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2021 Fiscal Year Annual Research Report

Exploiting cascade reactions of high performance tearylenes for solar applications.

Research Project

Project/Area Number 19K15312
Research InstitutionNara Institute of Science and Technology

Principal Investigator

Martin Colin  奈良先端科学技術大学院大学, 研究推進機構, 特任助教 (70836361)

Project Period (FY) 2019-04-01 – 2022-03-31
KeywordsTerarylenes / X-Rays / Cascade reaction / Photophysics
Outline of Annual Research Achievements

This grant focused on three key research areas (A, B and C).
A - Optimization of the cascade reaction: Analysis of the first generation (G1) of five molecules complete with photophysical, thermal and electrochemical analysis was completed in Year 2. In year 3 a further 8 molecules were prepared and tested. B - Studies of the cascade reaction in plastic/solid media: This part of the project was expanded from polymers and gels to also include other media such as micelles and pickering emulsions in conjunction with Assistant Professor M. Louis in the Kawai laboratory at NAIST. A Masters student has begun work on this topic. With the conclusion of my research position this part of the research topic will be continued in conjunction with Dr. Louis in NAIST. C - Expansion of frameworks towards detection of X-rays: A further second generation (G2) of eight targets designed to increase X-Ray absorption have now been prepared and fully characterized. These are added to the first generation prepared in Year 1 of this project. With the conclusion of my research position this part of the research topic will be continued in conjunction with Dr. Louis in NAIST.
A number of papers in these areas have been published

  • Research Products

    (5 results)

All 2021

All Journal Article (4 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Molecular Rotor Functionalized with a Photoresponsive Brake2021

    • Author(s)
      Asato Ryosuke、Martin Colin J.、Abid Seifallah、Gisbert Yohan、Asanoma Fumio、Nakashima Takuya、Kammerer Claire、Kawai Tsuyoshi、Rapenne Gwenael
    • Journal Title

      Inorganic Chemistry

      Volume: 60 Pages: 3492~3501

    • DOI

      10.1021/acs.inorgchem.0c03330

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands2021

    • Author(s)
      Asato Ryosuke、Martin Colin J.、Gisbert Yohan、Abid Seifallah、Kawai Tsuyoshi、Kammerer Claire、Rapenne Gwenael
    • Journal Title

      RSC Advances

      Volume: 11 Pages: 20207~20215

    • DOI

      10.1039/D1RA03875C

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nanocars based on Polyaromatic or Porphyrinic Chassis2021

    • Author(s)
      Nishino Toshio、Martin Colin J.、Yasuhara Kazuma、Rapenne Gwenael
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 79 Pages: 1050~1055

    • DOI

      10.5059/yukigoseikyokaishi.79.1050

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Energy Storage upon Photochromic 6-π Photocyclization and Efficient On-Demand Heat Release with Oxidation Stimuli2021

    • Author(s)
      Asato Ryosuke、Martin Colin J.、Nakashima Takuya、Calupitan Jan Patrick、Rapenne Gwenael、Kawai Tsuyoshi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 12 Pages: 11391~11398

    • DOI

      10.1021/acs.jpclett.1c03052

  • [Presentation] Systematic studies of structural variations in terarylene photohydride generators2021

    • Author(s)
      C. J. Martin, J. P. Calupitan, G. Rapenne, T. Nakashima and T. Kawai
    • Organizer
      RSC Photophysics and Photochemistry Group Early Career Members Meeting, Web meeting
    • Int'l Joint Research

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Published: 2022-12-28  

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