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2010 Fiscal Year Final Research Report

Investigation of crystal growth mechanisms of Si crystals floating on Si melt and development of crystal growth technique to realize high-quality Si multicrystals

Research Project

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Project/Area Number 20226001
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Applied materials science/Crystal engineering
Research InstitutionTohoku University

Principal Investigator

NAKAJIMA Kazuo  Tohoku University, エネルギー科学研究科, 客員教授 (80311554)

Co-Investigator(Kenkyū-buntansha) USAMI Noritaka  東北大学, 金属材料研究所, 准教授 (20262107)
FUJIWARA Kozo  東北大学, 金属材料研究所, 准教授 (70332517)
KUTSUKAKE Kentaro  東北大学, 金属材料研究所, 助教 (00463795)
MORISHITA Kohei  京都大学, エネルギー科学研究科, 特定助教 (00511875)
Project Period (FY) 2008 – 2010
Keywords結晶成長 / シリコン / 太陽電池
Research Abstract

We clarified fundamental crystal growth mechanisms of Si from melt such as formation mechanisms of microstructures and crystal defects by using an originally developed crystal growth furnace with in-situ observation system and model crystal growth experiments with purposely designed multi-seed crystals. The newly obtained fundamental knowledge on crystal growth mechanisms has been successfully implemented for development of floating cast method as a novel crystal growth technique to realize high-quality Si multicrystals with controlled microstructures and crystal defects, which will be utilized for high-efficiency solar cells.

  • Research Products

    (42 results)

All 2011 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (21 results) Book (3 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Implementation of faceted dendrite growth on floating cast method to realize high-quality multicrsytalline Si ingot for solar cells2011

    • Author(s)
      N.Usami, I.Takahashi, K.Kutsukake, K.Fujiwara, K.Nakajima
    • Journal Title

      J.Appl.Phys. 109

      Pages: 083527(4)

    • Peer Reviewed
  • [Journal Article] Impact of type of crystal defects in multicrystalline Si on electrical properties and interaction with impurities2011

    • Author(s)
      I.Takahashi, N.Usami, H.Mizuseki, Y.Kawazoe, G.Stokkan, K.Nakajima
    • Journal Title

      J.Appl.Phys. 109

      Pages: 033504(5)

    • Peer Reviewed
  • [Journal Article] Pattern formation mechanism of a periodically faceted interface during crystallization of Si2010

    • Author(s)
      M.Tokairin, K.Fujiwara, K.Kutsukake, H.Kodama, N.Usami, K.Nakajima
    • Journal Title

      J.Cryst.Growth 312

      Pages: 3670-3674

    • Peer Reviewed
  • [Journal Article] Growth mechanism of the Si <110> faceted dendrite2010

    • Author(s)
      K.Fujiwara, H.Fukuda, N.Usami, K.Nakajima, S.Uda
    • Journal Title

      Phys.Rev.B 81

      Pages: 224106(5)

    • Peer Reviewed
  • [Journal Article] A computational investigation of relationship between shear stress and multicrystalline structure in silicon2010

    • Author(s)
      I.Takahashi, N.Usami, K.Kutsukake, K.Morishita, K.Nakajima
    • Journal Title

      Jpn.J.Appl.Phys. 49

      Pages: 04DP01(4)

    • Peer Reviewed
  • [Journal Article] Generation mechanism of dislocations during directional solidification of multicrystalline silicon using artificially designed seed2010

    • Author(s)
      I.Takahashi, N.Usami, K.Kutsukake, G.Stokkan, K.Morishita, K.Nakajima
    • Journal Title

      J.Crystal Growth 312

      Pages: 897-901

    • Peer Reviewed
  • [Journal Article] Relationship between grain boundary structures in Si multicrystals and generation of dislocations during crystal growth2010

    • Author(s)
      N.Usami, R.Yokoyama, I.Takahashi, K.Kutsukake, K.Fujiwara, K.Nakajima
    • Journal Title

      J.Appl.Phys. 107

      Pages: 013511(5)

    • Peer Reviewed
  • [Journal Article] Formation mechanism of the faceted interface: in-situ observation of the Si (100) crystal-melt interface during crystallization2009

