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2011 Fiscal Year Final Research Report

Reaction control and creation of novel functionality with photoirradiation and application of electric field

Research Project

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Project/Area Number 20245001
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

OHTA Nobuhiro  北海道大学, 電子科学研究所, 教授 (70113529)

Co-Investigator(Renkei-kenkyūsha) NAKABAYASHI Takakazu  北海道大学, 電子科学研究所, 准教授 (30311195)
IIMORI Toshifumi  北海道大学, 電子科学研究所, 助教 (60360947)
Project Period (FY) 2008 – 2011
Keywords光反応ダイナミクス / 電子・エネルギー移動 / 光機能物性 / 電場効果 / 超伝導 / 光誘起相転移 / 蛍光寿命イメージング / バイオエレクトリクス
Research Abstract

It was shown that photochemical and photophysical dynamics could be controlled by application of electric fields in various molecular systems. It was also shown that electrical conductivity of materials could be controlled by photoirradiation and application of electric fields. For example, insulator, metal and superconductor could be converted to each other in some organic conducting materials, and novel functions could be created as a result of photoinduced phase transition in the presence of electric fields. Intracellular function was also shown to be influenced by application of nanosecond pulsed electric fields, based on the fluorescence lifetime imaging spectroscopy.

  • Research Products

    (27 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (5 results) Book (4 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Insulator-metal transitions induced by electric field and photoirradiation in organic2012

    • Author(s)
      F. Sabeth, T. Iimori, and N. Ohta
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Pages: 6984-6986

    • Peer Reviewed
  • [Journal Article] Gigantic photoresponse and reversible photoswitching in the ionic conductivity of polycrystalline-β-AgI2012

    • Author(s)
      F. Sabeth, T. Iimori, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 9209-9213

    • Peer Reviewed
  • [Journal Article] Gigantic electric dipole moment of organic microcrystals evaluated in dispersion liquid with polarized electroabsorption spectra2012

    • Author(s)
      H.-C. Chiang, T. Iimori, T. Onodera, H. Oikawa, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 8230-8235

    • Peer Reviewed
  • [Journal Article] Time-resolved photoresponse measurements of the electrical conductivity of the quasi-two-dimensional organic superconductor-β-(BEDT-TTF)_2I_3 using a nanosecond laser pulse2011

    • Author(s)
      T. Iimori, F. Sabeth, T. Naito, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Pages: 23998-24003

    • Peer Reviewed
  • [Journal Article] Intracellular pH sensing using autofluorescence lifetime microscopy2011

    • Author(s)
      S. Ogikubo, T. Nakabayashi, T. Adachi, Md. S. Islam, T. Yoshizawa, M. Kinjo, and N. Ohta
    • Journal Title

      J. Phys. Chem. B

      Volume: 115 Pages: 10385-10390

    • Peer Reviewed
  • [Journal Article] Magnetic field effects on electro-photoluminescence of photoinduced electron transfer systems in a polymer film2011

    • Author(s)
      K. Awasthi and N. Ohta
    • Journal Title

      J. Photochem. Photobiol. A

      Volume: 221 Pages: 1-12

    • Peer Reviewed
  • [Journal Article] Electroabsorption spectra of PbSe nanocrystal quantum dots2011

    • Author(s)
      X. Liu, T. Iimori, R. Ohshima, T. Nakabayashi, and N. Ohta
    • Journal Title

      Appl. Phys. Lett.

      Volume: 98 Pages: 161911-1-3

    • Peer Reviewed
  • [Journal Article] Photo-and field-induced charge-separation and phosphorescence quenching in organometallic complex Ir(ppy)_32011

    • Author(s)
      M. Mehata and N. Ohta
    • Journal Title

      Appl. Phys. Lett.

      Volume: 98 Pages: 181910-1-3

    • Peer Reviewed
  • [Journal Article] External Electric Field Effects on State Energy and Photoexcitation Dynamics of Water Soluble CdTe Nanoparticles2011

    • Author(s)
      R. Ohshima, T. Nakabayashi, Y. Kobayashi, N Tamai, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Pages: 15274-15281

    • Peer Reviewed
  • [Journal Article] Electric-field-Induced changes in absorption and fluorescence of the green fluorescent protein chromophore in a PMMA film2011

    • Author(s)
      T. Nakabayashi, K. Hino, Y. Ohta, S. Ito, H. Nakano, and N. Ohta
    • Journal Title

      J. Phys. Chem. B

      Volume: 115 Pages: 8622-8626

    • Peer Reviewed
  • [Journal Article] 超伝導状態を光で誘起できるか?-光と電場による有機電荷移動錯体の電気伝導特性の制御2011

    • Author(s)
      太田信廣、飯森俊文
    • Journal Title

      現代化学

      Volume: 6 Pages: 38-44

    • Peer Reviewed
  • [Journal Article] Photoirradiation effect on electrical conductivity in an organic superconductor : -κ-(BEDT-TTF)_2Cu[N(CN)_2]Br2011

