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2010 Fiscal Year Final Research Report

Low temperature fabrication of Si02/SiC structure by use of surface nanopores formed by nitric acid oxidation method

Research Project

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Project/Area Number 20246005
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University

Principal Investigator

KOBAYASHI Hikaru  Osaka University, 産業科学研究所, 教授 (90195800)

Co-Investigator(Kenkyū-buntansha) MATSUMOTO Taketoshi  大阪大学, 産業科学研究所, 助教 (20390643)
YAMAGUCHI Shunro  大阪大学, 産業科学研究所, 助教 (40167698)
Project Period (FY) 2008 – 2010
KeywordsSiC / SiO2 / 低温酸化 / MOS / 硝酸酸化 / リーク電流 / 水素処理 / 界面準位
Research Abstract

We have developed a method of low temperature formation by use of nitric acid oxidation method. 3C-SiC surfaces can be atomically flattened by hydrogen treatment at 400℃, and SiO_2/SiC structure with good electrical characteristics can be formed by two-step nitric acid oxidation method using 40 and 68wt% HNO_3 solutions below 120℃. The leakage current density flowing through SiO_2 is high with no hydrogen treatment, but it can be decreased by approximately six orders of magnitude using the hydrogen treatment. We have also fabricated SiO_2/4H-SiC structure by use of nitric acid vapor oxidation method at 600℃. The oxidation proceeds only from step edges, and the initial oxidation rate for C-face is 2.8 times higher than that for Si-face. For the Si-face, SiOC species is formed at the interface, while it is not present for the C-face.

  • Research Products

    (23 results)

All 2011 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (6 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Sub-micronmeter ultralow power TFT with 1.8nm NAOS SiO_2/20nm CVD SiON gate stack structure2011

    • Author(s)
      Y. Kubota, T. Matsumoto, S. Imai, M. Yamada, H. Tsuji, K. Taniguchi, S. Terakawa, H. Kobayashi
    • Journal Title

      IEEE Trans. 58(4)

      Pages: 1134-1140

    • Peer Reviewed
  • [Journal Article] Ultra-low power TFT with gate oxide fabricated by nitric acid oxidation method2010

    • Author(s)
      T. Matsumoto, Y. Kubota, M. Yamada, H. Tsuji, T. Shimatani, Y. Hirayama, S. Terakawa, S. Imai, H. Kobayashi
    • Journal Title

      IEEE Electron Device Lett. 31(8)

      Pages: 821-823

    • Peer Reviewed
  • [Journal Article] SiO_2/Si structure having low leakage current fabricated by nitric acid oxidation method with Si source2010

    • Author(s)
      T. Yanase, M. Matsumoto, H. Kobayashi
    • Journal Title

      Electrochem.Solid-State Lett. 13(7)

      Pages: H253-H256

    • Peer Reviewed
  • [Journal Article] Low temperature fabrication of 5~10nm SiO_2/Si structure using advanced nitric acid oxidation of silicon (NAOS) method2010

    • Author(s)
      Y. Fukaya, T. Yanase, Y. Kubota, S. Imai, T. Matsumoto, H. Kobayashi
    • Journal Title

      Appl.Surf.Sci. 256

      Pages: 5610-5613

    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of Si (NAOS) method for low temperature fabrication of SiO_2/Si and SiO_2/SiC structures2010

    • Author(s)
      H. Kobayashi, K. Imamura, W.-B. Kim, S.-S. Im, Asuha
    • Journal Title

      Appl.Surf.Sci. 256

      Pages: 5744-5756

    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with a low leakage current density formed with~100 % nitric acid vapor2010

    • Author(s)
      W.-B. Kim, T. Matsumoto, H. Kobayashi
    • Journal Title

      Nanotechnology 21

      Pages: 1152021-1152028

    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of SI method at 120℃ : HNO_3 concentration dependence2010

    • Author(s)
      K. Imamura, M. Takahashi, Asuha, Y. Hirayama, S. Imai, H. Kobayashi
    • Journal Title

      J.Appl.Phys. 107(5)

      Pages: 0545031-0545035

    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with an extremely low leakage current density formed in high concentration nitric acid2009

