2019 Fiscal Year Final Research Report
Development of environmentally benign oxidation system utilizing iron complex catalyst bearing functional ligand
| Project/Area Number |
19K21137
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| Project/Area Number (Other) |
18H05992 (2018)
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Multi-year Fund (2019)
Single-year Grants (2018) |
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| Review Section |
0502:Inorganic/coordination chemistry, analytical chemistry, inorganic materials chemistry, energy-related chemistry, and related fields
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2018-08-24 – 2020-03-31
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| Keywords | 脱水素的酸化 / 錯体触媒 / 協働作用配位子 |
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| Outline of Final Research Achievements |
Screening of iron complex catalysts bearing various functional ligands in acceptorless dehydrogenation of alcoholic compounds were performed, albeit efficient and promising catalytic system could not be achieved. During this investigation, novel type of iridium complex with new functional ligand, working along with another metal-ligand cooperating mechanism than previous catalyst, could be found. This findings provides useful information on future development of efficient dehydrogenation catalyst.
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| Free Research Field |
有機金属化学
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| Academic Significance and Societal Importance of the Research Achievements |
環境調和性に優れた脱水素型酸化反応はこれまで貴金属錯体を触媒として達成されてきた．この反応を資源量の多く持続可能性の高い鉄錯体触媒への代替を見据えて配位子・錯体の開発検討を試みた．残念ながら，将来的に発展可能性が期待できる鉄錯体触媒系を見出すには至らなかったが，従来の貴金属系において有効な配位子系を新たに見出すことには成功し，効率的な錯体触媒の開発におけるライブラリーを増やすことができた．
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