Development of Supramolecular-Fullerene Materials

2008 Fiscal Year Final Research Report

• Project/Area Number: 19750124
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: National Institute for Materials Science
• Principal Investigator: NAKANISHI Takashi National Institute for Materials Science, ナノ有機センター, 主任研究員 (40391221)
• Project Period (FY): 2007 – 2008
• Keywords: 膜・集合体 / ナノカーボン / フラーレン / 超分子化学 / 自己組織化 / 超撥水

Research Abstract

長鎖アルキル基を導入したフラーレン分子を用い、フラーレン間の分子間相互作用を巧みに制御することにより、次元制御されたフラーレン超分子構造を創製し、そのモルフォロジーを活かした、超分子ソフトマテリアルの開発を行った。フラワー状の組織体形成メカニズムの解明、フラーレン素材超撥水性素材の開発、有機半導体性を兼ね備えたサーモトロピック液晶素材等の創製に成功した。

Research Products

• [Journal Article] Self-Assembly Made Durable : Water-Repellent Materials Formed by Cross-Linking Fullerene Derivatives (2009)
  • Author(s): Jiaobing Wang, Yanfei Shen, Stefanie Kessel, Paulo Fernandes, Kaname Yoshida, Shiki Yagai, Dirk G. Kurth, Helmuth Mohwald, Takashi Nakanishi
  • Journal Title: Angew. Chem. Int. Ed. 48 Pages: 2166-2170
  • Peer Reviewed
• [Journal Article] Supramolecular Templates for Nanoflake-Metal Surfaces (2009)
  • Author(s): Yanfei Shen, Jiaobing Wang, Uwe Kuhlmann, Peter Hildebrandt, Katsuhiko Ariga, Helmuth Mohwald, Dirk G. Kurth, Takashi Nakanishi
  • Journal Title: Chem. Eur. J. 15(12) Pages: 2763-3767
  • Peer Reviewed
• [Journal Article] Supramolecular Shape Shifter : Polymorphs of Self-Organized Fullerene Assemblies (2009)
  • Author(s): Takashi Nakanishi, Jiaobing Wang, Helmuth Mohwald, Dirk G. Kurth, Tsuyoshi Michinobu, Masayuki Takeuchi, Katsuhiko Ariga
  • Journal Title: J. Nanosci. Nanotechnol. 9 Pages: 550-556
  • Peer Reviewed
• [Journal Article] Electron Transport and Electrochemistry of Mesomorphic Fullerenes with Long-Range Ordered Lamellae (2008)
  • Author(s): Takashi Nakanishi, Yanfei Shen, Jiaobing Wang, Shiki Yagai, Masahiro Funahashi, Takashi Kato, Paulo Fernandes, Helmuth Mohwald, Dirk G. Kurth
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 9236-9237
  • Peer Reviewed
• [Journal Article] Nano-Carbon Superhydrophobic Surfaces Created from Fullerene Based Hierarchical Supramolecular Assemblies (2008)
  • Author(s): Takashi Nakanishi, Tsuyoshi Michinobu, Kaname Yoshida, Naoto Shirahata, Katsuhiko Ariga, Helmuth Mohwald, Dirk G. Kurth
  • Journal Title: Adv. Mater. 20 Pages: 443-446
  • Peer Reviewed
• [Journal Article] Fine-tuning Supramolecular Assemblies of Fullerenes Bearing Long Alkyl Chains (2008)
  • Author(s): Takashi Nakanishi, Hirokazu Takahashi, Tsuyoshi Michinobu, Jonathan P. Hill, Toshiharu Teranishi, Katsuhiko Ariga
  • Journal Title: Thin Solid Films 516 Pages: 2401-2406
  • Peer Reviewed
• [Journal Article] Fullerene Nanowires on Graphite : Epitaxial Self-Organization of a Fullerene Bearing Double Long-Aliphatic Chains (2008)
  • Author(s): Takashi Nakanishi, Hirokazu Takahashi, Tsuyoshi Michinobu, Masayuki Takeuchi,Toshiharu Teranishi, Katsuhiko Ariga
  • Journal Title: Colloids & Surfaces A 321 Pages: 99-105
  • Peer Reviewed
• [Journal Article] フラーレンC60集合体 (2008)
  • Author(s): 中西尚志
  • Journal Title: 工業材料 56 Pages: 4-5
• [Journal Article] 分子間相互作用の精密制御による超分子マテリアル創製 (2008)
  • Author(s): 中西尚志
  • Journal Title: 表面 46 Pages: 105-115
• [Journal Article] 世界初!フラーレンからできた超撥水膜 (2008)
