2010 Fiscal Year Final Research Report
Construction of Function-accumulated Supramolecules by Controlling Flexible Structure on the Basis of Formation of Helical Pseudomacrocycles
| Project/Area Number |
20245029
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
NABESHIMA Tatsuya University of Tsukuba, 大学院・数理物質科学研究科, 教授 (80198374)
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| Co-Investigator(Renkei-kenkyūsha) |
AKINE Shigehisa 筑波大学, 大学院・数理物質科学研究科, 准教授 (30323265)
IKEDA Chusaku 筑波大学, 大学院・数理物質科学研究科, 準研究員 (30378541)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 超分子化学 / 配位結合 / 環状構造 / 協同効果 / 分子認識 |
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| Research Abstract |
The purpose of this study is to construct function-accumulated supramolecular systems by utilizing formation of an organic-inorganic hybrid helical supramolecule and/or various non-covalent interactions. The key strategy is transformation of flexible molecular structure to rigid. In particular, N-containing heterocycles, catechol and imine derivatives were employed as a binding unit to metal ions. We succeeded in synthesis of a variety of supramolecular systems having high cooperativity and/or multi-responding functions.
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[Journal Article] Wheel-Shaped Er^<III>Zn^<II> 3 Single-Molecule Magnet : A Macrocyclic Approach to Designing Magnetic Anisotropy2011
Author(s)
Yamashita, A., Watanabe, A., Akine, S., Nabeshima, T., Nakano, M., Yamamura, T., Kajiwara, T.
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Journal Title
Angew.Chem., Int.Ed. 50
Pages: 4016-4019
Peer Reviewed
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[Journal Article] A Novel Cis-Trans Isomerism Found in a Sulfur-Bridged Pd^<II> 2Au^I 2 Tetranuclear Complex with [Pd(amine) 2(thiolato) 2]-Type Building Units2008
Author(s)
Taguchi, M., Sameshima, Y., Igashira-Kamiyama, A., Akine, S., Nabeshima, T., Konno, T.
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Journal Title
Chem.Lett.37
Pages: 244-245
Peer Reviewed
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[Journal Article] Synthesis, Stability, and Complexation Behavior of Isolable Salen-Type N 2S 2 and N 2SO Ligands Based on Thiol and Oxime Functionalities2008
Author(s)
Akine, S., Akimoto, A., Shiga, T., Oshio, H., Nabeshima, T.
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Journal Title
Inorg.Chem. 47
Pages: 875-885
Peer Reviewed
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