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2009 Fiscal Year Final Research Report

Synthesis, systematization, and functionalization of newly developed hierarchical porous materials

Research Project

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Project/Area Number 19686048
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionThe University of Tokyo

Principal Investigator

OGURA Masaru  The University of Tokyo, 生産技術研究所, 准教授 (50298155)

Project Period (FY) 2007 – 2009
Keywordsゼオライト / 階層構造 / コンポジット / 酸塩基触媒 / 吸着材 / 貴金属低減 / ナノるつぼ / セラミックス
Research Abstract

A novel method to synthesize microporous materials or micro-meso-porous composite materials by use of mesoporous silica materials as a source, was developed as a suitable technique to obtain a hierarchical porous network. Another synthesis strategy for the newly-functionalized porous materials was also proposed; where hetero-atom doping on the surface of mesoporous silica materials in their synthesis or post-syntheis procedure, was carried out, and then the mesoporous materials were transferred into microporous materials without loss in the surface nature. As a result of this work, fabrication of a group of hierarchical porous silica from micro- through macropore with an important catalytic function of surface such as acid-base or redox properties, was successfully achieved.

  • Research Products

    (55 results)

All 2010 2009 2008 2007 Other

All Journal Article (20 results) Presentation (30 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis and characterization of aluminium containing CIT-1 and their structure-property relationship to hydrocarbon trap performance2010

    • Author(s)
      Thomas Mathew, S.P. Elangovan, T. Yokoi, Takashi Tatsumi, M. Ogura, Yoshihiro Kubota, Atsushi Shimojima, T. Okubo
    • Journal Title

      Microporous and Mesoporous Materials 129

      Pages: 126-135

  • [Journal Article] Promising catalytic performance and shape-selectivity of nitrogen-doped siliceous MFI zeolite for base-catalyzed reactions2010

    • Author(s)
      Taku Hasegawa, Cheralathan K. Krishnan, M. Ogura
    • Journal Title

      Microporous and Mesoporous Materials 132

      Pages: 290-295

  • [Journal Article] メソ多孔体から効率的に合成される高機能ゼオライト触媒2009

    • Author(s)
      小倉賢・渡部景一郎・長谷川卓
    • Journal Title

      化学工業 60

      Pages: 545-552

  • [Journal Article] Cooperative Effect of Sodium and Potassium Cations on Synthesis of Ferrierite2009

    • Author(s)
      Yasuhiro Suzuki, Toru Wakihara, Keiji Itabashi, M. Ogura, T. Okubo
    • Journal Title

      Topics in Catalysis 52

      Pages: 67-74

  • [Journal Article] Towards Realization of a Microand Mesoporous Composite Silicate Catalyst2008

    • Author(s)
      M. Ogura
    • Journal Title

      Catalysis Surveys from Asia 12

      Pages: 16-27

  • [Journal Article] A New Method for Post-Synthesis Coating of Zirconia on the Mesopore Walls of SBA-15 Without Pore Blocking2008

    • Author(s)
      Krishnan K. Cheralathan, Takahiro Hayashi, M. Ogura
    • Journal Title

      Advanced Materials 20

      Pages: 2131-2136

  • [Journal Article] Effective factors on solid phase conversion of Fe-containing mesoporous silica into Fe-beta2008

    • Author(s)
      Keiichiro Watanabe, M. Ogura
    • Journal Title

      Microporous and Mesoporous Materials 114

      Pages: 229-237

  • [Journal Article] ゼオライト特性を細孔壁にもつメソ多孔体2008

    • Author(s)
      小倉賢
    • Journal Title

      触媒 50

      Pages: 276-282

  • [Journal Article] Assembling mode of alumina and zirconia particles inside the mesopores of SBA-15 under high loading2008

    • Author(s)
      K.K. Cheralathan, Hirohito Hirata, M. Ogura
    • Journal Title

      Studies in Surface Science and Catalysis 174

      Pages: 161-166

  • [Journal Article] Solid acid porous materials for the catalytic transformation of 1-adamantanol2008

    • Author(s)
      S.P. Elangovan, Katsuki Inoue, Toshiyuki Yokoi, T. Okubo, Akio Kojima, M. Ogura
    • Journal Title

      Catalysis Today 131

      Pages: 367-371

  • [Journal Article] Nepheline from K2CO3/Nanosized Sodalite as a Prospective Candidate for Diesel Soot Combustion2008

