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2009 Fiscal Year Final Research Report

Mechanochemical synthesis of electrode materials with high capacity and their application to all-solid-state lithium secondary batteries

Research Project

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Project/Area Number 19686039
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionOsaka Prefecture University

Principal Investigator

HAYASHI Akitoshi  Osaka Prefecture University, 工学研究科, 助教 (10364027)

Project Period (FY) 2007 – 2009
Keywords全固体電池 / リチウム電池 / 電極活物質 / 固体電解質 / メカノケミストリー
Research Abstract

Development of all-solid-state lithium secondary batteries with high safety and reliability is highly demanded. In the present study, phosphorus-based anode materials and sulfur-based cathode materials with high capacity were mechanochemically synthesized. The mechanchemical process was also applied to the formation of a favorable contact among the active materials, a sulfide electrolyte and a conductive additive. It was found that surface modification of high-voltage cathodes with oxide and sulfide thin-films with lithium conductivity was effective in enhancing rate capability and energy density of solid-state batteries.

  • Research Products

    (33 results)

All 2010 2009 2008 2007 Other

All Journal Article (15 results) (of which Peer Reviewed: 13 results) Presentation (13 results) Book (3 results) Remarks (2 results)

  • [Journal Article] LiCoO2 Electrode Particles Coated with Li2S-P2S5 Solid Electrolyte for All-Solid-State Batteries2010

    • Author(s)
      A. Sakuda, A. Hayashi, T. Ohtomo, S. Hama, M. Tatsumisago
    • Journal Title

      Electrochem. Solid-State Lett. 13

      Pages: A73-A75

    • Peer Reviewed
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using LiMn204 Electrode and Li2S-P2S5 Solid Electrolyte2010

    • Author(s)
      H. Kitaura, A. Hayashi, K. Tadanaga, M. Tatsumisago
    • Journal Title

      J. Electrochem. Soc. 157

      Pages: A407-A411

    • Peer Reviewed
  • [Journal Article] 安全性・信頼性に優れた全固体リチウムニ次電池の開発2010

    • Author(s)
      林晃敏, 辰巳砂昌弘
    • Journal Title

      化学工業 61

      Pages: 46-50

  • [Journal Article] Preparation of Highly Lithium-Ion Conductive 80Li2S・20P2S5 Thin-Film Electrolytes Using Pulsed Laser Deposition2010

    • Author(s)
      A. Sakuda, A. Hayashi, S. Hama, M. Tatsumisago
    • Journal Title

      J. Am. Ceram. Soc. 93

      Pages: 765-768

    • Peer Reviewed
  • [Journal Article] Electrochemical Performance of All-Solid-State Lithium Secondary Batteries Improved by the Coating of Li2O-TiO2 Films on LiCoO2 Electrode2010

    • Author(s)
      A. Sakuda, A. Hayashi, M. Tatsumisago
    • Journal Title

      J. Power Sources 195

      Pages: 599-603

    • Peer Reviewed
  • [Journal Article] Interfacial Observation between LiCoO2 Electrode and Li2S-P2S5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy2010

    • Author(s)
      A. Sakuda, A. Hayashi, M. Tatsumisago
    • Journal Title

      Chem. Mater. 22

      Pages: 949-956

    • Peer Reviewed
  • [Journal Article] Characterization of Li2S-P2S5-Cu Composite Electrode for All-Solid-State Lithium Secondary Batteries2010

    • Author(s)
      A. Hayashi, R. Ohtsubo, M. Nagao, M. Tatsumisago
    • Journal Title

      J. Mater. Sci. 45

      Pages: 377-381

    • Peer Reviewed
  • [Journal Article] High Lithium Ion Conduction of Sulfide Glass-Based Solid Electrolytes and Their Application to All-Solid-State Batteries2009

    • Author(s)
      A. Hayashi, K. Minami, M. Tatsumisago
    • Journal Title

      J. Non-Cryst. Solids 355

      Pages: 1919-1923

    • Peer Reviewed
  • [Journal Article] Characterization of All-Solid-State Lithium Secondary Batteries Using CuxMo6S8-y Electrode and Li2S2S5 Solid Electrolyte2009

    • Author(s)
      M. Nagao, H. Kitaura, A. Hayashi, M. Tatsumisago
    • Journal Title

      J. Power Sources 189

      Pages: 672-675

    • Peer Reviewed
  • [Journal Article] Electrochemical Performance of NiP2 Negative Electrodes in All-Solid-State Lithium Secondary Batteries2009

    • Author(s)
      A. Hayashi, A. Inoue, M. Tatsumisago
    • Journal Title

      J. Power Sources 189

      Pages: 669-671

    • Peer Reviewed
  • [Journal Article] Novel Technique to form Electrode-Electrolyte Nanointerface in All-Solid-State Rechargeable Lithium Batteries2008

    • Author(s)
      A. Hayashi, Y. Nishio, H. Kitaura, M. Tatsumisago
    • Journal Title

      Electrochem. Commun 10

      Pages: 1860-1863

    • Peer Reviewed
  • [Journal Article] Development of New Glassy Materials for All-Solid-State Lithium Secondary Batteries: A Review2008

