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2010 Fiscal Year Final Research Report

Perovskite engineering : design of novel lead-free ferroelectric by the control of the chemical bonds

Research Project

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Project/Area Number 20246098
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

ITOH Mitsuru  Tokyo Institute of Technology, 応用セラミックス研究所, 教授 (30151541)

Co-Investigator(Renkei-kenkyūsha) TANIYAMA Tomoyasu  東京工業大学, 応用セラミックス研究所, 准教授 (10302960)
TANIGUCHI Hiroki  東京工業大学, 応用セラミックス研究所, 助教 (80422525)
Project Period (FY) 2008 – 2010
Keywords誘電体 / 磁性誘電体
Research Abstract

Strategy for lead-free ferroelectric and piezoelectric materials with perovskite-type structure was obtained based on the new idea based on the chemical bonds and crystal structures. As a result, many candidate materials were found out as well as new interpretation on the mechanism for the evolution of known ferroelectric materials. Thin films of novel compounds, which are not available by the conventional solid state technique, were also successfully obtained by the pulsed laser deposition technique.

  • Research Products

    (41 results)

All 2011 2010 2009 2008 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (20 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Raman Scattering Study on the Soft Mode in Pb(Mg_1/3Nb_2/3)O_32011

    • Author(s)
      Hiroki Taniguchi, Mitsuru Itoh, Desheng Fu
    • Journal Title

      Journal of Raman Spectroscopy vol.42

      Pages: 706-714

    • Peer Reviewed
  • [Journal Article] Structure of Ferroelectric Silver Niobate AgNbO_32011

    • Author(s)
      Masatomo Yashima, Shota Matsuyama, Rikiya Sano, Mitsuru Itoh, Kenji Tsuda, Desheng Fu
    • Journal Title

      Chemistry of Materials vol.23

      Pages: 1643-1645

    • Peer Reviewed
  • [Journal Article] Growth of Quantum Paraelectric La_1/2Na_1/2TiO_3 Single Crystals Using Optical Floating Zone Technique2011

    • Author(s)
      R.Haumont, R.Saint-Martin, J.Chaigneau, M.Devant, J.Hermet, B.Neela Sekhar, Y.Uesu, M.Itoh, J.M.Kiat
    • Journal Title

      Journal of Crystal Growth vol.321

      Pages: 36-39

    • Peer Reviewed
  • [Journal Article] Elastic and Anelastic Properties of Ferroelectric SrTi^<18>O_3 in the kHz-MHz Regime2011

    • Author(s)
      J.F.Scott, J.Bryson, M.A.Carpenter, J.Herrero-Albillos, M.Itoh
    • Journal Title

      Physical Review Letters vol.106

      Pages: 105502-1-"105502-4"

    • Peer Reviewed
  • [Journal Article] New Ferroelectric Aurivillius Oxides : Incorporation of Sc^<3+> in Stoichiometric Compositions2010

    • Author(s)
      Thathan Sivakumar, Mitsuru Itoh
    • Journal Title

      Chemistry of Materials vol.23

      Pages: 129-131

    • Peer Reviewed
  • [Journal Article] Dielectric and Soft-mode Behaviors of AgTaO_32010

    • Author(s)
      Hwee Ping Soon, Hiroki Taniguchi, Mitsuru Itoh
    • Journal Title

      Physical Review B vol.81

      Pages: 104105-1-"104105-7"

    • Peer Reviewed
  • [Journal Article] Invariant Lattice Strain and Polarization in BaTiO_3-CaTiO_3 Ferroelectric Alloys2010

    • Author(s)
      Desheng Fu, Mitsuru Itoh, Shin-ya Koshihara
    • Journal Title

      Journal of Physics : Condensed Matter vol.22

      Pages: 052204-1-"052204-4"

    • Peer Reviewed
  • [Journal Article] Ferroelectricity Triggered in the Quantum Paraelectric AgTaO_3 by Li-substitution2009

    • Author(s)
      Hwee Ping Soon, Hiroki Taniguchi, Mitsuru Itoh
    • Journal Title

      Applied Physics Letters vol.95

      Pages: 242904-1-"242904-3"

    • Peer Reviewed
  • [Journal Article] Relaxor Pb(Mg_1/3Nb_2/3)O_3 : A Ferroelectric with Multiple Inhomogeneities2009

    • Author(s)
      Desheng Fu, Hiroki Taniguchi, Mitsuru Itoh, Shin-ya Koshihara, N.Yamamoto, Shigeo Mori
    • Journal Title

      Physical Review Letters vol.103

      Pages: 207601-1-"207601-4"

    • Peer Reviewed
  • [Journal Article] Low-Driving-Voltage Electroluminescence in Perovskite Films2009

    • Author(s)
      Hiroshi Takashima, Kohei Shimada, Noboru Miura, Tetsuhiro Katsumata, Yoshiyuki Inaguma, Kazushige Ueda, Mitsuru Itoh
    • Journal Title