    • Author(s)
      Riichiro Kimura, Junji Wakabayashi, S.P. Elangovan, M. Ogura, T. Okubo
    • Journal Title

      Journal of American Chemical Society 130

      Pages: 12844-12845

  • [Journal Article] Post-synthesis coating of alumina on the mesopore walls of SBA-15 by ammonia/water vapour induced internal hydrolysis and its consequences on pore structure and acidity2008

    • Author(s)
      K.K. Cheralathan, T. Hayashi, M. Ogura
    • Journal Title

      Microporous and Mesoporous Materials 116

      Pages: 406-415

  • [Journal Article] Intermediate-range Order in Mesoporous Silicas Investigated by a High-energy X-ray Diffraction Technique2008

    • Author(s)
      T. Wakihara, W. Fan, S. Kohara, M. Ogura, G. Sankar, T. Okubo
    • Journal Title

      Chemistry Letters 37

      Pages: 30-31

  • [Journal Article] Formation of ZMM-n: the composite materials having both natures of zeolites and mesoporous silica materials2007

    • Author(s)
      M. Ogura, Y. Zhang, S.P. Elangovan, T. Okubo
    • Journal Title

      Microporous and Mesoporous Materials 101

      Pages: 224-230

  • [Journal Article] Steam-assisted crystallization法を用いたゼオライト-メソ多孔体コンポジット合成2007

    • Author(s)
      瀧澤健介・小倉賢
    • Journal Title

      生産研究 59

      Pages: 333-338

  • [Journal Article] Hydrocarbon Reformer Trap by Use of Transition Metal Oxide-Incorporated Beta Zeolites2007

    • Author(s)
      M. Ogura, T. Okubo, S.P. Elangovan
    • Journal Title

      Catalysis Letters 118

      Pages: 72-78

  • [Journal Article] Synthesis of 2-Adamantane Derivatives from 1-Adamantanol on Solid Acid Catalysts2007

    • Author(s)
      S.P. Elangovan, Katsuki Inoue, T. Okubo, Akio Kojima, M. Ogura
    • Journal Title

      Industrial & Engineering Chemical Research 46

      Pages: 1039-1044

  • [Journal Article] Effect of silicon source on the formation of nanosized LTA: An in situ small angle X-ray scattering and wide angle X-ray scattering study2007

    • Author(s)
      Wei Fan, Florian Meneau, Wim Bras, M. Ogura, G. Sankar, T. Okubo
    • Journal Title

      Microporous and Mesoporous Materials 101

      Pages: 134-141

  • [Journal Article] In situ Small-Angle and Wide-Angle X-ray Scattering Investigation on Nucleation and Crystal Growth of Nanosized Zeolite A2007

    • Author(s)
      W. Fan, M. Ogura, G. Sankar, T. Okubo
    • Journal Title

      Chemistry of Materials 19

      Pages: 1906-1917

  • [Journal Article] Pt/CeO2-ZrO2 present in the mesopores of SBA-15 - a better catalyst for CO oxidation

    • Author(s)
      Cheralathan K. Krishnan, Keiko Nakamura, Hirohito Hirata, M. Ogura
    • Journal Title

      Physical Chemistry Chemical Physics (印刷中)

  • [Presentation] メソポーラスシリカ細孔内セリア・ジルコニア固溶相の形成と低温CO酸化触媒の開発2010

    • Author(s)
      小倉賢, K.K. Cheralathan, 中村佳子, 平田裕人
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都
    • Year and Date
      2010-03-25
  • [Presentation] Synthesis of zeolites from mesoporous silica and their catalytic functions2010

    • Author(s)
      M. Ogura
    • Organizer
      Invited Seminar at National Chemical Laboratory
    • Place of Presentation
      Pune, India
    • Year and Date
      2010-02-22
  • [Presentation] Shape selective base catalysis of nitrogen containing zeolite2010

    • Author(s)
      M. Ogura
    • Organizer
      Lecture of Anna University Chennai
    • Place of Presentation
      Chennai, India
    • Year and Date
      2010-02-19
  • [Presentation] 自動車排ガス浄化触媒の基礎と最新技術2010

    • Author(s)
      小倉賢
    • Organizer
      情報機構セミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-02-17
  • [Presentation] 貴金属フリー自動車触媒開発への課題2010