    • Author(s)
      A. Hayashi
    • Journal Title

      Glass Tech.: Eur. J. Glass Sci. Technol. 49

      Pages: 213-220

    • Peer Reviewed
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using Sulfide-Based Glass Ceramic Electrolytes2008

    • Author(s)
      M. Tatsumisago, A. Hayashi
    • Journal Title

      Funct. Mater. Lett. 1

      Pages: 31-36

    • Peer Reviewed
  • [Journal Article] Electrochemical Performance of All-Solid-State Lithium Batteries with Mechanochemically Activated Li2S-Cu Composite Electrodes2008

    • Author(s)
      A. Hayashi, R. Ohtsubo, M. Tatsumisago
    • Journal Title

      Solid State Ionics 179

      Pages: 1702-1705

    • Peer Reviewed
  • [Journal Article] All-Solid-State Rechargeable Lithium

    • Author(s)
      A. Hayashi, R, Ohtsubo, T. Ohtomo, F. Mizuno, M. Tatsumisago
  • [Presentation] 硫化リチウム-ナノカーボン複合体正極を用いた全固体リチウムニ次電池の作動特性2010

    • Author(s)
      長尾元寛, 林晃敏, 辰巳砂昌弘
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-31
  • [Presentation] 硫化物固体電解質コートLiCoO2を用いた全固体リチウム電池用正極複合体の作製2010

    • Author(s)
      作田敦, 林晃, 敏大友崇督, 濱重則, 辰巳砂昌弘
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-31
  • [Presentation] 硫黄-ナノカーボン複合体を電極に用いた全固体Li/S電池の特性評価2009

    • Author(s)
      長尾元寛, 林晃敏, 辰巳砂昌弘
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-12-02
  • [Presentation] Li-Ni-Co-Mn系酸化物を正極とする全固体リチウム二次電池の電気化学特性2009

    • Author(s)
      北浦弘和, 林晃敏忠永清治, 辰巳砂昌弘
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-12-02
  • [Presentation] Development of All-Solid-State Lithium Secondary Batteries with Sulfide Glass-Ceramic Electrolytes2009

    • Author(s)
      林晃敏, 辰巳砂昌弘
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      オーストリア・ウイーン
    • Year and Date
      2009-10-07
  • [Presentation] Electrochemical Properties of All-Solid-State Li/S Batteries with Li2S-P2S5 Solid Electrolytes2009

    • Author(s)
      長尾元寛, 林晃敏, 辰巳砂昌弘
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      オーストリア・ウイーン
    • Year and Date
      2009-10-05
  • [Presentation] 黒リンを電極活物質に用いた全固体リチウム二次電池の電気化学的評価2009

    • Author(s)
      長尾元寛, 林晃敏, 辰巳砂昌弘
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-10
  • [Presentation] 全固体リチウム電池への応用にむけた電極/電解質ナノコンポジットの作製とキャラクタリゼーション2009

    • Author(s)
      林晃敏, 西尾勇祐, 辰巳砂昌弘
    • Organizer
      第4回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      大阪
    • Year and Date
      2009-07-23
  • [Presentation] Development of Sulfide Glass-Ceramic Electrolytes for All-Solid-State Lithium Rechargeable Batteries2009

    • Author(s)
      林晃敏, 辰巳砂昌弘
    • Organizer
      International Conference on Materials for Advanced Technologies(ICMAT2009)
    • Place of Presentation
      シンガポール
    • Year and Date
      2009-06-29
  • [Presentation] イオウ-銅電極活物質の作製と全固体リチウム二次電池への応用2009

    • Author(s)
      長尾元寛, 林晃敏, 辰巳砂昌弘
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Year and Date
      2009-03-31
  • [Presentation] All-Solid-State Lithium Rechargeable Batteries with Sulfide Glass-Based Solid Electrolytes2008

    • Author(s)
      林晃敏, 辰巳砂昌弘
    • Organizer
      2008 MRS Fall Meeting
    • Place of Presentation
      米国、ボストン
    • Year and Date
      2008-12-02
  • [Presentation] Li2S-P2S5系電解質とNi系電極活物質からなるナノ複合体の作製と全固体リチウム二次電池への応用2008

    • Author(s)
      西尾勇祐, 北浦弘和, 林晃敏, 辰巳砂昌弘
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-11-07
  • [Presentation] 金属リン化物M, P, (M=Ni, Cu)を電極に用いた全固体リチウム二次電池2008

    • Author(s)
      林晃敏, 井上明子, 辰巳砂昌弘
    • Organizer
      電気化学会75回大会
    • Place of Presentation
      山梨
    • Year and Date
      2008-03-31
  • [Book] 次世代二次電池材料の開発2009

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Total Pages
      103-113
    • Publisher
      シーエムシー出版
  • [Book] 次世代自動車用リチウムイオン電池の材料開発2008

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Total Pages
      159-169
    • Publisher
      シーエムシー出版
  • [Book] 全固体二次電池の開発-高性能化と製造技術-2007

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Total Pages
      295-308
    • Publisher
      サイエンス&テクノロジー
  • [Remarks] 成果の新聞発表:「次世代蓄電池充放電を実現」日本経済新聞(2009年11月23日)

  • [Remarks] 研究室ホームページ:

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/index.html

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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