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2021 Fiscal Year Research-status Report

カーバイド前駆体を用いた低温ナノポーラスグラフェン合成法の開発

Research Project

Project/Area Number 19K15389
Research InstitutionTohoku University

Principal Investigator

韓 久慧  東北大学, 学際科学フロンティア研究所, 助教 (40823092)

Project Period (FY) 2019-04-01 – 2023-03-31
KeywordsNanoporous graphene / Single-atom catalysts / Electrocatalyst
Outline of Annual Research Achievements

We developed two types of single-atom catalysts for energy-related applications based on the successful development of 3D nanoporous graphene with tunable microstructure and physicochemical properties: 3D nanoporous graphene anchored with platinum atoms for electrochemical hydrogen production; and 3D nanoporous graphene co-anchored with nickel and copper atoms for the oxygen reduction reaction and high-performance rechargeable Zinc-air batteries. Energy devices have been developed that are highly efficient, have a high power density, and are sufficiently stable. Additionally, we released a review article summarizing our systematic study on the development, characterization, and application of 3D nanoporous graphene materials.

Current Status of Research Progress
Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

The purpose of this research is to develop multiscale 3D nanoporous graphene materials for a variety of functional applications. We have achieved the designable production of 3D nanoporous graphenes and investigated their applications for electrochemical energy storage over the last two years. This year, we expanded our focus to electrochemical energy conversions and developed advanced electrocatalysts using the 3D nanoporous graphene materials. As a result, our research proceeds smoothly as planned.

Strategy for Future Research Activity

We intend to continue developing novel materials and innovative energy technologies based on three-dimensional nanoporous graphene. Additionally, we will investigate template-free methods for 3D graphene synthesis.

  • Research Products

    (20 results)

All 2022 2021 Other

All Journal Article (11 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 11 results) Presentation (7 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results) Remarks (2 results)

  • [Journal Article] 3D Continuously Porous Graphene for Energy Applications2022

    • Author(s)
      Han Jiuhui、Johnson Isaac、Chen Mingwei
    • Journal Title

      Advanced Materials

      Volume: 34 Pages: 2108750~2108750

    • DOI

      10.1002/adma.202108750

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dealloyed nanoporous materials for electrochemical energy conversion and storage2022

    • Author(s)
      Sang Qinqin、Hao Shuo、Han Jiuhui、Ding Yi
    • Journal Title

      EnergyChem

      Volume: 4 Pages: 100069~100069

    • DOI

      10.1016/j.enchem.2022.100069

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrasmall AuPd nanoclusters on amine-functionalized carbon blacks as high-performance bi-functional catalysts for ethanol electrooxidation and formic acid dehydrogenation2022

    • Author(s)
      Cui Yuhuan、Zhao Ming、Zou Yining、Zhang Junyu、Han Jiuhui、Wang Zhili、Jiang Qing
    • Journal Title

      Journal of Energy Chemistry

      Volume: 68 Pages: 556~563

    • DOI

      10.1016/j.jechem.2021.12.029

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic shrinkage of metal-oxygen bonds in atomic Co-doped nanoporous RuO2 for acidic oxygen evolution2022

    • Author(s)
      Wu Qiuli、Jiang Kang、Han Jiuhui、Chen Dechao、Luo Min、Lan Jiao、Peng Ming、Tan Yongwen
    • Journal Title

      Science China Materials

      Volume: 65 Pages: 1262~1268

    • DOI

      10.1007/s40843-021-1912-8

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Local Atomic Structure on Sodium Ion Storage in Hard Amorphous Carbon2021

    • Author(s)
      Han Jiuhui、Johnson Isaac、Lu Zhen、Kudo Akira、Chen Mingwei
    • Journal Title

      Nano Letters

      Volume: 21 Pages: 6504~6510

    • DOI

      10.1021/acs.nanolett.1c01595

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanoporous B13C2 towards Highly Efficient Electrochemical Nitrogen Fixation2021

    • Author(s)
      Lan Jiao、Luo Min、Han Jiuhui、Peng Ming、Duan Huigao、Tan Yongwen
    • Journal Title

      Small

      Volume: 17 Pages: 2102814~2102814

    • DOI

      10.1002/smll.202102814

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vapor phase dealloying kinetics of MnZn alloys2021

