2021 Fiscal Year Annual Research Report
Porous porphyrin solids for photochemical applications
| Project/Area Number |
19F19758
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
HILL Jonathan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, グループリーダー (30421431)
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| Co-Investigator(Kenkyū-buntansha) |
HYNEK JAN 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
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| Project Period (FY) |
2019-11-08 – 2022-03-31
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| Keywords | Porphyrin / Singlet Oxygen / Metal Organic Framework / Porous polymers / Macrocycles |
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| Outline of Annual Research Achievements |
Compounds based on oxidized porphyrins were prepared and tested for their action for the photochemical generation of singlet oxygen. The materials were then utilized for oxidation of organic substrate and tested for use as antimicrobial materials.
The zirconium-based porous coordination polymers were prepared and were found to generate singlet oxygen with good efficiency. These materials were then used to oxidize small organic molecules as models for pharmaceutical intermediates or toxic materials. This work was published.
Another class of porous polymers was prepared and those materials were found to promote oxidation of the model substrate with better selectivity for mild oixidation. Other macrocycles were also tested for singlet oxygen generation.
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| Research Progress Status |
令和3年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和3年度が最終年度であるため、記入しない。
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[Journal Article] Photosensitizer Encryption with Aggregation Enhanced Singlet Oxygen Production2022
Author(s)
Clarisse Bloyet, Flavien Sciortino, Yoshitaka Matsushita, Paul A. Karr, Anuradha Liyanage, Wipakorn Jevasuwan, Naoki Fukata, Subrata Maji, Jan Hynek, Francis D'Souza, Lok Kumar Shrestha, Katsuhiko Ariga, Tomohiko Yamazaki, Naoto Shirahata, Jonathan P. Hill, Daniel T. Payne
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Journal Title
Journal of the American Chemical Society
Volume: ー
Pages: ー
DOI
Peer Reviewed / Int'l Joint Research
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