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2009 Fiscal Year Final Research Report

Elucidation of molecular mixing state in a nanospace by the small and middle angle X-ray scattering and reverse Monte Carlo method

Research Project

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Project/Area Number 19685002
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionShinshu University

Principal Investigator

IIYAMA Taku  Shinshu University, 理学部, 准教授 (30313828)

Project Period (FY) 2007 – 2009
Keywordsナノ空間 / クラスター / 分子混合 / X線回折 / X線小角散乱 / リバースモンテカルロ / 多孔性固体 / ゆらぎ
Research Abstract

The purpose of this theme is the establishment of measurement and analysis methods of the molecular mixing state in the micropore of various porous solids. X-ray small angle scattering and X-ray diffraction are used as the experimental investigation and reverse Monte Carlo method is used as the analysis method of the micro molecular mixing. X-ray measurement system was optimized to the in situ measurement of adsorption state using parallel incident beam and transmission geometry. This apparatus and analysis method were applied to the some adsorption system such as the activated carbon-sulfate acid-water system. We found the characteristic features of molecules in the micropore such as the formation of the "hydration cluster" which is the cooperative behavior of sulfate ion and water molecules in the micropore. The microscopic description method of molecular mixing state was improved by this study, both of experimental and analysis procedures.

  • Research Products

    (20 results)

All 2010 2009 2008 2007

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (19 results)

  • [Journal Article] Direct determination of intermolecular structure of ethanol adsorbed in micropores using X-ray diffraction and reverse Monte Carlo analysis2009

    • Author(s)
      Taku Iiyama, Kousuke Hagi, Takafumi Urushibara, Sumio Ozeki
    • Journal Title

      Collids and Surfaces A 347

      Pages: 133-141

    • Peer Reviewed
  • [Presentation] 疎水性微小空間中の水の水素結合ネットワーク構造2010

    • Author(s)
      飯山拓, 二村竜祐, 藤崎布美佳, 浜崎亜富, 尾関寿美男, 星川晃範, 石垣徹
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2010-03-29
  • [Presentation] カーボンナノ空間に閉じ込められた水溶液に対するX線散乱法からのアプローチ2009

    • Author(s)
      二村竜祐, 飯山拓, 浜崎亜富, 尾関寿美男
    • Organizer
      第23回日本吸着学会研究発表会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2009-11-28
  • [Presentation] カーボンナノ空間中の有機電解質溶液の構造2009

    • Author(s)
      田中亜季実, 大場友則, 加納博文, 飯山拓, 尾関寿美男, 金子克美
    • Organizer
      第23回日本吸着学会研究発表会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2009-11-27
  • [Presentation] リバースモンテカルロ法によるゼオライトの細孔内吸着分子間構造の解明2009

    • Author(s)
      清家敦子, 飯山拓, 山崎誠志, 浜崎亜富, 尾関寿美男
    • Organizer
      第62回コロイドおよび界面化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2009-09-19
  • [Presentation] カーボンミクロ細孔中におけるナノ硫酸水溶液のXRD及びSAXSによる構造解析2009

    • Author(s)
      二村竜祐, 飯山拓, 浜崎亜富, 尾関寿美男
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
  • [Presentation] リバースモンテカルロ法による細孔内吸着分子構造の解明2009

    • Author(s)
      清家敦子, 飯山拓, 尾関寿美男
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
  • [Presentation] 吸着相のリバースモンテカルロシミュレーションにおける細孔モデルの構築2008

    • Author(s)
      清家敦子, 飯山拓, 尾関寿美男
    • Organizer
      第22回日本吸着学会研究発表会
    • Place of Presentation
      福岡
    • Year and Date
      2008-10-24
  • [Presentation] ナノ空間における硫酸塩水溶液の構造解析2008

    • Author(s)
      二村竜祐, 飯山拓, 尾関寿美男
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-08
  • [Presentation] X-ray diffraction and reverse Monte Carlo technique study of multi-component adsorption on carbon micropore2008

    • Author(s)
      飯山拓, 二村竜祐, 尾関寿美男
    • Organizer
      Symposium on Future Challenges for Carbon-Based Nanoporous Materials
    • Place of Presentation
      千葉
    • Year and Date
      2008-07-11
  • [Presentation] The Determination of Intermolecular Structure of Adsorbed Phase in the Micropore by X-ray techniques and Reverse Monte Carlo Method2008

    • Author(s)
      飯山拓, 羽木孝輔, 清家敦子, 浅見圭一, 清水篤史, 尾関寿美男
    • Organizer
      8th International Symposium on the Characterisation of Porous Solids
    • Place of Presentation
      イギリス・エジンバラ
    • Year and Date
      2008-06-11
  • [Presentation] Molecular Modeling of Activated Carbons for The Reverse Monte Carlo Method of Adsorbed Phase2008

    • Author(s)
      清家敦子, 飯山拓, 尾関寿美男
    • Organizer
      8th International Symposium on the Characterisation of Porous Solids
    • Place of Presentation
      イギリス・エジンバラ
    • Year and Date
      2008-06-11
  • [Presentation] The Direct Determination of Intermolecular Structure of Pollutants in Micropore Using in situ X-Ray Diffraction2008

    • Author(s)
      飯山拓, 尾関寿美男
    • Organizer
      5th International Conference Interfaces Against Pollution 2008
    • Place of Presentation
      京都
    • Year and Date
      2008-06-02
  • [Presentation] カーボンミクロ細孔中の硫酸ナノ水溶液の構造解析2008

    • Author(s)
      二村竜祐, 飯山拓, 尾関寿美男
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
  • [Presentation] 細孔内吸着分子集団の構造解析~実験でつなぐ吸着現象のミクロとマクロ2007

    • Author(s)
      飯山拓
    • Organizer
      第21回日本吸着学会研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2007-09-28
  • [Presentation] X線による微小空間中での硫酸水和構造の検討2007

    • Author(s)
      二村竜祐, 飯山拓, 尾関寿美男
    • Organizer
      第21回日本吸着学会研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2007-09-27
  • [Presentation] 二酸化炭素の活性炭細孔内における吸着構造の解明2007

    • Author(s)
      羽木孝輔, 飯山拓, 尾関寿美男
    • Organizer
      第60回コロイドおよび界面化学討論会
    • Place of Presentation
      松本
    • Year and Date
      2007-09-22
  • [Presentation] カーボンミクロ孔中での硫酸イオンの水和構造の検討2007

    • Author(s)
      二村竜祐, 飯山拓, 尾関寿美男
    • Organizer
      第60回コロイドおよび界面化学討論会
    • Place of Presentation
      松本
    • Year and Date
      2007-09-22
  • [Presentation] 制限空間内におけるエタノール分子の水素結合構造および相転移現象2007

    • Author(s)
      飯山拓, 羽木孝輔, 浅見圭一, 清水篤史, 尾関寿美男
    • Organizer
      第60回コロイドおよび界面化学討論会
    • Place of Presentation
      松本
    • Year and Date
      2007-09-21
  • [Presentation] Intermolecular structure and phase transition phenomena of 1-dimensional hydrogen bonding liquids in carbon micropores2007

    • Author(s)
      飯山拓, 羽木孝輔, 浅見圭一, 清水篤史, 尾関寿美男
    • Organizer
      9th International Conference on Fundamentals of Adsorption
    • Place of Presentation
      イタリア・ナクソス
    • Year and Date
      2007-05-22

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Published: 2011-06-18   Modified: 2016-04-21  

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