      Advanced Materials vol.21

      Pages: 3699-3702

    • Peer Reviewed
  • [Journal Article] Direct Observation of the Soft Mode in the Paraelectric Phase of PbTiO_3 by Confocal Micro-Raman Scattering2008

    • Author(s)
      Hwee Ping Soon, Hiroki Taniguchi, Yasuhiro Fujii, Mitsuru Itoh, Makoto Tachibana
    • Journal Title

      Physical Review B vol.78

      Pages: 172103-1-"172103-4"

    • Peer Reviewed
  • [Journal Article] ^<17>O and ^<93>Nb NMR Investigation of Magnetoelectric Effect in Pb(Fe_1/2Nb_1/2)O_32008

    • Author(s)
      Robert Blinc, Valentin V.Laguta, Bostjan Zalar, Blaz Zupanoio, Mitsuru Itoh
    • Journal Title

      Journal of Applied Physics vol.104

      Pages: 084105-1-"084105-4"

    • Peer Reviewed
  • [Journal Article] Positive and Negative Magnetodielectric Effects in A-Site Ordered (BiMn_3)Mn_4O_12 Perovskite2008

    • Author(s)
      Naoki Imamura, Maarit Karppinen, Teruki Motohashi, Desheng Fu, Mitsuru Itoh, Hisao Yamauchi
    • Journal Title

      Journal of the American Chemical Society vol.130

      Pages: 14948-14949

    • Peer Reviewed
  • [Journal Article] Crystal Growth and Piezoelectricity of BaTiO_3-CaTiO_3 Solid Solution2008

    • Author(s)
      Desheng Fu, Mitsuru Itoh, Shin-ya Koshihara
    • Journal Title

      Applied Physics Letters vol.93

      Pages: 012904-1-"102904-3"

    • Peer Reviewed
  • [Journal Article] Ferroelectric Phase Transition of Cd_2Nb_2O_7 Studied by Raman Scattering2008

    • Author(s)
      Hiroki Taniguchi, Takao Shimizu, Hitoshi Kawaji, Tooru Atake, Mitsuru Itoh, Makoto Tachibana
    • Journal Title

      Physical Review B vol.77

      Pages: 224104-1-"224104-5"

    • Peer Reviewed
  • [Journal Article] Anomalous Phase Diagram of Ferroelectric (Ba, Ca)TiO_3 Single Crystals with Giant Electromechanical Response2008

    • Author(s)
      Desheng Fu, Mitsuru Itoh, Shin-ya Koshihara, Taichi Kosuge, Shinji Tsuneyuki
    • Journal Title

      Physical Review Letters vol.100

      Pages: 227601-1-"227601-4"

    • Peer Reviewed
  • [Journal Article] Piezoelectric Properties of Lithium Modified Silver Niobate Perovskite Single Crystals2008

    • Author(s)
      Desheng Fu, Makoto Endo, Hiroki Taniguchi, Tomoyasu Taniyama, Shin-ya Koshihara, Mitsuru Itoh
    • Journal Title

      Applied Physics Letters vol.92

      Pages: 172905-1-"172905-3"

    • Peer Reviewed
  • [Journal Article] Optically Spin Oriented Electron Transmission across fully Epitaxial Fe_3O_4 /GaAs001 Interfaces2008

    • Author(s)
      T.Taniyama, T.Mori, K.Watanabe, E.Wada, M.Itoh, H.Yanagihara
    • Journal Title

      Journal of Applied Physics vol.103

      Pages: 07D705-1-"07D705-4"

    • Peer Reviewed
  • [Journal Article] Origin of Giant Dielectric Response in Nonferroelectric CaCu_3Ti_4O_12 : Inhomogeneous Conduction Nature Probed by Atomic Force Microscopy2008

    • Author(s)
      Desheng Fu, Hiroki Taniguchi, Tomoyasu Taniyama, Mitsuru Itoh, Shin-ya Koshihara
    • Journal Title

      Chemistry of Materials vol.20

      Pages: 1694-1698

    • Peer Reviewed
  • [Presentation] 収束電子回析法による強誘電体AgNbO_3および(Ag, Li)NbO_3の構造の研究2011

    • Author(s)
      津田健治, 佐野力也, 符徳勝, 伊藤満
    • Organizer
      日本電子顕微鏡学会第67回学術講演会
    • Place of Presentation
      福岡
    • Year and Date
      2011-05-16
  • [Presentation] 擬一次元鎖状ペロブスカイトK_2(NbO)_2Si_4O_12の合成と物性評価2011

    • Author(s)
      谷口博基, 森分博紀, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 強誘電体Ba_1-xCa_xTiO_3における相転移機構2011

    • Author(s)
      清水荘雄, 符徳勝, 谷口博基, 谷山智康, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 強誘電体BaTiO_3上のFe/Cu/Co構造の磁気抵抗特性2011

    • Author(s)
      内藤朋之, 伊藤満, 谷山智康
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 負圧効果によるBaTiO_3の強誘電相転移温度の巨大増加2011

    • Author(s)
      符徳勝, 深町浩平, 坂本尚紀, 脇谷尚樹, 鈴木久男, 伊藤満, 西山毅
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 高いT_cをもつ(Ba, Ca)TiO_3膜2011

