM-5 Zeolite Nanocrystals via Hydrothermal Synthesis using Water/Surfactant/Oil Solution2007

    • Author(s)
      T. Tago, K. Iwakai, M. Nishi and T. Masuda
    • Organizer
      11th Korean-Japan Symposiumon Catalyst
    • Place of Presentation
      Seoul, Yonsei University, Korea
    • Year and Date
      20070521-23

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Published: 2010-06-10   Modified: 2016-04-21  

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