2010 Fiscal Year Final Research Report
Creation of metal complexes and their assemblies causing multi-mode reversible conversion of structures and physical properties
| Project/Area Number |
20245013
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
YAMANOI Yoshinori 東京大学, 大学院・理学系研究科, 准教授 (20342636)
KUME Shoko 東京大学, 大学院・理学系研究科, 助教 (30431894)
SAKAMOTO Ryota 東京大学, 大学院・理学系研究科, 助教 (80453843)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 多重物性 / 分子素子 / フォトクロミズム / 電子輸送 / レドックス |
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| Research Abstract |
This study aims at creation of metal complexes and their assemblies which undergo reversible and multiple mode conversion of structures and physical properties. In this study, it is expected to induce multiple stabilities not only by analyzing the physical properties of the molecules but also by operating the bonding nature of the molecules, and to find unique chemical bond formation from the molecules with unprecedented electronic structures. Redox-conjugated photochromic molecules, pyrylinium-containing fused ring compounds with strong intramolecular donor-acceptor interaction, metalladitholenes with photo-, magneto-, and electro-functions and their-extended systems were developed.
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Research Products
(56 results)
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[Journal Article] A Photosensing System Composed of Photosystem I, Molecular Wire, Gold Nanoparticle, and Double Surfactants in Water2010
Author(s)
M. Miyachi Y. Yamanoi, Y. Shibata, H. Matsumoto, K. Nakazato, M. Konno, K. Ito, Y. Inoue, and H. Nishihara
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Journal Title
Chem. Commun
Volume: 46
Pages: 2557-2559
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[Journal Article] Counterion-Dependent Valence Tautomerization of Ferrocenyl-Conjugated Pyrylium Salts2009
Author(s)
M. Kondo, M. Uchikawa, K. Namiki, W.-W. Zhang, S. Kume, E. Nishibori, H. Suwa, S. Aoyagi, M. Sakata, M. Murata, Y. Kobayashi, and H. Nishihara
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Journal Title
J. Am. Chem. Soc
Volume: 131
Pages: 12112-12124
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[Journal Article] Superior Electron-Transport Ability of-Conjugated Redox Molecular Wires Preparedby the Stepwise Coordination Method on a Surface2009
Author(s)
Y. Nishimori, K. Kanaizuka, T. Kurita, T. Nagatsu, Y. Segawa, F. Toshimitsu, S. Muratsugu, M. Utsuno, S. Kume, M. Murata, and H. Nishihara
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Journal Title
Chem. Asian J.
Volume: 4
Pages: 1361-1367
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