  • Author(s): 中西尚志
  • Journal Title: 化学 63 Pages: 50-55
• [Journal Article] 分子間相互作用の精密制御によるフラーレン素材ソフトマテリアル (2008)
  • Author(s): 中西尚志
  • Journal Title: NEWSLETTER 33 Pages: 2-6
• [Journal Article] Flower-Shaped Supramolecular Assemblies : Hierarchical Organization of a Fullerene Bearing Long Aliphatic Chains (2007)
  • Author(s): Takashi Nakanishi, Katsuhiko Ariga, Tsuyoshi Michinobu, Kaname Yoshida, Hiroaki Takahashi, Toshiharu Teranishi, Helmuth Mohwald, Dirk G. Kurth
  • Journal Title: Small 3 Pages: 2019-2023
  • Peer Reviewed
• [Presentation] Supramolecular Fullerene Organizations towards Organic Soft-Materials with Controlled Dimensionality(依頼講演) (2009)
  • Author(s): Takashi Nakanishi
  • Organizer: IECB Institute Seminar
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2009-06-16
• [Presentation] フラーレン自己組織化材料:ナノ・マイクロ・バルクスケール(招待講演) (2009)
  • Author(s): 中西尚志
  • Organizer: 第56回応用物理学関連講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-03-31
• [Presentation] Fullerene fluids : Liquids and liquid crystals(招待講演) (2009)
  • Author(s): Takashi Nakanishi
  • Organizer: ACS 237th National Meeting
  • Place of Presentation: American Chemical Society, Salt Lake City, USA
  • Year and Date: 2009-03-22
• [Presentation] Supramolecular Soft Matter Based on Fullerene Organizations(招待講演) (2009)
  • Author(s): Takashi Nakanishi
  • Organizer: IWEPNM 2009
  • Place of Presentation: Kirchberg-Tirol, Austria
  • Year and Date: 2009-03-11
• [Presentation] Fullerene Based Soft Materials Developed by Fine-Tuning of Intermolecular Interactions(招待講演) (2009)
  • Author(s): Takashi Nakanishi
  • Organizer: 2nd International Symposium for Young Organic Chemists
  • Place of Presentation: NIMS, Japan
  • Year and Date: 2009-03-05
• [Presentation] Long-Range Ordered Lamellar Mesophase of Fullerene Derivatives Bearing Long-Aliphatic Chains and Its Electron Transport Property(Award for Encouragement of Research of Materials Science) (2008)
  • Author(s): Takashi Nakanishi, Yanfei Shen, Helmuth Mohwald, Shiki Yagai, Masahiro Funahashi, Takashi Kato
  • Organizer: The IUMRS International Conference in Asia 2008
  • Place of Presentation: Nagoya, Japan
  • Year and Date: 2008-12-12
• [Presentation] Development of Supramolecular Soft-Materials Based on Fullerene Derivatives Bearing Long-Aliphatic Chains(招待講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: The IUMRS International Conference in Asia 2008
  • Place of Presentation: Nagoya, Japan
  • Year and Date: 2008-12-10
• [Presentation] Supramolecular Fullerene Assemblies towards Organic-Materials Applications(招待講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: International Conference on Functional Materials(FM2008)
  • Place of Presentation: Chennai, India
  • Year and Date: 2008-11-28
• [Presentation] Supramolecular Materialization Based on Fullerene Derivatives(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Institute Seminar at NIIST, CSIR
  • Place of Presentation: Trivandrum, India
  • Year and Date: 2008-11-24
• [Presentation] Supramolecular Fullerene Soft-Materials(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Institute Seminar at ICMAB, CSIC
  • Place of Presentation: Barcelona, Spain
  • Year and Date: 2008-11-06