    • Author(s)
      T. Iimori, T. Naito, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Pages: 23998-24003

    • Peer Reviewed
  • [Journal Article] Electric-field-induced enhancement/quenching of photoluminescence of π-conjugated polymer S3-PPV : Excitation energy dependence2011

    • Author(s)
      M. S. Mehata, C.-S. Hsu, Y.-P. Lee, and N. Ohta
    • Journal Title

      J. Phys. Chem. B

      Volume: 114 Pages: 6258-6265

    • Peer Reviewed
  • [Journal Article] Electric field effects on optical spectra and excitation dynamics of capped CdS quantum dots embedded in a polymer film2010

    • Author(s)
      M. S. Mehata, M. Majumder, B. Mallik, and N. Ohta
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Pages: 15594-15601

    • Peer Reviewed
  • [Journal Article] Fluorescence decay dynamics of flavin adenine dinucleotide in a mixture of alcohol and water in the femtosecond and nanosecond time range2010

    • Author(s)
      T. Nakabayashi, Md. S.Islam, and N. Ohta
    • Journal Title

      J. Phys. Chem. B

      Volume: 114 Pages: 15254-15260

    • Peer Reviewed
  • [Presentation] Unprecedented Optoelectronic Function in Organic Conductors2011

    • Author(s)
      N. Ohta and T. Iimori
    • Organizer
      IUPAC 7^<th> International Conference on Novel Materials and Synthesis (NMS-VII) & 21^<st> International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXI)
    • Place of Presentation
      Shanghai, China. (Invited)
    • Year and Date
      20111016-21
  • [Presentation] Photoinduced electron transfer in solid films in the presence of external electric fields2010

    • Author(s)
      N. Ohta
    • Organizer
      Reaction Kinetics in Condensed Matter, Moscow Region State University
    • Place of Presentation
      Moscow. (Invited)
    • Year and Date
      20100922-26
  • [Presentation] Fluorescence Lifetime Imaging Spectroscopy in Living Cells with Particular Regards to pH dependence and Electric Field Effect2010

    • Author(s)
      N. Ohta, T. Nakabayashi, S. Oshita, M. Kinjo
    • Organizer
      SPIE
    • Place of Presentation
      San Francisco. (Invited)
    • Year and Date
      2010-01-25
  • [Presentation] Electric Field Effects on Structure, Dynamics and Function of Photoexcited Molecules2009

    • Author(s)
      N. Ohta
    • Organizer
      The 6^<th> Korea-Japan Symposium on Frontier Photoscience (KJFP 2009) & 2009 International Conference on Frontier Photoscience and Functional Materials (ICFPFM 2009)
    • Place of Presentation
      Daejeon, South Korea. (Plenary)
    • Year and Date
      20091030-1103
  • [Presentation] Electric field effects on photoluminescence and excitation dynamics2008

    • Author(s)
      N. Ohta
    • Organizer
      Dynamics and Spectrowscopy of Samll Molecules and Biomolecules
    • Place of Presentation
      Taipei. (Invited)
    • Year and Date
      2008-11-11
  • [Book] Molecular Electronic and Related Materials-Control and Probe with Light2010

    • Author(s)
      T. Iimori, T. Naito and N. Ohta
    • Total Pages
      167-184
    • Publisher
      T. Naito, Research Signpost/Transworld Research Network, chap.
  • [Book] Fluorescence Lifetime Imaging Study on Living Cells with Particular Regard to Electric Field Effects and pH Dependence2009

    • Author(s)
      N. Ohta and T. Nakabayashi
    • Total Pages
      607-621
    • Publisher
      edited by H. Fukumura, M. Irie, Y. Iwasawa, H, Masuhara, ahd K.
  • [Book] 光科学研究の最前線22009

    • Author(s)
      太田信廣
    • Total Pages
      66
    • Publisher
      電場・磁場効果の光計測
  • [Book] 第6節蛍光寿命イメージングによる細胞内環境の計測、ナノイメージング(nano imaging)(分担執筆)、第4編先端イメージング技術の開発研究、第1章生体の組織や分子を動的に観察する2008

    • Author(s)
      中林孝和、太田信廣
    • Total Pages
      245-254
    • Publisher
      エヌ・ティー・エス(NTS)
  • [Remarks] 新聞報道「電場と光の相乗効果で電気の流れ易さをコントロールすることに成功」日経プレスリリース2012年4月26日科学新聞2012年5月18日

  • [Remarks] 「細胞内の水素イオン濃度、無染色で可視化成功」日経プレスリリース2011年8月26日科学新聞2011年9月2日日刊工業新聞2011年9月7日

  • [Patent(Industrial Property Rights)] 蛍光寿命を利用した細胞内のpHイメージング方法とその装置2011

    • Inventor(s)
      太田信廣、中林孝和、荻窪真也、足立貴志
    • Industrial Property Rights Holder
      北海道大学、富士フィルム株式会社
    • Industrial Property Number
      特許、2010-053215
    • Filing Date
      2011-03-10

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Published: 2013-07-31  

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