    • Author(s)
      Lu Zhen、Zhang Fan、Wei Daixiu、Han Jiuhui、Xia Yanjie、Jiang Jing、Zhong Mingwang、Hirata Akihiko、Watanabe Kentaro、Karma Alain、Erlebacher Jonah、Chen Mingwei
    • Journal Title

      Acta Materialia

      Volume: 212 Pages: 116916~116916

    • DOI

      10.1016/j.actamat.2021.116916

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dilute molybdenum atoms embedded in hierarchical nanoporous copper accelerate the hydrogen evolution reaction2021

    • Author(s)
      Luo Min、Peng Wei、Zhao Yang、Lan Jiao、Peng Ming、Han Jiuhui、Li Hongju、Tan Yongwen
    • Journal Title

      Scripta Materialia

      Volume: 191 Pages: 56~61

    • DOI

      10.1016/j.scriptamat.2020.09.011

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Visualizing the {110} surface structure of equilibrium-form ZIF-8 crystals by low-dose Cs-corrected TEM2021

    • Author(s)
      Han Xiaocang、Chen Wenqian、Su Rui、Tian Yuan、Liu Pan、Guan Pengfei、Luo Min、Han Jiuhui、Cao Xiaoxiao、Pan Ming、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Pages: 13215~13219

    • DOI

      10.1039/D1NR03829J

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene-coated nanoporous nickel towards a metal-catalyzed oxygen evolution reaction2021

    • Author(s)
      Qiu Hua-Jun、Johnson Isaac、Chen Luyang、Cong Weitao、Ito Yoshikazu、Liu Pan、Han Jiuhui、Fujita Takeshi、Hirata Akihiko、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Pages: 10916~10924

    • DOI

      10.1039/D1NR02074A

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic Ni and Cu co-anchored 3D nanoporous graphene as an efficient oxygen reduction electrocatalyst for zinc-air batteries2021

    • Author(s)
      Cheng Yongtai、Wu Haofei、Han Jiuhui、Zhong Siying、Huang Senhe、Chu Shufen、Song Shuangxi、Reddy Kolan Madhav、Wang Xiaodong、Wu Shaoyi、Zhuang Xiaodong、Johnson Isaac、Liu Pan、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Pages: 10862~10870

    • DOI

      10.1039/D1NR01612A

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 3D nanoporous graphene-based platinum single-atom electrocatalysts for efficient hydrogen production2021

    • Author(s)
      Jiuhui Han
    • Organizer
      VANJ Conference 2021 (VANJ2021) - Bridging Academic and Industry
    • Int'l Joint Research / Invited
  • [Presentation] 3D nanoporous graphene-based single-atom electrocatalysts for efficient hydrogen production2021

    • Author(s)
      Jiuhui Han
    • Organizer
      8th Workshop of Ensemble Project for Young Researchers
  • [Presentation] 3D nanoporous energy materials: The extension from metal to functional carbon structures2021

    • Author(s)
      Jiuhui Han
    • Organizer
      Dealloying Webinar
    • Int'l Joint Research / Invited
  • [Presentation] Effect of Local Atomic Structure on Sodium-Ion Storage in Hard Amorphous Carbon2021

    • Author(s)
      Jiuhui Han
    • Organizer
      日本金属学会2021年秋期(第169回)講演大会
  • [Presentation] 3D nanoporous carbon-based energy materials2021

    • Author(s)
      Jiuhui Han
    • Organizer
      Chinese Materials Conference 2021
    • Int'l Joint Research / Invited
  • [Presentation] 2D graphene in a 3D architecture: New opportunities from bicontinuous nanoporous graphene2021

    • Author(s)
      Jiuhui Han
    • Organizer
      International Young Scholar Forum, The Institute of Physics, Chinese Academy of Science
    • Int'l Joint Research / Invited
  • [Presentation] Development and characterization of 3D nanoporous graphene2021

    • Author(s)
      Jiuhui Han
    • Organizer
      The 32nd Chinese Chemical Society Congress
    • Int'l Joint Research / Invited
  • [Remarks] ハードカーボン内のナトリウムイオンの貯蔵メカニズムに関する新たなモデル

    • URL

      https://www.tohoku.ac.jp/japanese/2021/06/press20210628-01-carbon.html

  • [Remarks] 材料化学: 化学的脱合金化法を用いて新しい多孔質カーボン電極を合成

    • URL

      https://www.wpi-aimr.tohoku.ac.jp/jp/aimresearch/highlight/2021/20210531_001395.html

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Published: 2022-12-28  

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