    • Author(s)
      W.-B. Kim, T. Matsumoto, H. Kobayashi
    • Journal Title

      J.Appl.Phys. 105

      Pages: 1037091-1037096

    • Peer Reviewed
  • [Journal Article] Band alignment of SiO_2/Si structure formed with nitric acid vapor below 500℃2009

    • Author(s)
      K. Imamura, M. Takahashi, S. Imai, H. Kobayashi
    • Journal Title

      Surf.Sci. 603(7)

      Pages: 968-972

    • Peer Reviewed
  • [Journal Article] Low temperature formation of SiO_2 thin films by nitric acid oxidation of Si (NAOS) and application to thin film transistor (TFT)2009

    • Author(s)
      T. Matsumoto, Asuha, W.-B. Kim, M. Yamada, S Imai, S. Terakawa, H. Kobayashi
    • Journal Title

      Microelectron.Eng. 86

      Pages: 1939-1941

    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer on atomically flat Si(111) surfaces with excellent electrical characteristics formed by nitric acid oxidation method2008

    • Author(s)
      W.-B. Kim, Asuha, T. Matsumoto, H. Kobayashi
    • Journal Title

      Appl.Phys.Lett. 93

      Pages: 072101-1-3

    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of 3C-SiC to fabricate MOS diodes with a low leakage current density2008

    • Author(s)
      M. Takahashi, S.-S. Im, M. Madani, H. Kobayashi
    • Journal Title

      J. Electrochem.Soc. 155(1)

      Pages: H47-51

    • Peer Reviewed
  • [Journal Article] Nitric Acid Oxidation Method to Form SiO_2/3C-SiC Structure at 120℃2008

    • Author(s)
      S.-S. Im, S. Terakawa, H. Iwasa, H. Kobayashi
    • Journal Title

      Appl.Surf.Sci. 254

      Pages: 3667-3671

    • Peer Reviewed
  • [Journal Article] SiC cleaning method by use of dilute HCN aqueous solutions2008

    • Author(s)
      M. Madani, Y.-L. Liu, M. Takahashi, H. Iwasa, H. Kobayashi
    • Journal Title

      J.Electrochem.Soc. 155(11)

      Pages: H895-H898

    • Peer Reviewed
  • [Presentation] Improvement of Si solar cell performance by new chemical methods : surface passivation, defect elimination, metal removal, and surface structure transfer2010

    • Author(s)
      小林光
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice(スロバキア)招待講演
    • Year and Date
      2010-11-22
  • [Presentation] Characterization of ultra-low power thin film transistors (TFTs) with SiO_2 layer formed by the nitric acid oxidation of Si (NAOS) method2010

    • Author(s)
      松本健俊, 小林光
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice(スロバキア)招待講演
    • Year and Date
      2010-11-22
  • [Presentation] 気相硝酸酸化(NAVOS)法によるSiO_2/4H-SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      SiC及び関連ワイドバンドギャップ半導体研究会第19回講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2010-11-14
  • [Presentation] 気相硝酸酸化法によるSiO_2/SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-23
  • [Presentation] Low temperature nitric acid oxidation of Si (NAOS) for fabrication of gate oxides in LSI and TFT2008

    • Author(s)
      小林光
    • Organizer
      The 1st International Symposium on Hybrid Materials and Processing
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2008-10-27
  • [Presentation] Nitric acid oxidation of Si at 120℃ to fabricate MOS Structure with excellent electrical characteristics2008

    • Author(s)
      小林光
    • Organizer
      1st International Conference on Thin Films and Porous Materials
    • Place of Presentation
      Zeralda, Algiers, Algeria
    • Year and Date
      2008-05-19
  • [Book] SiCパワーデバイス最新技術第11章SiCパワーデバイス用酸化膜の形成方法2010

    • Author(s)
      松本健俊、小林光
    • Total Pages
      138-159
    • Publisher
      サイエンス&テクノロジー株式会社
  • [Remarks] ホームページ

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/fcm/index.html

  • [Patent(Industrial Property Rights)] 半導体装置及びその製造方法2010

    • Inventor(s)
      小林光
    • Industrial Property Rights Holder
      小林光
    • Industrial Property Number
      特願2010-196672
    • Filing Date
      2010-09-02

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

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