    • Author(s)
      M.Tokairin, K.Fujiwara, K.Kutsukake, N.Usami, K.Nakajima
    • Journal Title

      Phys.Rev.B. 80

      Pages: 174108(4)

    • Peer Reviewed
  • [Journal Article] Growth Behavior of Faceted Si Crystals at Grain Boundary Formation2009

    • Author(s)
      K.Fujiwara, S.Tsumura, M.Tokairin, K.Kutsukake, N.Usami, S.Uda, K.Nakajima
    • Journal Title

      J.Cryst.Growth 312

      Pages: 19-23

    • Peer Reviewed
  • [Journal Article] Microstructures of Si multicrystals and their impact on minority carrier diffusion length2009

    • Author(s)
      H.Y.Wang, N.Usami, K.Fujiwara, K.Kutsukake, K.Nakajima
    • Journal Title

      Acta Materialia 57

      Pages: 3268-3276

    • Peer Reviewed
  • [Journal Article] Quantitative analysis of sub-grain boundaries in Si multicrystals and their impact on electrical properties and solar cell performance2009

    • Author(s)
      K.Kutsukake, N.Usami, T.Ohtaniuchi, K.Fujiwara, K.Nakajima
    • Journal Title

      J.Appl.Phys. 105

      Pages: 044909(4)

    • Peer Reviewed
  • [Journal Article] Floating cast method to realize high-quality Si bulk multicrystals for solar cells2009

    • Author(s)
      Y.Nose, I.Takahashi, W.Pan, N.Usami, K.Fujiwara, K.Nakajima
    • Journal Title

      J.Crystal Growth 311

      Pages: 228-231

    • Peer Reviewed
  • [Journal Article] Impact of defect density in Si bulk multicrystals on gettering effect of impurities2008

    • Author(s)
      I.Takahashi, N.Usami, R.Yokoyama, Y.Nose, K.Kutsukake, K.Fujiwara, K.Nakajima
    • Journal Title

      Jpn.J.Appl.Phys. 47

      Pages: 8790-8792

    • Peer Reviewed
  • [Journal Article] Structural origin of a cluster of bright spots in reverse bias electroluminescence image of solar cells based on Si multicrystals2008

    • Author(s)
      N.Usami, K.Kutsukake, K.Fujiwara, I.Yonenaga, K.Nakajima
    • Journal Title

      Appl.Phys.Express 1

      Pages: 075001(3)

    • Peer Reviewed
  • [Presentation] Toward realization of high-quality multicrystalline silicon for solar cells2010

    • Author(s)
      N.Usami
    • Organizer
      in The Forum on the Science and Technology of Silicon Materials 2010
    • Place of Presentation
      Okayama, Japan
    • Year and Date
      20101114-20101117
  • [Presentation] High efficiency solar cells obtained from small size ingots with 30cmφ by controlling the distribution and orientation of dendrite crystals using the dendritic casting method2010

    • Author(s)
      K.Nakajima, K.Morishita, K.Kutsukake, K.Fujiwara, N.Usami, S.Ono, I.Yamasaki
    • Organizer
      in the CSSC-4 Workshop(Invited Speaker)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      20101027-20101029
  • [Presentation] Impact of coherency of grain boundaries in Si multicrystals on materials properties to affect solar cell performance2010

    • Author(s)
      N.Usami, I.Takahashi, K.Kutsukake, K.Nakajima
    • Organizer
      in the CSSC-4 Workshop(Invited Speaker)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      20101027-20101029
  • [Presentation] Growth of high quality Si multicrystals by controlling their arrangement of dendrite crystals along the bottom of ingots and reducing the density of random grain boundaries2010

    • Author(s)
      K.Nakajima
    • Organizer
      in Nature Photonics Technology Conference "The Future of Photovoltaics", TFT hall(Invited Speaker)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      20101019-20101021
  • [Presentation] Impact of grain boundaries in multicrystalline Si on materials properties2010

    • Author(s)
      N.Usami
    • Organizer
      in 2010 International Conference of Solid State Devices and Materials
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      20100922-20100924
  • [Presentation] High efficiency solar cells obtained from small size ingots with 30cmφ by controlling the distribution and orientation of dendrite crystals grown along the bottom of the ingots2010

