2009 Fiscal Year Final Research Report
syntheses of conducting polymer thin films in supercritical carbon dioxide and their properties
| Project/Area Number |
19550127
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
YUASA Makoto Tokyo University of Science, 理工学部・工業化学科, 教授 (40192801)
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| Project Period (FY) |
2007 – 2009
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| Keywords | 超臨界二酸化炭素 / 導電性高分子 / ポルフィリン / 電解重合 / 薄膜 / チオフェン / ピロール / アニリン |
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| Research Abstract |
As one of investigations of conductive polymer thin films, monomers bearing porphyrin groups were elecro-polymerized under supercritical carbon dioxide environment to give closed and leveled polymer thin films. The polymer thin films had active sites of porphyrins, which had potential to act as oxygen reduction catalysts. We obtained valuable and useful knowledge and information for preparations of polymer thin films under supercritical carbon dioxide environment, their investigations to fuel cell cathode catalysts, etc.
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