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2009 Fiscal Year Final Research Report

Technology to Control Heterogeneous Catalytic Reactions by Forced Temperature Cycling

Research Project

  • PDF
Project/Area Number 19360360
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionThe University of Tokushima

Principal Investigator

SOTOWA Ken-ichiro  The University of Tokushima, 大学院・ソシオテクノサイエンス研究部, 准教授 (00336009)

Co-Investigator(Kenkyū-buntansha) SUGIYAMA Shigeru  徳島大学, 大学院・ソシオテクノサイエンス研究部, 教授 (70175404)
KATOH Masahiro  徳島大学, 大学院・ソシオテクノサイエンス研究部, 准教授 (80274257)
Project Period (FY) 2007 – 2009
Keywords反応率 / 吸着 / 触媒 / 選択率 / 非定常
Research Abstract

Chemical reactors are usually operated at a steady state. In this work, the effect of unsteady state operations on the conversion of catalytic reactions was studied. A chemical reactor particularly suited for temperature cycling operation was developed, and in an experimental study conducted using the reactor, it was demonstrated that a higher conversion can be achieved by employing a temperature cycling operation. Also, a result from a theoretical study showed that there are cases where further acceleration of chemical reaction can be expected.

  • Research Products

    (12 results)

All 2010 2009 2008 2007 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (9 results)

  • [Journal Article] Redox Nature of Fe-incorporated Magnesium ortho-Vanadate as a Catalyst for the Oxidative Dehydrogenation of Propane2007

    • Author(s)
      S. Sugiyama, T. Osaka, Y. Hirata, Y. Kondo, K. Nakagawa, K.-I. Sotowa
    • Journal Title

      Journal of Chemical Engineering of Japan Vol.40,No.12

      Pages: 1064-1071

    • Peer Reviewed
  • [Journal Article] Application of a Microreactor in the Oxidative Dehydrogenation of Propane to Propylene on Calcium Hydroxyapatite and Magnesium ortho-Vanadate Doped and Undoped with Palladium

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K.-I. Sotowa
    • Journal Title

      Journal of Chemical Engineering of Japan (in press)

    • Peer Reviewed
  • [Journal Article] he Effect of Carbon Monoxide on the Hydrogen Permeability of a Palladium Membrane

    • Author(s)
      M. Katoh, K. Nishihara, K. Kinouchi, K. Chohama, T. Horikawa, T. Tomida, K.-I. Sotowa
    • Journal Title

      International Journal of Modern Physics B (in press)

    • Peer Reviewed
  • [Presentation] Periodic operation Steady state Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Dydroxyapatite using Microreactor2010

    • Author(s)
      S. Sugiyama, N. Sugimoto, A. Ozaki, Y. Furukawa, K. Nakagawa, K. -I. Sotowa
    • Organizer
      11th International Conference on Microeaction Technology
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20100300
  • [Presentation] Reaction Kinetics and Conversion of CO Oxidation under Forced Temperature Cycling2009

    • Author(s)
      D. Okuyama, K. -I. Sotowa, K. Nakagawa, S. Sugiyama
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      20091200
  • [Presentation] Oxidative Dehydrogenation of Propane in Microreactor under Steady State and Unsteady State Operations2009

    • Author(s)
      N. Sugimoto, K. Nakagawa, K. -I. Sotowa, S. Sugiyama
    • Organizer
      22nd Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      20091200
  • [Presentation] Reaction Mechanism and the Effect of Forced Temperature Cycling on the Reactor Performance2009

    • Author(s)
      K. -I. Sotowa, K. Nakagawa, S. Sugiyama
    • Organizer
      AIChE Annual Meeting 2009
    • Place of Presentation
      Nashville, USA
    • Year and Date
      20091100
  • [Presentation] 温度周期操作下における不均一触媒反応の平均反応速度と素反応の温度依存性の関係2009

    • Author(s)
      外輪健一郎, 黒田勝也, 奥山大輔, 杉山茂, 中川敬三
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島
    • Year and Date
      20090900
  • [Presentation] Effect of Feed Concentration on CO Oxidation under Forced Temperature Cycling2008

    • Author(s)
      K. Kuroda, K. -I. Sotowa, S. Sugiyama, K. Nakagawa
    • Organizer
      21st Symposium on Chemical Engineering
    • Place of Presentation
      Saga, Japan
    • Year and Date
      20081200
  • [Presentation] Time-Average Reaction rate of CO Oxidation over Pt/Al2O3 Catalyst under Forced Temperature Cycling2008

    • Author(s)
      K. -I. Sotowa, K. Kuroda, K. Nakagawa, S. Sugiyama
    • Organizer
      International Workshop on Process Intensification
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      20081000
  • [Presentation] 温度周期操作デバイスの熱的挙動と一酸化炭素の酸化反応への適用2008

    • Author(s)
      石花健太, 外輪健一郎, 黒田勝也, 中川敬三, 杉山茂
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      浜松
    • Year and Date
      20080300
  • [Presentation] Oxidation of Carbon Monoxide under Forced Temperature Cycling2007

    • Author(s)
      K. Kuroda, K. Ishihana, K. -I. Sotowa, S. Sugiyama, K. Nakagawa
    • Organizer
      20th Symposium on Chemical Engineering
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      20071200

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Published: 2011-06-18   Modified: 2016-04-21  

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