    • Author(s)
      符徳勝, 深町浩平, 坂本尚紀, 脇谷尚樹, 鈴木久男, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 酸化物強誘電体の偏光ラマン分光2011

    • Author(s)
      藤井康裕, 能重昌嗣, 西尾泉, 谷口博基, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] リラクサーPb(Mg_1/3Nb_2/3)O_3の低周波数領域光散乱分光(III)2011

    • Author(s)
      是枝聡肇, 齊官清四郎, 谷口博基, 伊藤満, 森茂生
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] 収束電子回析法による(Ag, Li)NbO_3室温相の空間群決定2011

    • Author(s)
      佐野力也, 津田健治, 符徳勝, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] (Ba_1-xCa_x)TiO_3の透過型電子顕微鏡における微細構造評価2011

    • Author(s)
      小山司, 尾崎友厚, 森茂生, 符徳勝, 清水荘雄, 谷口博基, 伊藤満
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟
    • Year and Date
      2011-03-25
  • [Presentation] PLD法によるCaMoO_4:Eu薄膜作成と螢光特性2011

    • Author(s)
      趙明姫, 谷山智康, 谷口博基, 伊藤満, 高島浩
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      厚木
    • Year and Date
      2011-03-24
  • [Presentation] PLD法によるMnTiO_3薄膜作成と構造制御2011

    • Author(s)
      星野晃大, 清水荘雄, 谷口博基, 谷山智康, 阿藤敏行, 伊藤満, 稲熊宜之
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      厚木
    • Year and Date
      2011-03-24
  • [Presentation] Pb(Fe_2/3W_1/3)O_3-PbTiO_3の光起電力効果に関する研究2011

    • Author(s)
      有岡孝祐, 谷口博基, 谷山智康, 伊藤満
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      厚木
    • Year and Date
      2011-03-24
  • [Presentation] Interfacial Strain Induced Magnetic Anisotropy of Epitaxial Fe_3O_4/BaTiO_3 Heterostructures2010

    • Author(s)
      Y.Shirahata, T.Nozaki, M.Itoh, T.Taniyama
    • Organizer
      International Conference of Asian Union of Magnetics Societies (ICAUMS2010)
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2010-12-05
  • [Presentation] Switching of Magnetic Anisotropy due to Interfacial Strain at Fe/BaTiO_32010

    • Author(s)
      Y.Shirahata, T.Nozaki, H.Taniguchi, M.Itoh, T.Taniyama
    • Organizer
      55th Annual Conference on Magnetism & Magnetic Materials (MMM2010)
    • Place of Presentation
      Atlanta, Georgia, USA.
    • Year and Date
      2010-11-14
  • [Presentation] SrTiO_3(110)上へのBaTiO_3薄膜作製と物性評価2010

    • Author(s)
      有岡孝祐, 諏訪間大, 星野晃大, 清水荘雄, 谷口博基, 谷山智康, 伊藤満
    • Organizer
      2010年秋季第71回応用物理学会学術講演会
    • Place of Presentation
      長崎
    • Year and Date
      2010-09-14
  • [Presentation] Pb(Mg_1/3Nb_2/3)O_3リラクサーにおける局所分極発現機構2010

    • Author(s)
      谷口博基, 伊藤満
    • Organizer
      2010年セラミックス総合研究会
    • Place of Presentation
      札幌.
    • Year and Date
      2010-09-02
  • [Presentation] Low-Electric-Field-Driving Electroluminescence in ((Ca_0.6Sr_0.4)_0.997Pr_0.002)TiO_3 and SrTiO_3 Perovskite Films2009

    • Author(s)
      H.Takashima, N.Miura, Y.Inaguma, K.Ueda, M.Itoh
    • Organizer
      The 16th International Display Workshops (IDW09)
    • Place of Presentation
      Miyazaki, Japan.
    • Year and Date
      2009-12-09
  • [Presentation] 光励起下のSrTiO_3の電子状態2009

    • Author(s)
      藤原幸宏, 山下直飛人, 溝川貴司, 石川忠彦, 腰原伸也, 武貞正樹, 伊藤満
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-25
  • [Presentation] A Rhombohedral Phase at Room Temperature in Solid Solution (1-x)Na_0.5K_0.5NbO_3-xBaZrO_32009

    • Author(s)
      Ruiping Wang, Hiroshi Bando, Tetsuhiro Katsumata, Yoshiyuki Inaguma, Mitsuru Itoh
    • Organizer
      8th Pacific RIM Conference on Ceramic and Glass Technology (PAC RIM-8)
    • Place of Presentation
      Vancouver, Canada.
    • Year and Date
      2009-05-31
  • [Book] Ferroelectrics(Ferroelectricity in Silver perovskite Oxides)2011

    • Author(s)
      Desheng Fu, Mitsuru Itoh
    • Publisher
      InTech in press.
  • [Remarks] ホームページ

    • URL

      http://www.msl.titech.ac.jp/~itohlab/

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

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