    • Author(s)
      小倉賢
    • Organizer
      サイエンス&テクノロジー触媒セミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-01-26
  • [Presentation] 貴金属フリー自動車排ガス浄化触媒開発に向けて2010

    • Author(s)
      小倉賢
    • Organizer
      平成21年度小倉記念シンポジウム
    • Place of Presentation
      早稲田大学
    • Year and Date
      2010-01-09
  • [Presentation] 塩基性ゼオライトの使い方2009

    • Author(s)
      小倉賢
    • Organizer
      平成21年度産学交流サロン
    • Place of Presentation
      東京
    • Year and Date
      2009-12-14
  • [Presentation] P5+ドープシリケートゼオライトの合成と表面特性2009

    • Author(s)
      S. Vishnupriya・渡部景一郎・小倉賢
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      北九州
    • Year and Date
      2009-11-26
  • [Presentation] 環境浄化用ミクロ/メソ多孔質触媒に関する研究2009

    • Author(s)
      小倉賢
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-27
  • [Presentation] メソ多孔体から合成するゼオライト触媒の可能性2009

    • Author(s)
      小倉賢
    • Organizer
      第40回触媒サマーセミナー
    • Place of Presentation
      箱根
    • Year and Date
      2009-08-21
  • [Presentation] Nitrogen-doped zeolites crystallized by use of nitrided mesoporous silica as the precursor and their basic catalysis2009

    • Author(s)
      T. Hasegawa, M. Ogura
    • Organizer
      ZMPC2009
    • Place of Presentation
      早稲田大学
    • Year and Date
      2009-08-04
  • [Presentation] ナノ空間材料を用いた自動車排ガス浄化触媒2009

    • Author(s)
      小倉賢
    • Organizer
      触媒道場
    • Place of Presentation
      博多
    • Year and Date
      2009-07-03
  • [Presentation] 窒素含有ゼオライトの合成とその塩基触媒特性の検討2009

    • Author(s)
      小倉賢, 長谷川卓
    • Organizer
      石油学会第52回年会
    • Place of Presentation
      東京
    • Year and Date
      2009-05-20
  • [Presentation] Synthesis of zeolites with nitrogen doped in the framework for efficient base catalysts2009

    • Author(s)
      T. Hasegawa, M. Ogura
    • Organizer
      6th world congress on Catalysis by Acids and Bases
    • Place of Presentation
      Genova, Italia
    • Year and Date
      2009-05-14
  • [Presentation] Zirconia-Coated Mesoporous Silica Having Both Natures of Ceramic Surface and Mesoporosity2008

    • Author(s)
      M. Ogura, Hirohito Hirata, Keiko Nakamura, K.K. Cheralathan
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      名古屋
    • Year and Date
      2008-12-13
  • [Presentation] セラミックス/メソポーラスシリカ複合体の合成と窒素吸着による構造特性評価2008

    • Author(s)
      小倉賢・平田裕人・K.K. Cheralathan
    • Organizer
      第22回日本吸着学会研究発表会
    • Place of Presentation
      九州大学
    • Year and Date
      2008-10-24
  • [Presentation] メソ多孔質シリカのセラミックスコーティングによるセラミックス/メソ多孔質シリカコンポジット合成2008

    • Author(s)
      小倉賢・平田裕人・K.K. Cheralathan
    • Organizer
      第102回触媒討論会研究発表会A講演
    • Place of Presentation
      名古屋大学
    • Year and Date
      2008-09-25
  • [Presentation] "穴"を利用した貴金属フリー自動車触媒への挑戦2008

    • Author(s)
      小倉賢
    • Organizer
      平成20年度ゼオライトフォーラム「多孔体を利用する環境保全への挑戦:自動車触媒と光触媒」
    • Place of Presentation
      大阪大学
    • Year and Date
      2008-08-08
  • [Presentation] Several Attempts on Synthesis of Mesoporous Silica-based Composite Materials2008

    • Author(s)
      Masaru Ogura, K.K. Cheralathan
    • Organizer
      A3 Seminar on Mesoporous Materials, organized by the A3 Foresight Program of JSPS
    • Place of Presentation
      早稲田大学
    • Year and Date
      2008-06-26
  • [Presentation] K-doped Microporous Tectoaluminosilicate for Soot Combustion2008

