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2009 Fiscal Year Final Research Report

Study on bio-polyester synthesis from recycled alkenoic acids

Research Project

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Project/Area Number 19681008
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

TSUGE Takeharu  Tokyo Institute of Technology, 大学院・総合理工学研究科, 准教授 (70332260)

Project Period (FY) 2007 – 2009
Keywordsポリヒドロキシアルカン酸 / 酵素合成 / 連鎖移動 / ケミカルリサイクル / 不飽和脂肪酸 / 熱分解
Research Abstract

The aim of this study is to develop the chemical recycling system of polyhydroxyalkanoate (PHA) by integrating pyrolysis and enzymatic or microbial synthesis of PHA. The major product obtained from pyrolysis of PHA, alkenoic acids, is the key material of this recycling system. We demonstrated that alkenoic acids are able to be re-synthesized to original PHA.

  • Research Products

    (13 results)

All 2010 2009 2008 2007 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (9 results) Remarks (1 results)

  • [Journal Article] In vitro synthesis of polyhydroxyalkanoate catalyzed by class II and III PHA synthases: a useful technique for surface coatings of a hydrophobic support with PHA2010

    • Author(s)
      Sato, S., Minato, M., Kikkawa, Y., Abe, H., Tsuge, T.
    • Journal Title

      J. Chem. Technol. Biotechnol. 85

      Pages: 779-782

    • Peer Reviewed
  • [Journal Article] Polyhydroxyalkanoate film formation and synthase activity during in vitro and in situ polymerization on hydrophobic surfaces2008

    • Author(s)
      Sato S, Ono Y, Mochiyama Y, Sivaniah E, Kikkawa Y, Sudesh K, Hiraishi T, Doi Y, Abe H, Tsuge T
    • Journal Title

      Biomacromolecules 9

      Pages: 2811-2818

    • Peer Reviewed
  • [Journal Article] Chain transfer reaction catalyzed by various polyhydroxyalkanoate synthases with poly(ethylene glycol) as an exogenous chain transfer agent Appl.

    • Author(s)
      Tomizawa, S., Saito, Y., Hyakutake, M., Nakamura, Y., Abe, H., Tsuge, T
    • Journal Title

      Microbiol. Biotechenol. (in press)

    • Peer Reviewed
  • [Presentation] 組換え大腸菌によるアルケン酸からの中鎖ポリヒドロキシアルカン酸生合成2010

    • Author(s)
      佐藤俊、石井直樹、阿部英喜、柘植丈治
    • Organizer
      高分子学会、
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-28
  • [Presentation] QCMを用いたPHAナノ薄膜形成過程の解析2009

    • Author(s)
      持山由規子、佐藤俊、阿部英喜、柘植丈治
    • Organizer
      日本生物工学会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-09-23
  • [Presentation] 熱分解クロトン酸からのポリヒドロキシブタン酸酵素再合成の検討2009

    • Author(s)
      吉岡真佐子、佐藤俊、阿部英喜、柘植丈治
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
  • [Presentation] 連鎖移動反応を利用した大腸菌産生ポリエステルのBio-PEGylation2009

    • Author(s)
      富澤哲、阿部英喜、柘植丈治
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-16
  • [Presentation] J・アグス:連鎖移動反応を誘発させた大腸菌が合成するポリエステルの分子量2008

    • Author(s)
      柘植丈治、富澤哲
    • Organizer
      高分子学会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-29
  • [Presentation] ポリエステル重合酵素による疎水表面での重合反応解析2008

    • Author(s)
      佐藤俊、持山由規子、吉川佳広、阿部英喜、柘植丈治
    • Organizer
      高分子学会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-29
  • [Presentation] QCMを用いたポリヒドロキシアルカン酸in vitro重合反応の解析2008

    • Author(s)
      持山由規子、佐藤俊、阿部英喜、柘植丈治
    • Organizer
      高分子学会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
  • [Presentation] R-ヒドラターゼを利用したポリヒドロキシアルカン酸のin vitro重合とAFM観察2007

    • Author(s)
      佐藤俊、小野勇将、吉川佳広、阿部英喜、柘植丈治
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-20
  • [Presentation] 微生物合成ポリエステルの分子量特性2007

    • Author(s)
      柘植丈治、富澤哲、J・アグス、P・カハル、阿部英喜、田口精一
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-20
  • [Remarks]

    • URL

      http://www.iem.titech.ac.jp/tsuge/

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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