• [Presentation] Novel Fullerene Soft-Materials Based on Supramolecular Sciences(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Department Seminar at Universidad Complutense de Madrid
  • Place of Presentation: Spain
  • Year and Date: 2008-11-04
• [Presentation] 分子間相互作用の精密制御によるフラーレン超分子マテリアル創製(科学奨励賞受賞講演) (2008)
  • Author(s): 中西尚志
  • Organizer: 第61回コロイドおよび界面化学討論会
  • Place of Presentation: 九州大学
  • Year and Date: 2008-09-07
• [Presentation] Hierarchical Assemblies of Fullerene-Aliphatic Chain Amphiphiles in Organic Solvents (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: 17th International Symposium on Surfactant in Solution
  • Place of Presentation: Berlin, Germany
  • Year and Date: 2008-08-21
• [Presentation] Development of Supramolecular Materials Based on Fullerene Derivatives Bearing Long-Aliphatic Chains(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Intergroup Seminar in the Laboratory of Organic Chemistry at ETH
  • Place of Presentation: Zurich, Switzerland
  • Year and Date: 2008-07-18
• [Presentation] Hierarchically Ordered Supramolecular Materials Based on Fullerene Assemblies(The Best Poster Award) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: E-MRS Spring Meeting 2008
  • Place of Presentation: Strasbourg, France
  • Year and Date: 2008-05-29
• [Presentation] Supramolecular Materials Based on Self-Organizations of Fullerene-Aliphatic Chains Amphiphiles(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Department Seminar at University Neuchatel
  • Place of Presentation: Department Seminar at University Neuchatel
  • Year and Date: 2008-05-23
• [Presentation] Development of Novel Supramolecular Soft-Materials Based on Fullerene-Aliphatic Chains Derivatives(依頼講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: Department Seminar at University Erlangen-Nurnberg
  • Place of Presentation: Germany
  • Year and Date: 2008-04-08
• [Presentation] フラーレンを素材とする超分子材料創製への挑戦(依頼講演) (2008)
  • Author(s): 中西尚志
  • Organizer: 産業技術総合研究所,ナノテクノロジー研究部門セミナー
  • Place of Presentation: 産業技術総合研究所(つくば)
  • Year and Date: 2008-03-10
• [Presentation] Supramolecular Materials Based on Hierarchical Organization of Fullerenes(招待講演) (2008)
  • Author(s): Takashi Nakanishi
  • Organizer: 日中機能性分子の合成と自己組織化シンポジウム
  • Place of Presentation: Chinese Academy of Science in Beijing, China
  • Year and Date: 2008-02-24
• [Presentation] Hierarchical Ordered Fullerene Assemblies -Development of Novel Supramolecular Soft Materials-(依頼講演) (2007)
  • Author(s): Takashi Nakanishi
  • Organizer: Institute Seminar at Changchun Institute of Applied Chemistry
  • Place of Presentation: Chinese Academy of Science, China
  • Year and Date: 2007-12-13
• [Presentation] 超分子材料創製への挑戦-フラーレン超分子・分子間相互作用の精密制御-(依頼講演) (2007)
  • Author(s): 中西尚志
  • Organizer: 名古屋大学G-COE in Chemistry, Materials Chemistry Seminar
  • Place of Presentation: 名古屋大学工学部
  • Year and Date: 2007-12-11
• [Presentation] フラワー状フラーレン超分子組織体 (2007)
  • Author(s): 中西尚志,竹内正之,有賀克彦,Dirk G.Kurth
  • Organizer: 第18回MRS日本学術シンポジウム
  • Place of Presentation: 日本大学駿河台
  • Year and Date: 2007-12-08
• [Presentation] フラーレン超分子階層組織化による超撥水膜表面の創製 (2007)
  • Author(s): 中西尚志,竹内正之,有賀克彦,Dirk G.Kurth
  • Organizer: 第18回MRS日本学術シンポジウム