    • Author(s)
      Masaru Ogura
    • Organizer
      5th International Conference Interfaces Against Pollution 2008 (IAP08)
    • Place of Presentation
      京都大学
    • Year and Date
      2008-06-02
  • [Presentation] メソポーラスシリカからのゼオライト結晶化とミクロメソコンポジットの実現可能性2008

    • Author(s)
      小倉賢
    • Organizer
      石油学会第57回研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2008-05-16
  • [Presentation] イソオクタン排出に対するHC reformer trapとPt触媒の複合効果2008

    • Author(s)
      小倉賢・新部裕佳子・駒場慎一
    • Organizer
      第101回触媒討論会研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
  • [Presentation] 階層的多孔構造をもつシリケートの創製の試み2007

    • Author(s)
      小倉賢
    • Organizer
      新化学発展協会主催「先端化学技術部会第284回講演会」
    • Place of Presentation
      東京
    • Year and Date
      2007-12-19
  • [Presentation] 固相転移法を用いたFe2+, P5+導入ゼオライトの合成2007

    • Author(s)
      渡部景一郎・小倉賢
    • Organizer
      第23回ゼオライト研究発表会
    • Place of Presentation
      秋田
    • Year and Date
      2007-11-27
  • [Presentation] MCM-22/SBA-15コンポジットの酸性質と芳香族化合物吸着特性2007

    • Author(s)
      小倉賢・井上和哉・山口太地
    • Organizer
      第37回石油石油化学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-10-26
  • [Presentation] SBA-15細孔内アルミナおよびジルコニアコーティング法の開発2007

    • Author(s)
      小倉賢・K.K. Cheralathan・林高弘
    • Organizer
      第21回日本吸着学会
    • Place of Presentation
      北海道
    • Year and Date
      2007-09-20
  • [Presentation] 三元触媒の貴金属使用量低減を目指したHC reformer trapによるイソオクタン排出低減2007

    • Author(s)
      小倉賢・渡部景一郎・新部裕佳子・駒場慎一
    • Organizer
      第100回触媒討論会研究発表会A講演
    • Place of Presentation
      北海道
    • Year and Date
      2007-09-20
  • [Presentation] ディーゼルパーティキュレート除去用ソーダライト担持カリウム触媒上での相転移による高活性点の形成2007

    • Author(s)
      小倉賢・大久保達也・棚田浩
    • Organizer
      第100回触媒討論会研究発表会B講演
    • Place of Presentation
      北海道
    • Year and Date
      2007-09-18
  • [Presentation] Coating alumina and zirconia on mesoporous walls of SBA-15: a new vapour-induced internal hydrolysis (VIH) method2007

    • Author(s)
      Krishnan K. Cheralathan, M. Ogura, Takahiro Hayashi
    • Organizer
      15th International Zeolite Conference (IZC)
    • Place of Presentation
      Beijing, China
    • Year and Date
      2007-08-10
  • [Presentation] 環境触媒の高性能化を目指したゼオライトの合成・修飾2007

    • Author(s)
      小倉賢
    • Organizer
      第56回研究発表会(石油学会)
    • Place of Presentation
      船堀(東京)
    • Year and Date
      2007-05-18
  • [Book] ナノ空間材料の創製と応用2009

    • Author(s)
      小倉賢, 他(分担執筆)
    • Total Pages
      295-305(314)
    • Publisher
      フロンティア出版
  • [Book] 触媒便覧2008

    • Author(s)
      小倉賢, 他(共同執筆)
    • Total Pages
      187-191
    • Publisher
      講談社
  • [Book] 触媒材料(環境調和型新材料シリーズ)2007

    • Author(s)
      小倉賢, 他(分担執筆)
    • Total Pages
      42-48
    • Publisher
      日刊工業新聞社
  • [Remarks]

    • URL

      http://www.ogulab.iis.u-tokyo.ac.jp

  • [Patent(Industrial Property Rights)] 触媒及びその製造方法2009

    • Inventor(s)
      平田裕人, 小倉賢
    • Industrial Property Rights Holder
      東京大学, トヨタ自動車
    • Industrial Property Number
      特願・2009-052387
    • Filing Date
      2009-03-05

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Published: 2011-06-18   Modified: 2016-04-21  

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