    • Author(s)
      K.Nakajima, K.Kutsukake, K.Fujiwara, N.Usami, S.Ono, I.Yamasaki
    • Organizer
      in The 25th European Photovoltaic Solar Energy Conference and Exhibition (25th EU PVSEC) The 5th World Conference on Photovoltaic Energy Conversion (WCPEC-5) Feria Valencia
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      20100906-20100910
  • [Presentation] Suppression of generation of dislocations in Si multicrystals by controlling coherency of grain boundaries at the initial stage of crystal growth2010

    • Author(s)
      N.Usami, I.Takahashi, R.Yokoyama, K.Kutsukake, K.Fujiwara, K.Nakajima
    • Organizer
      in The 25th European Photovoltaic Solar Energy Conference and Exhibition (25th EU PVSEC), The 5th World Conference on Photovoltaic Energy Conversion (WCPEC-5), Feria Valencia
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      20100906-20100910
  • [Presentation] Growth mechanism of Si faceted dendrites and its application to the casting method for growing structure-controlled polycrystalline Si ingots2010

    • Author(s)
      K.Fujiwara, K.Nakajima, K.Kutsukake, N.Usami, S.Uda
    • Organizer
      in the 16th International Conference on Crystal Growth
    • Place of Presentation
      Beijin, China
    • Year and Date
      20100808-20100813
  • [Presentation] Formation mechanism of twin boundaries in silicon multicrystals during crystal growth2010

    • Author(s)
      K.Kutsukake, T.Abe, N.Usami, K.Fujiwara, K.Morishita, K.Nakajima
    • Organizer
      in The 35th IEEE Photovoltaic Specialists Conference, Hawaii Convention Center, Honolulu, In Proceedings of The 35th IEEE Photovoltaic Specialists Conference(pp.810-811)(2010).
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      20100720-20100725
  • [Presentation] Quantitative Analysis of Defects and Microstructures in Si Multicrystals Using X-ray Diffraction2009

    • Author(s)
      K.Kutsukake, N.Usami, K.Fujiwara, K.Nakajima
    • Organizer
      in 19th International Photovoltaic Science and Engineering Conference and Exhibition (PVSEC19)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      20091109-20091113
  • [Presentation] Improvement in quantitative analysis of defects and microstructures in Si multicrystals using X-ray diffraction2009

    • Author(s)
      K.Kutsukake, N.Usami, K.Fujiwara, K.Nakajima
    • Organizer
      in 2009 International Conference on Solid State Devices and Materials (SSDM2009)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20091007-20091009
  • [Presentation] A computational investigation of relationship between shear stress and multicrystal structure in Si2009

    • Author(s)
      I.Takahashi, N.Usami, K.Kutsukake, K.Morishita, K.Nakajima
    • Organizer
      in 2009 International Conference on Solid State Devices and Materials (SSDM2009)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20091007-20091009
  • [Presentation] Control of microstructures and crystal defects in Si multicrystals grown by the casting method -how to improve the quality of multicrystals to the level of single crystals-2009

    • Author(s)
      K.Nakajima, N.Usami, K.Fujiwara, K.Kutsukake
    • Organizer
      in 24th European Photovoltaic Solar Energy Conference and Exhibition, CCH- Congress Center and International Fair Hamburg
    • Place of Presentation
      Hamburg, Germany
    • Year and Date
      20090921-20090924
  • [Presentation] How can we decrease defect density in Si multicrystals to realize high-efficiency solar cells?2009

    • Author(s)
      N.Usami, K.Kutsukake, I.Takahashi, R.Yokoyama, K.Fujiwara, K.Nakajima
    • Organizer
      in 24th European Photovoltaic Solar Energy Conference and Exhibition, CCH- Congress Center and International Fair
    • Place of Presentation
      Hamburg,Germany
    • Year and Date
      20090921-20090924
  • [Presentation] A computational investigation of relationship betwenn shear stress and multicrystal structure in Si2009

