Transition Metal Catalyzed Synthesis of π-Conjugated Systems Having Main Group Elements

2008 Fiscal Year Final Research Report

• Project/Area Number: 19750074
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Synthetic chemistry
• Research Institution: Tokyo University of Science (2008); Kyoto University (2007)
• Principal Investigator: MATSUDA Takanori Tokyo University of Science, 理学部応用化学科, 講師 (80359778)
• Project Period (FY): 2007 – 2008
• Keywords: シロール / シラフルオレン / 閉環メタセシス / ヒドロシリル化 / ベンゾシロール / ベンゾフラン / フラン

Research Products

• [Journal Article] Palladium-Catalyzed Sequential Carbon?Carbon Bond Cleavage/Formation Producing Arylated Benzolactones (2008)
  • Author(s): Takanori Matsuda, Masanori Shigeno, and Masahiro Murakami
  • Journal Title: Org. Lett 10 Pages: 5219-5221
  • Peer Reviewed
• [Journal Article] Gold-catalysed intramolecular trans-allylsilylation of alkynes forming 3-allyl-1-silaindenes (2008)
  • Author(s): Takanori Matsuda, Sho Kadowaki, Yoshiyuki Yamaguchi, and Masahiro Murakami
  • Journal Title: Chem. Commun Pages: 2744-2746
  • Peer Reviewed
• [Journal Article] Synthesis of Silole Skeletons via Metathesis Reactions (2008)
  • Author(s): Takanori Matsuda, Yoshiyuki Yamaguchi, and Masahiro Murakami
  • Journal Title: Synlett Pages: 561-564
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Carbonylation of Spiropentanes (2007)
  • Author(s): Takanori Matsuda, Tomoya Tsuboi, and Masahiro Murakami
  • Journal Title: J. Am. Chem. Soc 129 Pages: 12596-12597
  • Peer Reviewed
• [Journal Article] Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones (2007)
  • Author(s): Takanori Matsuda, Masanori Shigeno, and Masahiro Murakami
  • Journal Title: J. Am. Chem. Soc 129 Pages: 12086-12087
  • Peer Reviewed
• [Journal Article] Ruthenium-Catalysed Double trans-Hydrosilylation of 1,4-Diarylbuta-1,3-diynes Leading to 2,5-Diarylsiloles (2007)
  • Author(s): Takanori Matsuda, Sho Kadowaki, and Masahiro Murakami
  • Journal Title: Chem. Commun Pages: 2627-2629
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Reactions of Cyclobutanones with Alcohols and Amines Forming Esters and Amides (2007)
  • Author(s): Takanori Matsuda, Masanori Shigeno, Yohei Maruyama, and Masahiro Murakami
  • Journal Title: Chem. Lett 36 Pages: 744-745
  • Peer Reviewed
• [Presentation] 金触媒によるアリールボロン酸のホモカップリング反応 (2009)
  • Author(s): 松田学則、浅井太郎
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2009-03-29
• [Presentation] ロジウム触媒によるo-アルキニルフェノールの環化反応 (2009)
  • Author(s): 松田学則、藤崎陽介、坪井智也、村上正浩
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] Asymmetric Construction of Quaternary Carbon Centers by Rhodium-Catalyzed Enantioselective C?C Bond Cleavage (2008)
  • Author(s): Takanori Matsuda, Masanori Shigeno, Masaomi Makino, and Masahiro Murakami
  • Organizer: 5th Symposium on Chemical Approaches to Chirality
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2008-12-01
• [Presentation] ロジウム触媒による炭素?炭素結合切断反応の合成化学的利用 (2008)
  • Author(s): 松田学則
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-27
• [Presentation] パラジウム触媒によるシクロブタノンの炭素?炭素結合切断を経由するラクトン合成 (2008)
  • Author(s): 重野真徳、松田学則、村上正浩
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパスおよび立教池袋中学校・高等学校
  • Year and Date: 2008-03-27
• [Presentation] アルキンの分子内アリールシリル化によるシロール誘導体の合成 (2008)
  • Author(s): 山口善之、松田学則、村上正浩
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパスおよび立教池袋中学校・高等学校
  • Year and Date: 2008-03-26
• [Presentation] 遷移金属触媒によるジインの環化異性化反応 (2008)
  • Author(s): 呉屋剛、松田学則、村上正浩
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパスおよび立教池袋中学校・高等学校
  • Year and Date: 2008-03-26
• [Presentation] Rhodium-Catalyzed Asymmetric Synthesis of Lactones by Enantioselective C?C Bond Cleavage of Cyclobutanones (2008)
  • Author(s): Masanori Shigeno, Takanori Matsuda, and Masahiro Murakami
  • Organizer: The 9th Youngnam?Kinki Joint Symposium on Organometallic Chemistry
  • Place of Presentation: Kyoto, Japan
  • Year and Date: 2008-01-25
• [Presentation] Synthesis of Siloles by Ruthenium-Catalyzed Double trans-Hydrosilylation of 1,3-Diynes (2007)
  • Author(s): Takanori Matsuda, Sho Kadowaki, Yoshiyuki Yamaguchi, and Masahiro Murakami
  • Place of Presentation: Miyagi, Japan
  • Year and Date: 2007-11-02
• [Presentation] ロジウム触媒による3-(2-ヒドロキシフェニル)シクロブタノンからの3,4-ジヒドロクマリンの不斉合成 (2007)
  • Author(s): 重野真徳、松田学則、村上正浩
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島大学東広島キャンパス
  • Year and Date: 2007-10-27
• [Presentation] Rhodium-Catalyzed Asymmetric Synthesis of Lactones by Intramolecular Addition/Ring-Opening of Phenols to Cyclobutanones (2007)
  • Author(s): Masanori Shigeno, Takanori Matsuda, Masahiro Murakami
  • Organizer: The Fourth International Symposium on Integrated Synthesis
  • Place of Presentation: Shiga, Japan
  • Year and Date: 2007-09-23
• [Presentation] 閉環メタセシス反応によるシロール骨格の合成 (2007)
  • Author(s): 山口善之、松田学則、村上正浩
  • Organizer: 第24回有機合成化学セミナー
  • Place of Presentation: 淡路夢舞台国際会議場
  • Year and Date: 2007-09-12
• [Presentation] Synthesis of (±)-β-Cuparenone via Rhodium-Catalyzed Carbonylation of Spiropentane (2007)
  • Author(s): Takanori Matsuda, Tomoya Tsuboi, and Masahiro Murakami
  • Organizer: 14th IUPAC Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS14)
  • Place of Presentation: Nara, Japan
  • Year and Date: 2007-08-03
• [Presentation] Synthesis of Sesquiterpenes via Rhodium-Catalyzed Carbon?Carbon Bond Cleavage (2007)
  • Author(s): Takanori Matsuda, Masanori Shigeno, Tomoya Tsuboi, Masaomi Makino, and Masahiro Murakami
  • Organizer: International Conference on Asymmetric Organocatalysis
  • Place of Presentation: Shiga,Japan
  • Year and Date: 2007-05-29
• [Book] Mingos, D. M. P., Crabtree, R. H., Ojima, I., Eds.; Elsevier : Oxford (2007)
  • Author(s): Michinori Suginome, Takanori Matsuda, Toshimichi Ohmura, Atsushi Seki, and Masahiro Murakami
  • Total Pages: 725-787