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2011 Fiscal Year Final Research Report

Atomic force spectroscopy of chemical bonding process with bias voltage tuning between a tip and a sample

Research Project

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Project/Area Number 20310058
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKanazawa University

Principal Investigator

ARAI Toyoko  金沢大学, 数物科学系, 教授 (20250235)

Co-Investigator(Renkei-kenkyūsha) TOMITORI Masahiko  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 教授 (10188790)
MURATA Hideyuki  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 教授 (10345663)
Project Period (FY) 2008 – 2011
Keywords走査プローブ顕微鏡 / 化学結合 / 結合形成過程 / ナノ表面・界面 / 顕微分光
Research Abstract

The purpose of this study was to reveal the formation process of bonding state between an atom of a sample surface and an atom at the tip apex of atomic force microscopy(AFM) using our developing bias-voltage non-contact atomic force microscopy/spectroscopy(bias nc-AFM/S). Towards this purpose we developed a force sensor with a high sensitivity, improved our electronic control system for the bias nc-AFM/S, and performed simultaneous measurements with high sensitivities of force, electric current and energy dissipation between the sample and the nc-AFM tip. Through this study we concluded that the covalent bond formation between a Si atom and a Si atom strongly depends on their local electronic density of states(LDOS).

  • Research Products

    (17 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (8 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Local interaction imaging by SiGe quantum dot probe2012

    • Author(s)
      Jeong, Y. K., Arai, T, Tomitori, M.
    • Journal Title

      Current Appl. Phys.

      Volume: 12 Pages: 581-584

    • DOI

      DOI:10.1016/j.cap.2011.09.005

    • Peer Reviewed
  • [Journal Article] Atomic resolution force microscopy imaging on a strongly ionic surface with differently functionalized tip2010

    • Author(s)
      Arai, T., Gritschneder, S., Troger, L., Reichling, M.
    • Journal Title

      J. Vac. Sci. Technol. B

      Volume: 28 Pages: 1279-1283

    • DOI

      DOI:10.1116/1.3511505

    • Peer Reviewed
  • [Journal Article] Adsorption State of 4, 4 Diamino-p-terphenyl through an Amino Group Bound to Si(111)-7x7 Surface Examined by X-ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy2010

    • Author(s)
      Nishimura, T., Itabashi, A., Sasahara, A., Murata, H., Arai, T., Tomitori, M.
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Pages: 11109-11114

    • DOI

      DOI:10.1021/jp102976a

    • Peer Reviewed
  • [Journal Article] Low-flux elucidation of initial growth of Ge clusters deposited on Si(111)-7x7 observed by scanning tunneling microscopy2009

    • Author(s)
      Ansari, Z. A., Arai, T., Tomitori, M.
    • Journal Title

      Phys. Rev. B

      Volume: 79 Pages: 033302-1-033302-4

    • DOI

      DOI:10.1103/PhysRevB.79.033302

    • Peer Reviewed
  • [Journal Article] 走査型プローブ顕微鏡にみる電圧印加のナノ力学的相互作用2008

    • Author(s)
      富取正彦, 新井豊子
    • Journal Title

      表面科学

      Volume: 29 Pages: 239-245

    • DOI

      DOI:10.1380/jsssj.29.239

    • Peer Reviewed
  • [Presentation] Non-contact AFM observation of Si(111)-(7×7) terminated with hydrogen2011

    • Author(s)
      Arai, T., Ishikawa, T., Ikeshima, T., Tomitori, M.
    • Organizer
      The 6th International Symposium on Surface Science(ISSS6)
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-12-12
  • [Presentation] NC-AFM and Force spectroscopy applied to H terminated Si(111) 7x72011

    • Author(s)
      Arai, T., Ikeshima, T., Zhang, Y., Tomitori, M.
    • Organizer
      14th International Conferencence on Noncontact Atomic Force Microscopy(ncAFM2011)
    • Place of Presentation
      Lindau(Germany)
    • Year and Date
      2011-09-19
  • [Presentation] π電子系分子で界面制御したシリコン/有機半導体素子の製作と評価2010

    • Author(s)
      西村高志,村田英幸,笹原亮,新井豊子,富取正彦
    • Organizer
      応用物理学会北陸・信越支部学術講演会
    • Place of Presentation
      金沢大学(石川県)
    • Year and Date
      2010-11-19
  • [Presentation] Nanoscale analysis by combined spectroscopies based on non-contact atomic force microscopy under a bias voltage2010

    • Author(s)
      Arai, T., Ikeshima, T., Kiyohara, K., Tomitori, M.
    • Organizer
      13th International Conferencence on Noncontact Atomic Force Microscopy(ncAFM2010)
    • Place of Presentation
      川県立音楽堂(石川県)
    • Year and Date
      2010-08-02
  • [Presentation] Surface electron spectroscopy based on nc-AFM with changing bias voltage at closer tip-sample separations2009

    • Author(s)
      Arai, T., Kiyohara, K., Sato, T., Tomitori, M.
    • Organizer
      10th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures(ACSIN10)
    • Place of Presentation
      Granada Conference Centre(Spain)
    • Year and Date
      2009-09-22
  • [Presentation] From non-contact to atomic scale contact between a Si tip and a Si surface analyzed using an nc-AFM and nc-AFS based instrument2009

    • Author(s)
      Arai, T., Kiyohara, K., Sato, T., Kushida, S., Tomitori, M.
    • Organizer
      12th international conference on noncontact atomic force microscopy(ncAFM2009)
    • Place of Presentation
      Yale Univ.(USA)
    • Year and Date
      2009-08-11
  • [Presentation] Surface electron spectroscopy based on nc-AFM with changing bias voltage2008

    • Author(s)
      Arai, T., Kushida, S., Kiyohara, K., Tomitori, M.
    • Organizer
      11th international conference on noncontact atomic force microscopy(ncAFM2008)
    • Place of Presentation
      Hotel Rafael Atocha, Madrid(Spain)
    • Year and Date
      2008-09-16
  • [Presentation] Current-Voltage Characteristics with Staircases of a Si Point Contact between a Si Tip and a Si Substrate2008

    • Author(s)
      Arai, T., Kiyohara, K., Kushida, S., Tomitori, M.
    • Organizer
      International Conference on Nanoscience^+Technology(ICN+T 2008)
    • Place of Presentation
      Keystone(USA)
    • Year and Date
      2008-07-20
  • [Book] 走査プローブ顕微鏡.正しい実験とデータ解析のために必要なこと-2009

    • Author(s)
      新井豊子
    • Total Pages
      357-363
    • Publisher
      共立出版
  • [Remarks]

    • URL

      http://nanophys.w3.kanazawa-u.ac.jp/

  • [Patent(Industrial Property Rights)] ポジショニング機構、及び、それを用いた顕微鏡2010

    • Inventor(s)
      富取正彦、新井豊子、中榮穣
    • Industrial Property Rights Holder
      北陸先端科学技術大学院大学
    • Industrial Property Number
      特許、特許第4644821号
    • Filing Date
      2010-12-17
  • [Patent(Industrial Property Rights)] Positioning mechanism and microscope with the same2010

    • Inventor(s)
      富取正彦、新井豊子、中榮穣
    • Industrial Property Rights Holder
      北陸先端科学技術大学院大学
    • Industrial Property Number
      US patent、US 7, 672, 048 B2
    • Filing Date
      2010-03-02
    • Overseas

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Published: 2013-07-31  

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