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2011 Fiscal Year Final Research Report

Construction of Spin Network by Chemical Modification of Organic Radical Self-Assemblies

Research Project

  • PDF
Project/Area Number 20310060
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKeio University

Principal Investigator

YOSHIOKA Naoki  慶應義塾大学, 理工学部, 教授 (30222392)

Project Period (FY) 2008 – 2011
Keywords有機ラジカル / 自己組織化 / 分子磁性 / 構造物性相関
Research Abstract

Magnetism had been recognized as a unique characteristic of inorganic compounds such as metals and metal oxides. Because bulk magnetic ordering is closely correlated with the arrangement of open-shell molecules in the molecular crystal, supramolecular design techniques such as hydrogen bond is successfully applied to construct spin networks.

  • Research Products

    (17 results)

All 2012 2011 2010 2009 2008

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (12 results)

  • [Journal Article] Magnetic Tuning of All-Organic Binary Alloys between Two Stable Radicals2012

    • Author(s)
      G. Seber, R. S. Freitas, J. T. Mague, A. Paduan-Filho, X. Gratens, V. Bindilatti, N. F. Oliveira, Jr., N. Yoshioka, and P. M. Lahti
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Pages: 3825-3833

    • Peer Reviewed
  • [Journal Article] Theoretical Study of Intermolecular Magnetic Interaction of Chromium(V)-Nitrido Complex Self-Assembly with Tetradentate Schiff Base Ligands2012

    • Author(s)
      N. Matsuoka, N. Yoshioka
    • Journal Title

      Chemical Physics Letters

      Volume: 523 Pages: 65-68

    • Peer Reviewed
  • [Journal Article] Theoretical Study of Magnetic Properties of Oxovanadium(IV) Complex Self-assemblies with Tetradentate Schiff Base Ligands2011

    • Author(s)
      N. Matsuoka, M. Tsuchimoto, N. Yoshioka
    • Journal Title

      Journal of Physical Chemistry B

      Volume: (掲載決定) Pages: 115

    • Peer Reviewed
  • [Journal Article] Magnetic property and crystal structure of bis [N-(4-chlorophenyl) salicylidene aminato] oxovanadium(IV)2010

    • Author(s)
      N. Matsuoka, H. Kawamura, N. Yoshioka
    • Journal Title

      Chemical Physics Letters

      Volume: 488 Pages: 32-37

    • Peer Reviewed
  • [Journal Article] Electronic structures and magnetic properties of copper(II) complexes with axially coordinated nitronyl nitroxide radicals2009

    • Author(s)
      N. Matsuoka, N. Yoshioka
    • Journal Title

      Polyhedron

      Volume: 28 Pages: 1875-1879

    • Peer Reviewed
  • [Presentation] Design of Nitronyl Nitroxide Self-Assemblies Exhibiting Strong Magnetic Interactions2011

    • Author(s)
      N. Yoshioka
    • Organizer
      The 5th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji Island(Japan)
    • Year and Date
      2011-11-15
  • [Presentation] Effect of Ring Extension on Crystal Structures and Magnetic Properties ofBenzimidazole and Indole Nitronyl Nitroxide Derivetives2011

    • Author(s)
      Y. Yamaguchi, C. Maeda, N. Yoshioka
    • Organizer
      The 5th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji Island(Japan)
    • Year and Date
      2011-11-14
  • [Presentation] Effect of Pivaloyl and Nitro Groups on the Solid State Magnetic Property of Indole Nitronyl Nitroxide2011

    • Author(s)
      H. Sugawara, C. Maeda, N. Yoshioka
    • Organizer
      The 5th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji Island(Japan)
    • Year and Date
      2011-11-14
  • [Presentation] Effect of Electron Withdrawing Groups on Crystal Structure and Solid State Magnetic Property of Indole Nitronyl Nitroxide2011

    • Author(s)
      S. Jo, C. Maeda, N. Yoshioka
    • Organizer
      The 5th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji Island(Japan)
    • Year and Date
      2011-11-14
  • [Presentation] インドールニトロニルニトロキシドの結晶構造および固体磁気特性に及ぼすシアノ基導入効果2011

    • Author(s)
      徐〓、前田千尋、吉岡直樹
    • Organizer
      第20回有機結晶シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2011-10-21
  • [Presentation] 環拡張したベンズイミダゾールニトロニルニトロキシド誘導体の構造と磁気特性イ2011

    • Author(s)
      山口裕太、前田千尋、吉岡直樹
    • Organizer
      第20回有機結晶シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2011-10-21
  • [Presentation] Design of Nitroxy Radical Self-Assemblies Exhibiting Strong Magnetic Interaction2011

    • Author(s)
      N. Yoshioka
    • Organizer
      2011 International Conference on Synthesis, Properties and Implications of Nitroxides(SPIN 2011)
    • Place of Presentation
      Marseilles(France)
    • Year and Date
      2011-09-27
  • [Presentation] Design of Nitroxy Radical Self-Assemblies Exhibiting Strong Magnetic Interaction2010

    • Author(s)
      N. Yoshioka
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu(U. S. A.)
    • Year and Date
      2010-12-18
  • [Presentation] Design and Construction of Molecular Magnetic Materials Using Open-Shell Molecules2010

    • Author(s)
      N. Yoshioka
    • Organizer
      1st International Conference on Computation for Science and Technology
    • Place of Presentation
      Chiang Mai(Thailand)
    • Year and Date
      2010-08-05
  • [Presentation] ピロール-2-ニトロニルニトロキシドラジカル及び類縁体の集積形態と低温磁気特性2009

    • Author(s)
      鹿島直樹, 吉岡直樹, 他
    • Organizer
      2009分子科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2009-09-24
  • [Presentation] インドールニトロニルニトロキシドの固体磁気特性に及ぼす6位ハロゲン導入効果2009

    • Author(s)
      村岡貴梓、須藤信浩、吉岡直樹
    • Organizer
      2009分子科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2009-09-24
  • [Presentation] Control of Inter-columnar Magnetic Interaction of Indole Nitronyl Nitroxide Derivatives By Chemical Modification of Benzo-ring2008

    • Author(s)
      N. Yoshioka, et al
    • Organizer
      11th International Conference on Molecule-based Magnets(ICMM2008)
    • Place of Presentation
      Florence(Italy)
    • Year and Date
      2008-09-11

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Published: 2013-07-31  

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