2009 Fiscal Year Final Research Report
Development of Oxidant-Free Oxidation of Alcohols Catalyzed by Group 9 Metal Complexes and their Application to Organic Synthesis
| Project/Area Number |
19750075
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
FUJITA Ken-ichi Kyoto University, 地球環境学堂, 准教授 (80293843)
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| Project Period (FY) |
2007 – 2009
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| Keywords | 酸化反応 / アルコール / 脱水素 / ケトン / アルデヒド / イリジウム触媒 / ロジウム触媒 |
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| Research Abstract |
An efficient catalytic system for oxidant-free oxidation of alcohols has been developed by using group 9 metal complexes having functional ligands (hydroxypyridines, aminopyridines, and phenylpyridines) as catalysts. Various secondary and primary alcohols were converted to corresponding ketones and aldehydes, respectively, by catalytic dehydrogenative transformation. The present catalytic system exhibited the highest activity for dehydrogenative oxidation of alcohols among the reported systems.
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