  • Place of Presentation: 日本大学駿河台
  • Year and Date: 2007-12-08
• [Presentation] 超分子材料創製を指向した多形フラーレン集合体の開発(依頼講演) (2007)
  • Author(s): 中西尚志
  • Organizer: 千葉大学工学部セミナー
  • Place of Presentation: 千葉大学工学部
  • Year and Date: 2007-12-07
• [Presentation] フラワー状フラーレン超分子組織体の形成メカニズムおよび応用(ポスター賞受賞) (2007)
  • Author(s): 中西尚志,高橋宏和,竹内正之,Dirk G.Kurth,有賀克彦
  • Organizer: 第60回コロイドおよび界面化学討論会
  • Place of Presentation: 信州大学
  • Year and Date: 2007-09-22
• [Presentation] フラーレン超分子を素材とするナノカーボン超撥水表面の創製 (2007)
  • Author(s): 中西尚志,竹内正之,Dirk G.Kurth,有賀克彦
  • Organizer: 第60回コロイドおよび界面化学討論会
  • Place of Presentation: 信州大学
  • Year and Date: 2007-09-20
• [Presentation] Supramolecular Self-Organized Systems of Fullerenes Bearing Long Alkyl Chains (2007)
  • Author(s): Takashi Nakanishi, Hirokazu Takahashi, Tsuyoshi Michinobu, Dirk G. Kurth, Katsuhiko Ariga
  • Organizer: The 12th International Conference on Organized Molecular Films
  • Place of Presentation: Krakow, Poland
  • Year and Date: 2007-07-02
• [Book] Materialization of Fullerenes(BOTTOM-UP NANOFABRICATION) (2009)
  • Author(s): Takashi Nakanishi, Kun'ichi Miyazawa, Katsuhiko Ariga
  • Total Pages: 249-263
  • Publisher: American Scientific Publishers
• [Book] Supramolecular Chemistry of Fullerenes : Regulation of Properties and Self-Organized Structures of Fullerenes(BOTTOM-UP NANOFABRICATION) (2009)
  • Author(s): Takashi Nakanishi, Katsuhiko Ariga
  • Publisher: American Scientific Publishers
• [Book] 自己組織化による凹凸制御(撥水・撥油の技術と材料) (2008)
  • Author(s): 中西尚志
  • Total Pages: 114-124
  • Publisher: シーエムシー出版
• [Book] フラーレン超分子の微細加工技術と展望(ナノカーボンハンドブック) (2008)
  • Author(s): 中西尚志,道信剛志
  • Total Pages: 695-699
  • Publisher: エヌ・ティー・エス
• [Book] 有機溶媒によるフラーレン集合体の作製(ナノカーボンハンドブック) (2007)
  • Author(s): 中西尚志,有賀克彦
  • Total Pages: 588-594
  • Publisher: エヌ・ティー・エス
• [Book] フラーレン超分子化学(ナノカーボンハンドブック) (2007)
  • Author(s): 中西尚志,中嶋直敏
  • Total Pages: 567-581
  • Publisher: エヌ・ティー・エス
• [Patent(Industrial Property Rights)] 撥水性超分子組織体およびその製造方法 (2009)
  • Inventor(s): 中西尚志
  • Industrial Property Rights Holder: 物質・材料研究機構/科学技術振興機構
  • Industrial Property Number: 特願2009-81977
  • Filing Date: 2009-03-30
• [Patent(Industrial Property Rights)] 機能性金属複合基板およびその製造方法 (2008)
  • Inventor(s): 中西尚志
  • Industrial Property Rights Holder: 物質・材料研究機構/科学技術振興機構
  • Industrial Property Number: 特願2008-276146
  • Filing Date: 2008-10-27
• [Patent(Industrial Property Rights)] ナノフレーク状金属複合材料、その製造方法および表面増強ラマン散乱活性基板 (2008)
  • Inventor(s): 中西尚志、有賀克彦
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 特願2008-199217
  • Filing Date: 2008-08-01
• [Patent(Industrial Property Rights)] フレーレン誘導体組成物とこれを用いた電界効果トランジスタ素子 (2008)
  • Inventor(s): 中西尚志
  • Industrial Property Rights Holder: 物質・材料研究機構/科学技術振興機構
  • Industrial Property Number: 特願2008-163860
  • Filing Date: 2008-06-23
• [Patent(Industrial Property Rights)] 液状フラーレン誘導体、その製造方法、および、それを用いた素子 (2007)
  • Inventor(s): 中西尚志,道信剛志,ジョナサン・ヒル,有賀克彦
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: PCT,JP2007/63502
  • Filing Date: 2007-07-05
  • Overseas
• [Patent(Industrial Property Rights)] 超分子組織体およびその製造方法 (2007)
  • Inventor(s): 中西尚志,有賀克彦,Dirk G.Kurth
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Patent Publication Number: 特開2008-303148
  • Filing Date: 2007-06-05