2009 Fiscal Year Final Research Report
Deperopment of solvent-free reaction process using solid desperse
| Project/Area Number |
19550154
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
SASAKI Yo Kinki University, 理工学部, 講師 (70205871)
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| Co-Investigator(Kenkyū-buntansha) |
IWASAKI Mitsunobu 近畿大学, 理工学部, 准教授 (20278740)
MORIMOTO Jyunji 近畿大学, 理工学部, 教授 (30088471)
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| Co-Investigator(Renkei-kenkyūsha) |
ICHIHARA Junko 大阪大学, 産業科学研究所, 助教 (60110772)
YAMAGUCHI Syunro 大阪大学, 産業科学研究所, 助教 (40167698)
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| Project Period (FY) |
2007 – 2009
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| Keywords | グリーンケミストリー / 無溶媒反応 / 触媒 / 粉体分散媒 |
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| Research Abstract |
We applied the solvent-free reaction system for cyclooctene photoepxdation under oxygenatomosphere irradiating of black light over mixture of SiO_2 powderdisperse and photocatalyst powder. we have previously developed A new synthetic method of sulfoxides and sulfones using solvent-free oxidations of sulfides with urea-hydrogen peroxide complex (urea-H_2O_2)and tetrabutylammonium phosphomolybdate catalyst on fluorapatite ((Bu_4N)_3[PMo_<12>O_<40>]/FAp). For chiral sulfoxides, our methodology included the use of chial auxiliaries that were shown to affect the asymmetric oxidations.
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