• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2021 Fiscal Year Annual Research Report

Shaping Conducting Polymer Fibers by Means of Electrochemiluminescence Microscopy

Research Project

Project/Area Number 19F19769
Research InstitutionTokyo Institute of Technology

Principal Investigator

ビラニ エレナ  東京工業大学, 物質理工学院, 特任助教 (40943618)

Co-Investigator(Kenkyū-buntansha) VILLANI ELENA  東京工業大学, 物質理工学院, 外国人特別研究員
Project Period (FY) 2019-11-08 – 2022-03-31
Keywords電気化学発光 / バイポーラ電気化学 / ルミノール / 導電性高分子 / 電解重合 / イメージング
Outline of Annual Research Achievements

The combination of ECL and bipolar electrochemistry has resulted in a successful strategy to enrich the scientific knowledge of the research fellow regarding bipolar electrochemistry, and bipolar electrochemical systems in general. Indeed, in the research paper published in Analytical Chemistry, we have developed a simple and straightforward analytical tool to map the electrode potential established over a bipolar electrode, by imaging the location where the potential is suitable to trigger the luminescent reaction. Noteworthy, such analytical tool allows the quantification of the potential variation over the bipolar electrode when the geometry of the electrochemical cell or the positioning of the driving electrodes is varied, and also permits to monitor its evolution as a function of the total applied voltage. The strength of the method relies on the simplicity of use, because it can be readily adapted to any type of bipolar electrochemical configuration.
Another innovative approach explored during the collaborative research has been the use of different type of conducting polymer films as bipolar electrodes to generate the ECL emission from luminol and hydrogen peroxide in a wireless manner. The results of this research have been published in Electrochimica Acta journal as a part of the Special Issue of the 71st Annual Meeting of the International Society of Electrochemistry (ISE) held in 2020.

Research Progress Status

令和3年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和3年度が最終年度であるため、記入しない。

  • Research Products

    (15 results)

All 2022 2021 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Book (2 results) Remarks (2 results)

  • [Journal Article] A Flow Electrochemical Cell with Split Bipolar Electrode for Anodic Oxidation of Organic Compounds2022

    • Author(s)
      Sakagami Hiroki、Takenaka Hiroaki、Iwai Suguru、Shida Naoki、Villani Elena、Gotou Akihiro、Isogai Tomohiro、Yamauchi Akiyoshi、Kishikawa Yosuke、Fuchigami Toshio、Tomita Ikuyoshi、Inagi Shinsuke
    • Journal Title

      ChemElectroChem

      Volume: 9 Pages: e202200084

    • DOI

      10.1002/celc.202200084

    • Peer Reviewed
  • [Journal Article] Bipolar Electrochemical Fluorination of Triphenylmethane and Bis(phenylthio)diphenylmethane Derivatives in a U-shaped Cell2021

    • Author(s)
      SHIDA Naoki、VILLANI Elena、SANUKI Mokurai、MIYAMOTO Kazuhiro、GOTOU Akihiro、ISOGAI Tomohiro、YAMAUCHI Akiyoshi、FUCHIGAMI Toshio、TOMITA Ikuyoshi、INAGI Shinsuke
    • Journal Title

      Electrochemistry

      Volume: 89 Pages: 476~479

    • DOI

      10.5796/electrochemistry.21-00074

    • Peer Reviewed / Open Access
  • [Journal Article] Electrogenerated chemiluminescence of luminol on wireless conducting polymer films2021

    • Author(s)
      Villani Elena、Shida Naoki、Inagi Shinsuke
    • Journal Title

      Electrochimica Acta

      Volume: 389 Pages: 138718~138718

    • DOI

      10.1016/j.electacta.2021.138718

    • Peer Reviewed
  • [Journal Article] Mapping the Distribution of Potential Gradient in Bipolar Electrochemical Systems through Luminol Electrochemiluminescence Imaging2021

    • Author(s)
      Villani Elena、Inagi Shinsuke
    • Journal Title

      Analytical Chemistry

      Volume: 93 Pages: 8152~8160

    • DOI

      10.1021/acs.analchem.0c05397

    • Peer Reviewed
  • [Journal Article] Recent progress in bipolar electropolymerization methods toward one-dimensional conducting polymer structures2021

    • Author(s)
      Chen Zhenghao、Villani Elena、Inagi Shinsuke
    • Journal Title

      Current Opinion in Electrochemistry

      Volume: 28 Pages: 100702~100702

    • DOI

      10.1016/j.coelec.2021.100702

    • Peer Reviewed
  • [Presentation] π共役高分子膜の共反応物型電気化学発光に関する研究2022

    • Author(s)
      梅津 和将・Villani Elena・信田 尚毅・冨田 育義・稲木 信介
    • Organizer
      日本化学会 第102回春季年会
  • [Presentation] Selective Deposition of Aggregation Induced Emission Molecules on Patterned Metal/conducting polymers Electrodes by an Electrolytic Micellar Disruption Approach2022

    • Author(s)
      周 亜倩・張 厳匀・ビラニ エレナ・冨田 育義・稲木 信介
    • Organizer
      電気化学会第89回大会
  • [Presentation] Luminol Electrochemiluminescence Imaging on Wireless Conducting Polymer Film Structures2021

    • Author(s)
      Villani, E.; Zhang, Y.; Shida, N.; Koizumi, Y.; Endo, K.; Tomita, I.; Inagi, S.
    • Organizer
      72nd Annual Meeting of the International Society of Electrochemistry
    • Int'l Joint Research
  • [Presentation] Visualizing the distribution of potential gradient in bipolar electrochemical systems using electrochemiluminescence imaging2021

    • Author(s)
      Villani, E.; Inagi, S.
    • Organizer
      18th International Symposium on Electroanalytical Chemistry
    • Int'l Joint Research / Invited
  • [Presentation] Luminol Electrochemiluminescence Imaging on Wireless Conducting Polymer Film Structures2021

    • Author(s)
      Vilani Elena・Zhou Yaqian・信田 尚毅・冨田 育義・稲木 信介
    • Organizer
      2021年電気化学秋季大会
  • [Presentation] Electrochemiluminescence of Luminol on Conductive Poly (3,4-ethylenedioxythiophene) and its Composites in the Film State2021

    • Author(s)
      Yanyun Zhang・Elena Villani・Naoki Shida・Ikuyoshi Tomita・Shinsuke Inagi
    • Organizer
      第45回有機電子移動化学討論会
  • [Book] Science of Synthesis: Electrochemistry in Organic Synthesis2021

    • Author(s)
      Elena Villani, Shinsuke Inagi
    • Total Pages
      19
    • Publisher
      Thieme
  • [Book] 有機電解合成の新潮流2021

    • Author(s)
      稲木信介,ビラニエレナ,信田尚毅
    • Total Pages
      9
    • Publisher
      シーエムシー出版
  • [Remarks] エレナビラニプロフィール 稲木研究室

    • URL

      http://www.echem.titech.ac.jp/~inagi/VillaniProfile.html

  • [Remarks] Profile Dr. Elena Villani

    • URL

      http://www.echem.titech.ac.jp/~inagi/e-VillaniProfile.html

URL: 

Published: 2022-12-28  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi