2020 Fiscal Year Annual Research Report
New Functional Ceramic Membranes Using Nanoporous Metals
Project/Area Number |
19F19074
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Research Institution | National Institute for Materials Science |
Principal Investigator |
目 義雄 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, NIMS招聘研究員 (00354217)
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Co-Investigator(Kenkyū-buntansha) |
JIANG BO 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 外国人特別研究員
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Project Period (FY) |
2019-04-25 – 2021-03-31
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Keywords | mesoporous materials |
Outline of Annual Research Achievements |
We develop a sophisticated and controllable dual-reducing agent strategy to synthesize the mesoporous nickel–cobalt boron (NiCoB) amorphous alloy spheres (AASs) with adjustable compositions by using a soft template-directed assembly approach. The selective use of tetrabutylphosphonium bromide (Bu4PBr) is beneficial to generate well-defined mesopores. Our meso-Ni10.0Co74.5B15.5 AASs generate the highest catalytic performance for the hydrolytic dehydrogenation of ammonia borane (AB). Its high performance is attributed to the combination of optimal synergistic effects between Ni, Co, and B as well as the high surface area and the good mass transport efficiency due to the open mesopores.
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Research Progress Status |
令和2年度が最終年度であるため、記入しない。
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Strategy for Future Research Activity |
令和2年度が最終年度であるため、記入しない。
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Research Products
(2 results)
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[Journal Article] morphous Alloy Architectures in Pore Walls: Mesoporous Amorphous NiCoB Alloy Spheres with Controlled Compositions via a Chemical Reduction2020
Author(s)
Yunqing Kang, Bo Jiang, Juanjuan Yang, Zhe Wan, Jongbeom Na, Qian Li, Hexing Li, Joel Henzie, Yoshio Sakka, Yusuke Yamauchi, Toru Asahi.
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Journal Title
ACS Nano.
Volume: 14
Pages: 17224-17232
DOI
Peer Reviewed / Int'l Joint Research