2010 Fiscal Year Final Research Report
Synthesis of Space-Controlled Lanthanide Complexes and Their Functionalization
| Project/Area Number |
20245014
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
TSUKUBE Hiroshi Osaka City University, 大学院・理学研究科, 教授 (00144725)
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| Co-Investigator(Kenkyū-buntansha) |
SHINODA Satoshi 大阪市立大学, 大学院・理学研究科, 准教授 (00285280)
MIYAKE Hiroyuki 大阪市立大学, 大学院・理学研究科, 准教授 (00271198)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 希土類錯体 / 超分子 / 発光センシング / 分子認識 / キラリティー変換 / 金属タンパク / 円二色性スペクトル / 発光材料 |
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| Research Abstract |
A series of lanthanide complexes have been developed, which had characteristic coordination spheres of 1 or 10 nm diameters. They offered selective luminescence and circular dichroism sensing of inorganic anions, amino acids, proton, and protein derivatives based on unique lanthanide coordination chemistry. The lanthanide complexes with octadentate cyclen ligands further exhibited enough high dynamism to mediate the chirality transfer processes.
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Research Products
(21 results)
