2011 Fiscal Year Final Research Report
Metal Catalyzed Reversible Conversion between Chemical Energy and Electrical One
| Project/Area Number |
20002005
|
|---|
| Research Category |
Grant-in-Aid for Specially Promoted Research
|
| Allocation Type | Single-year Grants |
|---|
| Review Section |
Science and Engineering
Chemistry
|
|---|
| Research Institution | Institute for Molecular Science |
|---|
Principal Investigator |
TANAKA Koji 分子科学研究所, 生命錯体分子科学研究領域, 教授 (00029274)
|
|---|
| Project Period (FY) |
2008 – 2011
|
| Keywords | 二酸化炭素還元 / 化学エネルギー変換 / 有機ヒドリド試薬 / 光誘起多電子還元反応 / NAD/NADHモデル配位子 |
|---|
| Research Abstract |
Irradiation of visible light to newly prepared Ru^<II> complexes enabled C-H bond formation using water molecules as the hydrogen source. The process for O-O bond formation through a coupling reaction of two water molecules was detected for the first time by the Resonance Raman spectra of a dinuclear Ru complex that has an ability to catalyze four electron oxidation of water. An Ru^<III>-oxyl radical complex showed novel functionalities in the oxidation of methanol as hydrogen atom acceptor and one electron receiver, respectively.
|
-
-
-
-
-
-
-
-
-
[Journal Article] Characterization of redox states of Ru(OH_2)(Q)(tpy)^<2+>(Q=3, 5-di-tert-butyl-1, 2-benzoquinone, tpy=2, 2': 6', 2"-terpyridine) and related species through experimental and theoretical studies2009
Author(s)
M.-K. Tsai, J. Rochford, D. E. Polyansky, T. Wada, K. Tanaka, E. Fujita, J. T. Muckerman
-
Journal Title
Inorg. Chem
Volume: 48
Pages: 4372-4383
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
