2009 Fiscal Year Final Research Report
Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands
Project/Area Number |
19550061
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Nagoya University |
Principal Investigator |
MATSUMOTO Tsuyoshi Nagoya University, 大学院・理学研究科, 助教 (50311717)
|
Project Period (FY) |
2007 – 2009
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Keywords | 多核金属錯体 / チオラート / スルフィド / ニッケル / 鉄硫黄クラスター / 大環状 / 三座チオラート配位子 / クラスター |
Research Abstract |
New deca- and dodeca-nuclear cyclic nickel (II) complexes bridged by thioether-thiolate hybrid ligands and tert-butanethiolate ligands have been synthesized, which represents a new addition to the family of large cyclic Ni thiolate cluster. The site-selective nickel-thiolate bonds of the decanuclear complex were cleaved by treatment with I_2 to form a pentanuclear complex assuming a semicircular core structure. We have also synthesized a 3:1 site-differentiated [4Fe-4S] clusters carrying a tridentate thiolate ligand and a carboxylate ligand.
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[Journal Article] Host plant genome overcomes the lack of bacterial gene for symbiotic nitrogen fixation2009
Author(s)
Hakoyama, T. ; Niimi, K. ; Watanabe, H. ; Tabata, R. ; Matsubara, J. ; Sato, S. ; Nakamura, Y. ; Tabata, S. ; Li, J. ; Matsumoto, T. ; Tatsumi, K. ; Nomura, M. ; Tajima, S. ; Ishizaka, M; Yano, K. ; Imaizumi-Anraku, H. ; Kawaguchi, M. ; Kouchi, H. ; Suganuma, N.
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Journal Title
Nature 462
Pages: 514-517
Peer Reviewed
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[Journal Article] Evidence for a Rapid Degenerate Hetero-Cope-type Rearrangement in Cp*W(S)2-CH2-CH2-CH=CH22009
Author(s)
Eweiner, F. ; Senda, S. ; Bergander, K. ; Muck-Lichtenfeld, C. ; Grimme, S. ; Frohlich, R. ; Aoyama, M. ; Kawaguchi, H. ; Ohki, Y. ; Matsumoto, T. ; Kehr, G. ; Tatsumi, K. ; Erker, G.
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Journal Title
Chem. Asian J. 4
Pages: 1830-1833
Peer Reviewed
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[Remarks] 成果は論文誌の表紙等に取り上げられた
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[Remarks] Chem Asian J. 2008, 3号の表紙
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[Remarks] Angew. Chem. Int. Ed. 2010 (in press)の中表紙