    • Author(s)
      I.Takahashi, N.Usami, R.Yokoyama, K.Kutsukake, K.Fujiwara, K.Morishita, K.Nakajima
    • Organizer
      in the CSSC-3 Workshop
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20090603-20090605
  • [Presentation] Growth of high-quality Si multicrystals using dendritic casting method and mechanism to obtain high-quality crystals with low defects2009

    • Author(s)
      K.Nakajima, K.Fujiwara, K.Kutsukake, N.Usami
    • Organizer
      in the CSSC-3 Workshop
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20090603-20090605
  • [Presentation] Analysis of microstructures in Si multicrystals and their impact on electrical properties2009

    • Author(s)
      N.Usami, H.Y.Wang, K.Fujiwara, K.Kutsukake, K, Nakajima
    • Organizer
      in the CSSC-3 Workshop
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20090603-20090605
  • [Presentation] Role of crystal growth in challenges to high-efficiency solar cells2009

    • Author(s)
      N.Usami, K.Fujiwara, K.Kutsukake, K.Nakajima
    • Organizer
      in GCOE Singapore workshop (NTU-Tohoku U)
    • Place of Presentation
      Singapore
    • Year and Date
      20090224-20090225
  • [Presentation] In-situ observation of Si (100) crystal-melt interface2009

    • Author(s)
      M.Tokairin, K.Fujiwara, K.Kutsukake, N.Usami, K.Nakajima
    • Organizer
      in GCOE Singapore workshop (NTU-Tohoku U)
    • Place of Presentation
      Singapore
    • Year and Date
      20090224-20090225
  • [Presentation] Comprehensive study of defects in Si Multicrystals Toward High-Efficiency Solar Cells2009

    • Author(s)
      K.Kutsukake, N, Usami, K.Fujiwara, K.Nakajima
    • Organizer
      in PVSEC18
    • Place of Presentation
      Kolkata, India
    • Year and Date
      20090119-20090123
  • [Presentation] Comprehensive study of sub-grain boundaries in Si multicrystals toward defect engineering for high-efficiency solar cell2008

    • Author(s)
      N.Usami, K.Kutsukake, K.Fujiwara, K.Nakajima
    • Organizer
      in the 5th International Symposium on Advanced Science and Technology of Silicon Materials
    • Place of Presentation
      Kona, USA
    • Year and Date
      20081110-20081114
  • [Book] 太陽電池の物理2010

    • Author(s)
      ペーターヴュルフェル著, 宇佐美徳隆、石原照也、中嶋一雄監訳
    • Publisher
      丸善
  • [Book] Fundamental understanding of subgrain boundaries(Advances in Materials Research 14)(Crystal Growth of Si for Solar Cells, edited by K.Nakajima, and N.Usami)(chap.6)2009

    • Author(s)
      K.Kutsukake, N.Usami, K.Fujiwara, K.Nakajima
    • Total Pages
      83-95
    • Publisher
      Springer
  • [Book] Mechanism of Dendrite Crystal(Advances in Materials Research 14)(Crystal Growth of Si for Solar Cells, edited by K.Nakajima, and N.Usami)(chap.5)2009

    • Author(s)
      K.Fujiwara, K.Nakajima
    • Total Pages
      71-81
    • Publisher
      Springer
  • [Patent(Industrial Property Rights)] Siバルク多結晶インゴットの製造方法2010

    • Inventor(s)
      宇佐美徳隆、中嶋一雄、高橋勲
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      特許,特許第4528995号
    • Acquisition Date
      2010-06-18
  • [Patent(Industrial Property Rights)] 半導体バルク結晶の作製方法2009

    • Inventor(s)
      中嶋一雄、藩伍根、野瀬嘉太郎
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      特許,特許第4292300号
    • Acquisition Date
      2009-04-17
  • [Patent(Industrial Property Rights)] 半導体バルク多結晶の製造方法2009

    • Inventor(s)
      宇佐美徳隆、中嶋一雄、沓掛健太朗
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      特願,特願2009-120594
    • Filing Date
      2009-05-19
  • [Patent(Industrial Property Rights)] Si結晶インゴットの製造方法

    • Inventor(s)
      中嶋一雄、宇佐美徳隆
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      特願,特願2008-180842

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Published: 2012-01-26   Modified: 2016-04-21  

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