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2020 Fiscal Year Annual Research Report

Experimental study on photochemistry of water and CO molecules on silicate dust

Research Project

Project/Area Number 19K23449
Research InstitutionHokkaido University

Principal Investigator

NGUYEN THANH  北海道大学, 低温科学研究所, 博士研究員 (40846599)

Project Period (FY) 2019-08-30 – 2021-03-31
KeywordsMolecular clouds / Astrochemistry
Outline of Annual Research Achievements

I have experimentally studied the chemical desorption and physico-chemical behavior of phosphine molecules, which is one of curial molecules of phosphorus (P)-bearing species in molecular clouds.
I have completed the study involving the physico-chemical behavior of PH3 by the H-D substitution reaction in dust grains (Nguyen et al. submitted to ApJ (2021)). I found that phosphine and its deuterated isotopologue PD3 are released into the gas phase from icy surfaces via chemical desorption. Since the activation barriers for the abstraction of H or D atoms is 1500 K, quantum tunneling should play a role at low temperatures. Under the present experimental conditions, the H-D substitution reactions of PH3 is slightly lower than the D-H substitution reactions of PD3. Therefore, the rates of the substitution reactions should not be constrained by quantum tunneling but rather by other elementary processes such as atom diffusion on ice. In addition, the experimental results suggest the possible presence of deuterated phosphine isotopologue (PH2D) in PH3-rich interstellar environments.

  • Research Products

    (4 results)

All 2020 Other

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Remarks (1 results)

  • [Journal Article] UV-ray irradiation never causes amorphization of crystalline CO2: A transmission electron microscopy study2020

    • Author(s)
      M.Tsuge, T. Nguyen, Y. Oba, T. Hama, A. Kouchi, N. Watanabe
    • Journal Title

      Chemical Physics Letters

      Volume: 760 Pages: 137999(6pp)

    • DOI

      10.1016/j.cplett.2020.137999

    • Peer Reviewed
  • [Journal Article] An Experimental Study of Chemical Desorption for Phosphine in Interstellar Ice2020

    • Author(s)
      T. Nguyen, Y. Oba, T. Shimonishi , A. Kouchi , and N. Watanabe
    • Journal Title

      The Astrophysical Journal Letters

      Volume: 898 Pages: L52 (6pp)

    • DOI

      10.3847/2041-8213/aba695

    • Peer Reviewed / Open Access
  • [Journal Article] A new multi-beam apparatus for the study of surface chemistry routes to formation of complex organic molecules in space2020

    • Author(s)
      E. Congiu, A. Sow, T. Nguyen, S. Baouche, F. Dulieu
    • Journal Title

      Review of Scientific Instruments

      Volume: 91 Pages: 124504(36pp)

    • DOI

      10.1063/5.0018926

    • Peer Reviewed / Int'l Joint Research
  • [Remarks] Astrophysical Chemistry /Ice& Planetary Science

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/index.html

URL: 

Published: 2021-12-27  

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